Skip to main content

Energy-Filtered Reflection Electron Microscopy

  • Chapter
Energy-Filtering Transmission Electron Microscopy

Part of the book series: Springer Series in Optical Sciences ((SSOS,volume 71))

Abstract

The imaging of crystal surfaces at high resolution using electron beams has been a long-standing challenge for physicists. Techniques for this purpose promise wide application, from research into the kinetics and atomic mechanisms of crystal growth to studies of semiconductor interfaces and monolayer magnetism. Ideally, such a method should be capable of identifying atomic species, should provide real-time atomic resolution imaging over a wide range of temperatures, and should allow imaging of individual sub-surface layers. Currently, while no one technique can achieve all these goals, the following techniques come closest : secondary-electron scanning microscopy in ultrahigh vacuum (UHV SEM) [8.1], scanning Auger microscopy (SAM) [8.1], scanning tunnelling microscopy (STM) [8.2], sub-surface backscattered channelling imaging [8.3,4], forbidden-reflection TEM lattice imaging in ultra-high vacuum (UHV HREM) [8.5] and the reflection electron microscopy (REM) technique reviewed in this chapter. (The field-ion microscope may also provide an even higher performance than these methods in certain specialised cases [8.2]). These electron beam techniques offer resolutions of about 1 nm for REM and SEM [8.1], 2 nm for SAM [8.2], and about 0.25 nm for STM and UHV HREM. The resolution of the low-energy electron microscopy (LEEM) technique [8.6] may also become competitive in the future if chromatic-aberration corrected designs can be implemented.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

eBook
USD 16.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 16.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. G.G. Hembree, J.S. Drucker, F.C. Luo, M. Krishnamurthy, J.A.V. Venables: Auger electron spectroscopy and microscopy with probe size limited resolution. Appl. Phys. Lett. 58, 1–8 (1991)

    Article  Google Scholar 

  2. D.R Woodruff, T.A. Delchar: Modern Techniques of Surface Science (Cambridge University Press, Cambridge 1986)

    Google Scholar 

  3. P. Morin, M. Pitaval, D. Besnard, G. Fontaine: Backscattered channelling imaging. Phil. Mag. 40, 511–520 (1979)

    Article  Google Scholar 

  4. J.T. Czernuszka, N.J. Long, P.B. Hirsch: Electron channelling contrast imaging of dislocations. In Proc. XII th Int’l Congr. on Electron Microscopy, ed. by R.M. Fisher (San Francisco Press, San Francisco 1990) Vol.2, pp.600–601

    Google Scholar 

  5. Y. Haga, K. Takayanagi: Single atom imaging in high resolution UHV electron microscopy: Bismuth on Si(111) surface. Ultramicroscopy 45, 95–102 (1992)

    Article  Google Scholar 

  6. E. Bauer, M. Maunschau, W. Swiech, W. Telieps: Surface studies by LEEM and PEEM. Ultramicroscopy 31, 49–55 (1989)

    Article  Google Scholar 

  7. E. Ruska: Die elektronenmikroskopische Abbildung elektronenbestrahlter Oberflächen. Z. Physik 83, 492–503 (1933)

    Article  ADS  Google Scholar 

  8. J. S. Halliday, R.C. Newman: Reflexion electron microscopy using diffracted electrons. Brit. J. Appl. Phys. 11, 158–165 (1960)

    Article  ADS  Google Scholar 

  9. K. Takayanagi, Y. Tanishiro, K. Kobayashi, K. Akiyama, K. Yagi: Surface structures observed by high resolution UHV electron microscopy at atomic level. Jpn. J. Appl. Phys. 26, L957–L960 (1987)

    Article  ADS  Google Scholar 

  10. N. Osakabe, Y. Tanishiro, K. Yagi, G. Honjo: Observation of Si(lll) 7×7 – 1×1 transition by REM. Surf. Sci. 97, 393–404 (1980)

    Article  ADS  Google Scholar 

  11. A.V. Latyshev, A.L. Aseev, A.B. Krasilnikov: Reflection electron microscopy study of structural transformations on silicon. Surf. Sci. 227, 24–34 (1990)

    Article  ADS  Google Scholar 

  12. J.M. Cowley: Surface energies and surface structure of small crystals studied by use of a STEM instrument. Ultramicroscopy 114, 587–606 (1982)

    Google Scholar 

  13. Z.L. Wang, J.M. Cowley: Reflection electron energy loss spectroscopy. Surf. Sci. 193, 501–512 (1988)

    Article  ADS  Google Scholar 

  14. K. Yagi: Reflection electron microscopy. Surface Science Reports 17, 305–362 (1993)

    Article  ADS  Google Scholar 

  15. J.M. Cowley: Reflection electron microscopy. In Surface and Interface Characterisation by Electron Optical Methods, ed by A. Howie and U. Valdrè (Plenum, New York 1988) pp.127–149

    Chapter  Google Scholar 

  16. P.A. Crozier, M. Gajdardziska-Josifovska, J.M. Cowley: Observation of reconstruction on (111) MgO. In Proc. XII th Int’l Congr. on Electron Microscopy, ed. by R.M. Fisher (San Francisco Press, San Francisco 1990) Vol.2, pp.280–281

    Google Scholar 

  17. N. Yao, Z.L. Wang, J.M. Cowley: REM and REELS identification of atomic terminations at β-alumina surfaces. Ultramicroscopy 28, 533–549 (1989)

    Google Scholar 

  18. F. Tsai, J.M. Cowley: Observations of ferrolelectric domain boundaries in BaTiO3 by REM. Ultramicroscopy 45, 43–54 (1992)

    Article  Google Scholar 

  19. A. Yamanaka, K. Yagi: Surface electromigration of In and Cu on Si(111) surfaces studied by REM. Surf. Sci. 242, 181–190 (1991)

    Article  ADS  Google Scholar 

  20. A. Ichimiya, K. Kambe, G. Lehmpfuhl: Observation of the surface state resonance by the CBED RHEED technique. J. Phys. Soc. Jpn. 49, 684–691 (1980)

    Article  ADS  Google Scholar 

  21. P.K. Larsen, P.J. Dobson: RHEED and Reflection Imaging of Surfaces. NATO ASI Series (Plenum, New York 1988) Vol. B188

    Google Scholar 

  22. T. Hsu, J.M. Cowley: Reflection electron microscopy of f.c.c. metals. Ultramicroscopy 11, 239–250 (1983)

    Article  Google Scholar 

  23. J. Spence, W. Lo, M. Kuwabara: Observation of the graphite surface by reflection electron microscopy during STM operation. Ultramicroscopy 33, 69–82 (1990)

    Article  Google Scholar 

  24. T. Hsu: A laboratory guide for reflection electron microscopy. Norelco Reporter 31, 1–15 (1984)

    Google Scholar 

  25. P.R. Swann, J.S. Jones, O. Krivanek, D.J. Smith, J.A. Venables, J.M. Cowley: UHV conversion of a 300 kV HREM. Proc. 45th Ann. Meeting of EMSA (San Francisco Press, San Francisco 1987) pp. 136–137.

    Google Scholar 

  26. Y. Kondo et al.: Design and development of UHV HRTEM. Ultramicroscopy 35, 111–118 (1991)

    Article  Google Scholar 

  27. K. Takayanagi, K. Yagi, K. Kobayashi, G. Honjo: Technique for routine UHV in-situ electron microscopy of growth process of epitaxial thin films. J. Phys. E 11, 441–455 (1978)

    Article  ADS  Google Scholar 

  28. K. Heinemann, H. Poppa: An ultrahigh vacuum multipurpose specimen chamber with sample introduction system for in-situ transmission electron microscopy investigations. J. Vac. Sci. Techn. A 4, 127–138 (1986)

    Article  ADS  Google Scholar 

  29. M.L. McDonald, J.M. Gibson, F.C. Unterwald: The design of an ultra-high vacuum specimen environment for a high resolution TEM. J. Sci. Instr. 86, 13–21 (1988)

    Google Scholar 

  30. C. Elibol, H.J. Ou, G.G. Hembree, J.M. Cowley: Improved instrument for medium energy electron diffraction and microscopy of surfaces. Rev. Sci. Instr. 56, 1215–1228 (1985)

    Article  ADS  Google Scholar 

  31. J.A.V. Venables, A.P. Janssen, P. Akhter, J. Derrien, C.J. Harland: Surface studies in a UHV field-emission gun scanning electron microscope. J. Micr. 118, 351–367 (1980)

    Article  Google Scholar 

  32. M. Ichikawa, K. Hayakawa: Micro-probe RHEED. Jpn. J. Appl. Phys. 21, 145–159 (1982)

    Article  ADS  Google Scholar 

  33. K. Kambe: Anomalous reflected images of objects on crystal surfaces in REM. Ultramicroscopy 25, 259–266 (1988)

    Article  Google Scholar 

  34. S. Miyake, K. Hayakawa: Resonance effects in low and high energy electron diffraction by crystals. Acta Cryst A 26, 60–77 (1970)

    Article  Google Scholar 

  35. L.M. Peng, J.M. Cowley, T. Hsu: Diffraction contrast in REM — steps. Micron and Micr. Acta. 18, 179–186 (1987)

    Article  Google Scholar 

  36. T. Hsu, L-M. Peng: Experimental studies of steps in REM. Ultramicroscopy 22, 217–224 (1987)

    Article  Google Scholar 

  37. Y. Uchida, G. Lehmpfuhl: Observation of double contours of monatomic steps in REM. Ultramicroscopy 23, 53–60 (1987)

    Article  Google Scholar 

  38. J.M. Cowley, L. Peng: The image contrast of surface steps in REM. Ultramicroscopy 59, 59–68 (1985)

    Article  Google Scholar 

  39. N. Osakabe, Y. Tanishiro, K. Yagi, G. Honjo: Image contrast of dislocations and atomic steps on (111) silicon surface in reflection electron microscopy. Surf. Sci. 102, 424–437 (1981)

    Article  Google Scholar 

  40. H. Banzhof, K.H. Herrman, H. Lichte: Reflection electron microscopy and interferometry of atomic steps on gold and platinum. Microscopy Research and Technique 20, 450–466 (1992)

    Article  Google Scholar 

  41. N. Osakabe: Observation of surfaces by reflection electron holography. Microscopy Research and Technique 20, 457–466 (1992)

    Article  Google Scholar 

  42. Z.L. Wang, J. Liu, P. Lu, J. M. Cowley: Electron resonance reflections from perfect crystals and crystal surfaces with steps. Ultramicroscopy 27, 101–112 (1989)

    Article  Google Scholar 

  43. H.A. Bethe: Theorie der Beugung von Electronen an Kristallen. Ann. Physik (Leipzig) 87, 55–76 (1928)

    Article  ADS  Google Scholar 

  44. H. Shuman: Bragg diffraction imaging of defects at crystal surfaces. Ultramicroscopy 2, 361–376 (1977)

    Article  Google Scholar 

  45. L.M. Peng, J.M. Cowley: Diffraction contrast in REM. Screw dislocations. Micron and Micros. Acta 18, 171–180 (1987)

    Article  Google Scholar 

  46. A. Howie: Reflection high energy electron diffraction and reflection electron imaging of surfaces. In RHEED and Reflection Imaging of Surfaces, ed. by P. Larsen and P. Dobson (Plenum, New York 1988)

    Google Scholar 

  47. L.M. Peng, J.M. Cowley: Multislice for RHEED. Acta Cryst. A 42, 545–552 (1986)

    Article  Google Scholar 

  48. G.R. Anstis, X.S. Gan: Simulation for reflection electron microscopy. Scanning Electron Microscopy 1992, Proc. Pfefferkorn Conf. in Signal Processing, (SEM Inc., AMF O’Hare)

    Google Scholar 

  49. Z.L. Wang, J.C.H. Spence: Magnetic contrast in reflection electron microscopy. Surf. Sci. 234, 98–108 (1990)

    Article  ADS  Google Scholar 

  50. J. Spence, Y. Kim: Adatom site determination using channelling effects in RHEED on X-ray and Auger electron production. In RHEED and Reflection Electron Imaging of Surfaces, ed. by P.K. Larsen and P.J. Dobson (Plenum, New York 1988) pp.117–128

    Chapter  Google Scholar 

  51. Z.L. Wang, J. Bentley: Optimum experimental conditions for quantitative surface microanalysis by REM. Micros. Microanal. Microstr. 2, 301–314 (1991)

    Article  Google Scholar 

  52. J. Bruley, L.M. Brown, S.D. Berger: A study of the electronic structure of diamond by STEM. EMAG1985, ed. by G. Tatlock, Conf. Ser. 78 (Inst. of Phys., Bristol 1985) pp.561–564.

    Google Scholar 

  53. A. Howie: Surface reactions and excitations. Ultramicroscopy 11, 141–148 (1983)

    Article  Google Scholar 

  54. J. Schilling: Reflection ELS of Ga, In, Al, Si at 10 kV. Z. Physik B 25, 61–67 (1976)

    Article  ADS  Google Scholar 

  55. R.F. Egerton: Electron Energy-Loss Spectroscopy in the Electron Microscope (Plenum, New York 1986)

    Google Scholar 

  56. O.L. Krivanek, A.J. Gubbens, N. Dellby: Developments in EELS instrumentation for spectroscopy and imaging. Microsc. Microanalysis and Microstructures 2, 315–332 (1991)

    Article  Google Scholar 

  57. H. Liebl: The image aberration caused by the acceleration field between concentric spherical electodes. Optik 83, 129–135 (1989)

    Google Scholar 

  58. L.M. Peng, J.M. Cowley: Thermal diffuse scattering and REM image contrast preservation. Ultramicroscopy 29, 168–176 (1989)

    Article  Google Scholar 

  59. A. Bleloch, A. Howie, R. Milne, M. Walls: Elastic and inelastic scattering effects in reflection electron microscopy. Ultramicroscopy 29, 175–185 (1989)

    Article  Google Scholar 

  60. G. Meyer-Ehmsen: Direct calculation of the dynamical reflectivity matrix for RHEED. Surf. Sci. 219, 177–188 (1989)

    Article  ADS  Google Scholar 

  61. L. Wang, J.M. Cowley: Electron channelling effects in filtered CBED RHEED. Ultramicroscopy 55, 228–240 (1994)

    Article  Google Scholar 

  62. N. Yamamoto, S. Muto: REM of multilayer. Jpn. J. Appl. Phys. 23, L804–L807 (1984)

    Google Scholar 

  63. G. Ndubuisi, J. Liu, J. M. Cowley: REM observation of the prismatic faces of sapphire. Proc. XHth Int’l Congr. on Electron Microscopy, ed. by R. Fisher (San Francisco Press, San Francisco 1990) Vol. 1, pp.330–331.

    Google Scholar 

  64. J. Liu, J.M. Cowley: Energy-filtered scanning reflection imaging of copper. Proc. 42th Ann. Meeting of EMSA (San Francisco Press, San Francisco 1989) pp.542–543.

    Google Scholar 

  65. J. Spence, J. Mayer: Zero loss Omega filtered REM and RHEED on the Zeiss 912. Proc. 49th Ann. Meeting of EMSA, (San Francisco Press, San Francisco 1991) pp.616–617.

    Google Scholar 

Download references

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1995 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Spence, J.C.H. (1995). Energy-Filtered Reflection Electron Microscopy. In: Reimer, L. (eds) Energy-Filtering Transmission Electron Microscopy. Springer Series in Optical Sciences, vol 71. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-48995-5_8

Download citation

  • DOI: https://doi.org/10.1007/978-3-540-48995-5_8

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-662-14055-0

  • Online ISBN: 978-3-540-48995-5

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics