Abstract
Photothermal deflection spectroscopy (PDS), like the other thermal-wave methods, can be used to obtain the absorption spectra of materials. Several groups have obtained PDS spectra of semiconductor electrodes in photoelectrochemical (PEC) cells [1–3]. Subsequent to our original work [1], we have carried out an extensive study involving the measurement of both PDS and photoaction spectra for several different n-CdS electrodes in polysulfide electrolytes. The information obtained by the two combined spectroscopic techniques can be qualitatively compared taking into account both the magnitude and phase variations of the spectra. The phase information is especially useful in helping one to decide whether the weak subbandgap signals are due to bulk absorptions, surface absorptions, or a combination of both.
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References
R.E. Wagner, V.K.T. Wong, A. Mandelis- Analyst 111, 299 (1985).
J.P. Roger, D. Fournier, A.C. Boccara, R. Noufi, D. Cahen: Thin Solid Films 121, 11 (1985).
M.A. Tamor, R.E. Hetrick: Appl. Phys. Lett. 46, 460 (1985).
D. Dutton: Phys. Rev. 112, 785 (1985).
A. Mandelis, Y.C. Teng and B.S.H. Royce: J. Appi. Phys. 50, 7138 (1979).
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© 1988 Springer-Verlag Berlin Heidelberg
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Wagner, R.E., Mandelis, A. (1988). Characterization of n-CdS/Polysulfide Photoelectrochemical Cells via Photothermal Deflection and Photoaction Spectroscopies. In: Hess, P., Pelzl, J. (eds) Photoacoustic and Photothermal Phenomena. Springer Series in Optical Sciences, vol 58. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-48181-2_9
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DOI: https://doi.org/10.1007/978-3-540-48181-2_9
Publisher Name: Springer, Berlin, Heidelberg
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