Abstract
During the past year numerous experimental and theoretical investigations have been carried out on the prompt dissociation of several polyatomic molecules by intense CO2 laser pulses. The fact that this dissociation process is isotopically selective [1,2] undoubtedly provided the major impetus for this activity. In this presentation attention will not be focused on the important application of laser isotope separation, but on the physical processes by which a single molecule, without the benefit of collisions, may by exposure to an infrared laser pulse acquire sufficient energy for dissociation to occur.
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References
R.V. Ambartzumian, V.S. Letokhov, E.A. Ryabov, N.V. Chekalin: JETP Lett. 20, 273 (1974)
J.L. Lyman, R.J. Jensen, J. Rink, C.P. Robinson, S.D. Rockwood: Appl. Phys. Lett. 27, 87 (1975)
M.C. Borde, A. Henry, M.L. Henry: C.R. Acad. Sc. (Paris) B262, 1389 (1966)
M.C. Borde, A. Henry, M.L. Henry: C.R. Acad. Sc. (Paris) B263, 619 (1967)
N.V. Karlov, Yu. Petrov, A.M. Prokhorov, D.M. Stel’Markh: JETP Lett. 11, 135 (1970)
N.K. Isenor, M.C. Richardson: Appl. Phys. Lett. 18, 225 (1971)
N.K. Isenor, V. Merchant, R.S. Hallsworth, M.C. Richardson: Can. J. Phys. 51, 281 (1973)
E. Yablonovitch: (to be published)
R.V. Ambartzumian, Yu.A. Gorokhov, V.S. Letokhov, G.N. Makarov: ZhETF Pis. Red. 21, 375 (1975) [JETP Lett. 21, 171 (1975)]
R.V. Ambartzumian, Yu.A. Gorokhov, V.S. Letokhov, G.N. Makarov: ZhETF Pis. Red. 22, 96 and 374 (1975)
R.V. Ambartzumian: paper presented at the Nordfjord Conference on Tunable Lasers and Applications, June (1976)
L.S. Letokhov: paper presented at the Laser Chemistry Conference, Steamboat Springs, Colorado, February (1976)
S.D. Rockwood: papers presented at Nordfjord Conference on Tunable Lasers and Applications, June (1976) and at the Laser Chemistry Conference, Steamboat Springs, Colorado, February (1976)
A.V. Nowak, J.L. Lyman: J. Quant. Spectrosc. Rad. Transfer 15, 945 (1975)
J.P. Aldridge, H. Filip, H. Flicker, R.F. Holland, R.S. McDowell, N.G. Nereson, K. Fox: J. Mol. Spectrosc. 58, 165 (1975); R.S. McDowell, H.W. Galbraith, B.J. Krohn, C.D. Cantrell, E.D. Hinkley: Opt. Comm. (to be published); C.D. Cantrell, H.W. Galbraith: J. Mol. Spectrosc. 58, 158 (1975)
S.A. Alimpiev, N.V. Karlov: ZhETF 6(6, 542 (1974)
S.A. Alimpiev, N.V. Karlov [Sov. Phys.- JETP 39, 260 (1974)]
see also, I. Burak, J.I. Steinfeld, D.G. Sutton: J. Quant. Spectrosc. Rad. Transfer 9, 959 (1969)
C.D. Jackson: Los Alamos Scientific Laboratory Report LA-6025-MS-1975
R.J. Glauber: Phus. Rev. 130, 2529 and 131 (1963)
R.J. Glauber: Phus. Rev. 131, 2766 (1963)
W.H. Louisell: Quantum Statistical Properties of Radiation (John Wiley, New York 1973) p. 205
D.M. Larsen, N. Bloembergen: Opt. Comm. to be published (1976)
C.J. Elliott, B.J. Feldman: Bull. Am. Phys. Soc. 20, 1282 (1975)
S. Mukamel, J. Jortner: (to be published); receipt of a preprint, “A model for isotope separation via molecular multiphoton dissociation”, is acknowledged
N. Bloembergen: Opt. Comm. 15, 416 (1975)
R.V. Ambartzumian, Yu.A. Gorokhov, V.S. Letokhov, G.B. Makarov, A.A. Puretzky: ZhETF Pis. Red. 23, January (1976)
Private communications by P.L. Kelley, R.V. Khokhlov, V. Platonenko
F.H.M. Faisal: (to be published); receipt of a preprint, “A model for dissociation of polyatomic molecules by multiple absorption of photons”, is acknowledged
V.S. Letokhov, A.A. Makarov: Opt. Comm. (to be published)
G. Herzberg: Molecular Spectra and Molecular Structure, Vol. 2, 1st ed. (Van Nostrand, New York 1945) pp 375 and 447
M.F. Goodman, J. Stone: Phys. Rev. A5, 1355 (1972)
J. Stone, E. Thiele, M.F. Goodman: J. Chem. Phys. 59, 2909 (1973)
M.F. Goodman, J. Stone, E. Thiele: J. Chem. Phys. 63, 2929 (1975)
J. Stone, E. Thiele, M.F. Goodman: J. Chem. Phys. 63, 2936 (1975); J. Stone, M.F. Goodman: Phys. Rev. A (in press)
E.J. Heller, S.A. Rice: J. Chem. Phys. 61, 936 (1974)
S. Nordholm, S.A. Rice: J. Chem. Phys. 61, 203 and 768 (1974)
D.S. Frankel, J.I. Steinfeld: J. Chem. Phys. 62, 3358 (1975)
J.I. Steinfeld, I. Burak, D.G. Sutton, A.V. Nowak: J. Chem. Phys. 52, 5421 (1970)
W.E. Lamb, Jr.: paper presented at the Conference on Laser Chemistry, Steamboat Springs, Colorado, February (1976)
See, for example, the following reviews: V.S. Letokhov: Science 180, 451 (1973).
C.B. Moore: Accounts Chem. Res. 6, 323 (1973.
N.V. Karlov: Appl. Opt. 13, 301 (1974).
J.P. Aldridge, J.H. Birely, C.D. Cantrell, D.C. Cartwright: submitted to Physics of Quantum Electronics, Vol. 4 S.F. Jacobs, M. Sargent III, M.O. Scully, C.T. Walker, eds. (Addison-Wesley, Reading); V.S. Letokhov, C.B. Moore: Sov. J. Quant. Electronics 3, 247 and 485 (1976).
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Bloembergen, N., Cantrell, C.D., Larsen, D.M. (1976). Collisionless Dissociation of Polyatomic Molecules by Multiphoton Infrared Absorption. In: Mooradian, A., Jaeger, T., Stokseth, P. (eds) Tunable Lasers and Applications. Springer Series in Optical Sciences, vol 3. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-37996-6_15
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DOI: https://doi.org/10.1007/978-3-540-37996-6_15
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