Skip to main content

Collisionless Dissociation of Polyatomic Molecules by Multiphoton Infrared Absorption

  • Conference paper
Tunable Lasers and Applications

Part of the book series: Springer Series in Optical Sciences ((SSOS,volume 3))

Abstract

During the past year numerous experimental and theoretical investigations have been carried out on the prompt dissociation of several polyatomic molecules by intense CO2 laser pulses. The fact that this dissociation process is isotopically selective [1,2] undoubtedly provided the major impetus for this activity. In this presentation attention will not be focused on the important application of laser isotope separation, but on the physical processes by which a single molecule, without the benefit of collisions, may by exposure to an infrared laser pulse acquire sufficient energy for dissociation to occur.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. R.V. Ambartzumian, V.S. Letokhov, E.A. Ryabov, N.V. Chekalin: JETP Lett. 20, 273 (1974)

    ADS  Google Scholar 

  2. J.L. Lyman, R.J. Jensen, J. Rink, C.P. Robinson, S.D. Rockwood: Appl. Phys. Lett. 27, 87 (1975)

    Article  ADS  Google Scholar 

  3. M.C. Borde, A. Henry, M.L. Henry: C.R. Acad. Sc. (Paris) B262, 1389 (1966)

    Google Scholar 

  4. M.C. Borde, A. Henry, M.L. Henry: C.R. Acad. Sc. (Paris) B263, 619 (1967)

    Google Scholar 

  5. N.V. Karlov, Yu. Petrov, A.M. Prokhorov, D.M. Stel’Markh: JETP Lett. 11, 135 (1970)

    ADS  Google Scholar 

  6. N.K. Isenor, M.C. Richardson: Appl. Phys. Lett. 18, 225 (1971)

    ADS  Google Scholar 

  7. N.K. Isenor, V. Merchant, R.S. Hallsworth, M.C. Richardson: Can. J. Phys. 51, 281 (1973)

    Article  Google Scholar 

  8. E. Yablonovitch: (to be published)

    Google Scholar 

  9. R.V. Ambartzumian, Yu.A. Gorokhov, V.S. Letokhov, G.N. Makarov: ZhETF Pis. Red. 21, 375 (1975) [JETP Lett. 21, 171 (1975)]

    ADS  Google Scholar 

  10. R.V. Ambartzumian, Yu.A. Gorokhov, V.S. Letokhov, G.N. Makarov: ZhETF Pis. Red. 22, 96 and 374 (1975)

    ADS  Google Scholar 

  11. R.V. Ambartzumian: paper presented at the Nordfjord Conference on Tunable Lasers and Applications, June (1976)

    Google Scholar 

  12. L.S. Letokhov: paper presented at the Laser Chemistry Conference, Steamboat Springs, Colorado, February (1976)

    Google Scholar 

  13. S.D. Rockwood: papers presented at Nordfjord Conference on Tunable Lasers and Applications, June (1976) and at the Laser Chemistry Conference, Steamboat Springs, Colorado, February (1976)

    Google Scholar 

  14. A.V. Nowak, J.L. Lyman: J. Quant. Spectrosc. Rad. Transfer 15, 945 (1975)

    Article  ADS  Google Scholar 

  15. J.P. Aldridge, H. Filip, H. Flicker, R.F. Holland, R.S. McDowell, N.G. Nereson, K. Fox: J. Mol. Spectrosc. 58, 165 (1975); R.S. McDowell, H.W. Galbraith, B.J. Krohn, C.D. Cantrell, E.D. Hinkley: Opt. Comm. (to be published); C.D. Cantrell, H.W. Galbraith: J. Mol. Spectrosc. 58, 158 (1975)

    Article  ADS  Google Scholar 

  16. S.A. Alimpiev, N.V. Karlov: ZhETF 6(6, 542 (1974)

    Google Scholar 

  17. S.A. Alimpiev, N.V. Karlov [Sov. Phys.- JETP 39, 260 (1974)]

    ADS  Google Scholar 

  18. see also, I. Burak, J.I. Steinfeld, D.G. Sutton: J. Quant. Spectrosc. Rad. Transfer 9, 959 (1969)

    Article  ADS  Google Scholar 

  19. C.D. Jackson: Los Alamos Scientific Laboratory Report LA-6025-MS-1975

    Google Scholar 

  20. R.J. Glauber: Phus. Rev. 130, 2529 and 131 (1963)

    Article  MathSciNet  ADS  Google Scholar 

  21. R.J. Glauber: Phus. Rev. 131, 2766 (1963)

    Article  MathSciNet  ADS  Google Scholar 

  22. W.H. Louisell: Quantum Statistical Properties of Radiation (John Wiley, New York 1973) p. 205

    Google Scholar 

  23. D.M. Larsen, N. Bloembergen: Opt. Comm. to be published (1976)

    Google Scholar 

  24. C.J. Elliott, B.J. Feldman: Bull. Am. Phys. Soc. 20, 1282 (1975)

    Google Scholar 

  25. S. Mukamel, J. Jortner: (to be published); receipt of a preprint, “A model for isotope separation via molecular multiphoton dissociation”, is acknowledged

    Google Scholar 

  26. N. Bloembergen: Opt. Comm. 15, 416 (1975)

    Article  ADS  Google Scholar 

  27. R.V. Ambartzumian, Yu.A. Gorokhov, V.S. Letokhov, G.B. Makarov, A.A. Puretzky: ZhETF Pis. Red. 23, January (1976)

    Google Scholar 

  28. Private communications by P.L. Kelley, R.V. Khokhlov, V. Platonenko

    Google Scholar 

  29. F.H.M. Faisal: (to be published); receipt of a preprint, “A model for dissociation of polyatomic molecules by multiple absorption of photons”, is acknowledged

    Google Scholar 

  30. V.S. Letokhov, A.A. Makarov: Opt. Comm. (to be published)

    Google Scholar 

  31. G. Herzberg: Molecular Spectra and Molecular Structure, Vol. 2, 1st ed. (Van Nostrand, New York 1945) pp 375 and 447

    Google Scholar 

  32. M.F. Goodman, J. Stone: Phys. Rev. A5, 1355 (1972)

    Article  ADS  Google Scholar 

  33. J. Stone, E. Thiele, M.F. Goodman: J. Chem. Phys. 59, 2909 (1973)

    Article  ADS  Google Scholar 

  34. M.F. Goodman, J. Stone, E. Thiele: J. Chem. Phys. 63, 2929 (1975)

    Article  ADS  Google Scholar 

  35. J. Stone, E. Thiele, M.F. Goodman: J. Chem. Phys. 63, 2936 (1975); J. Stone, M.F. Goodman: Phys. Rev. A (in press)

    Article  ADS  Google Scholar 

  36. E.J. Heller, S.A. Rice: J. Chem. Phys. 61, 936 (1974)

    Article  ADS  Google Scholar 

  37. S. Nordholm, S.A. Rice: J. Chem. Phys. 61, 203 and 768 (1974)

    Article  ADS  Google Scholar 

  38. D.S. Frankel, J.I. Steinfeld: J. Chem. Phys. 62, 3358 (1975)

    Article  ADS  Google Scholar 

  39. J.I. Steinfeld, I. Burak, D.G. Sutton, A.V. Nowak: J. Chem. Phys. 52, 5421 (1970)

    Article  ADS  Google Scholar 

  40. W.E. Lamb, Jr.: paper presented at the Conference on Laser Chemistry, Steamboat Springs, Colorado, February (1976)

    Google Scholar 

  41. See, for example, the following reviews: V.S. Letokhov: Science 180, 451 (1973).

    Article  ADS  Google Scholar 

  42. C.B. Moore: Accounts Chem. Res. 6, 323 (1973.

    Article  Google Scholar 

  43. N.V. Karlov: Appl. Opt. 13, 301 (1974).

    Article  ADS  Google Scholar 

  44. J.P. Aldridge, J.H. Birely, C.D. Cantrell, D.C. Cartwright: submitted to Physics of Quantum Electronics, Vol. 4 S.F. Jacobs, M. Sargent III, M.O. Scully, C.T. Walker, eds. (Addison-Wesley, Reading); V.S. Letokhov, C.B. Moore: Sov. J. Quant. Electronics 3, 247 and 485 (1976).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1976 Springer-Verlag Berlin Heidelberg

About this paper

Cite this paper

Bloembergen, N., Cantrell, C.D., Larsen, D.M. (1976). Collisionless Dissociation of Polyatomic Molecules by Multiphoton Infrared Absorption. In: Mooradian, A., Jaeger, T., Stokseth, P. (eds) Tunable Lasers and Applications. Springer Series in Optical Sciences, vol 3. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-37996-6_15

Download citation

  • DOI: https://doi.org/10.1007/978-3-540-37996-6_15

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-662-13481-8

  • Online ISBN: 978-3-540-37996-6

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics