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Raman Scattering in Amorphous Semiconductors

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Light Scattering in Solids

Part of the book series: Topics in Applied Physics ((TAP,volume 8))

Abstract

Much of the study of Raman scattering in crystalline materials focuses on the few allowed single phonon processes. The corresponding interest in amorphous materials is on the breakdown of selection rules and the broad range of allowed scattering processes. Because of the absence of a well defined crystal momentum, a larger wealth of information about vibrational spectra can be extracted from Raman scattering in amorphous materials. In this chapter we shall be concerned with the experimental and theoretical results obtained from the prototypical elemental and compound amorphous semiconductors and how those results have been used to elucidate the vibrational levels and structure of the amorphous state. The structural results are both supplementary and complementary to information obtainable by the traditional structural analysis techniques of X-ray, electron and neutron diffraction.

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References

  1. N. F. Mott, E. A. Davis: Electronic Processes in Non-Crystalline Materials (Oxford University Press, London, 1971).

    Google Scholar 

  2. J. Stuke, W. Brennig (Eds.): Proc. 5th Intern. Conf. Liquid and Amorphous Semiconductors, Garmisch, 1973 (Taylor and Francis, London, 1974).

    Google Scholar 

  3. J.M. Ziman: J. Phys. C2, 1704 (1969).

    ADS  Google Scholar 

  4. R.J. Bell: Rep. Progr. Phys. 35, 1315 (1972).

    ADS  Google Scholar 

  5. P. Dean: Rev. Mod. Phys. 44, 127 (1972).

    ADS  Google Scholar 

  6. J. Wong, C.A. Angell: Appl. Spectrosc. Rev. 4, 155 (1971) and references therein.

    ADS  Google Scholar 

  7. M. Hass: J. Phys. Chem. Solids 31, 415 (1970).

    ADS  Google Scholar 

  8. W.B. Grant, H. Schulz, S. Hüfner, J. Pelzl: Phys. Stat. Sol. (b), 60, 331 (1973) and references therein.

    ADS  Google Scholar 

  9. M. Balkanski (Ed.): Proc. 2nd Intern. Conf. Light Scattering in Solids, Paris, 1971 (Flammarion, Paris, 1971), Chapter IV.

    Google Scholar 

  10. P. Chaudari, J. Cuomo, R.J. Gambino: Appl. Phys. Letters 22, 337 (1973).

    ADS  Google Scholar 

  11. H. O. Hooper, A. M. de Graaf (Eds.): Amorphous Magnetism (Plenum, New York, 1973).

    Google Scholar 

  12. A.L. Robinson: Science 182, 908 (1973).

    ADS  Google Scholar 

  13. G. Lucovsky: In Proc. 5th Intern. Conf. Liquid and Amorphous Semiconductors, Garmisch, 1973 (Taylor and Francis, London, 1974), p. 1099.

    Google Scholar 

  14. H. Böttger: Phys. Stat. Sol. (b) 62, 9 (1974).

    ADS  Google Scholar 

  15. R. Shuker, R. Gamon: Phys. Rev. Letters 25, 222 (1970).

    ADS  Google Scholar 

  16. R. Shuker, R.W. Gamon: In Proc. 2nd Intern. Conf Light Scattering in Solids, Paris, 1971 (Flammarion Sciences, Paris, 1971), p. 334.

    Google Scholar 

  17. M.H. Brodsky, S. Kirkpatrick, D. Weaire (Eds.): Proc. Intern. Tetrahedrally Bonded Amorphous Semiconductors (American Institute of Physics, New York, 1974).

    Google Scholar 

  18. M.H. Brodsky: J. Vac. Sci. Technol. 8, 125 (1971).

    ADS  Google Scholar 

  19. S.C. Moss, D. Adler: Comments in Solid State Phys. 5, 47 (1973).

    Google Scholar 

  20. J.E. Smith, Jr., M.H. Brodsky, B.L. Crowder, M.I. Nathan, A. Pinczuk: Phys. Rev. Letters 26, 642 (1971).

    ADS  Google Scholar 

  21. R. Alben, J.E. Smith, Jr., M.H. Brodsky, D. Weaire: Phys. Rev. Letters 30, 1141 (1973).

    ADS  Google Scholar 

  22. M. Wihl, M. Cardona, J. Tauc: J. Non-Cryst. Solids 8–10, 172 (1972).

    ADS  Google Scholar 

  23. J.E. Smith, Jr., M.H. Brodsky, B.L. Crowder, M.I. Nathan: In Proc. 2nd. Intern. Conf. Light Scattering in Solids, Paris, 1971 (Flammarion, Paris, 1971), p. 330.

    Google Scholar 

  24. G. Dolling, R.A. Cowley: Proc. Phys. Soc, London 88, 463 (1966).

    ADS  Google Scholar 

  25. R.W. Stimets, J. Waldman, J. Lin, T.S. Chang, R.J. Temkin, G.A.N. Connell: Sol. Stat. Comm. 13, 1485 (1973).

    ADS  Google Scholar 

  26. W. Prettl, N.J. Shevchik, M. Cardona: Phys. Stat. Sol. (b) 59, 241 (1973).

    ADS  Google Scholar 

  27. M.H. Brodsky, A. Lurio: Phys. Rev. B9. 1646 (1974).

    ADS  Google Scholar 

  28. F.R. Ladan, A. Zylbersztejn: Phys. Rev. Letters 28, 1198 (1972).

    ADS  Google Scholar 

  29. B. Schröder: In Proc. Intern. Conf. Tetrahedrally Bonded Amorphous Semiconductors, Yorktown, 1974 (American Institute of Physics, New York, 1974), p. 114.

    Google Scholar 

  30. J.D. Axe, D.T. Keating, G.S. Cargill, III, R. Alben: In Proc. Intern. Conf. Tetrahedrally Bonded Amorphous Semiconductors, Yorktown, 1974 (American Institute of Physics, New York, 1974), p. 279.

    Google Scholar 

  31. J.S. Lannin: Sol. Stat. Comm. 11, 1523 (1972).

    ADS  Google Scholar 

  32. J.S. Lannin: Sol. Stat. Comm. 12, 947 (1973).

    ADS  Google Scholar 

  33. J. S. Lannin: In Proc. 5th Intern. Conf. Amorphous and Liquid Semiconductors, Garmisch, 1973 (Taylor and Francis, London, 1974), p. 1245.

    Google Scholar 

  34. A.J. Martin, W. Brenig: Phys. Stat. Sol. (b) 64, 163 (1974).

    ADS  Google Scholar 

  35. L. von Heimendahl: In Proc. Intern. Conf Tetrahedrally Bonded Amorphous Semiconductors, Yorktown, 1974 (American Institute of Physics, New York, 1974), p. 274.

    Google Scholar 

  36. G. A.N. Connell: Phys. Stat. Solidi (b) 69, 9 (1975).

    ADS  Google Scholar 

  37. C.N. King, W.A. Phillips, J.P. de Neufville: Phys. Rev. Letters 32, 538 (1974).

    ADS  Google Scholar 

  38. P. Flubacher, A.J. Leadbetter, J.A. Morrison, B.P. Stoicheff: J. Phys. Chem. Solids 12, 53 (1959).

    ADS  Google Scholar 

  39. A. S. Barker: In Far Infrared Properties of Solids, ed. by S. S. Mitra and S. Nudelman (Plenum Press, New York, 1970), p. 247.

    Google Scholar 

  40. R. Shuker, R. Gamon: Phys. Lett. 33A, 96 (1970).

    Google Scholar 

  41. B.L. Crowder, J.E. Smith, Jr., M.H. Brodsky, M.I. Nathan: In Proc. Second Intern. Conf Ion Implantation, Garmisch (1971), p. 255.

    Google Scholar 

  42. J. E. Smith, Jr., M. H. Brodsky, B. L. Crowder, M. I. Nathan: J. Non-Cryst. Solids 8–10, 179 (1972).

    ADS  Google Scholar 

  43. J. C. Bourgoin, J. F. Morhange, R. Beserman: Rad. Effects 22, 205 (1974).

    Google Scholar 

  44. M. H. Brodsky, R. S. Title: Phys. Rev. Letters 23, 581 (1969).

    ADS  Google Scholar 

  45. R. S. Title, M. H. Brodsky, B. L. Crowder: In Proc. 10th Intern. Conf. Physics of Semiconductors, Cambridge, Mass., 1970 (U. S. Atomic Energy Comm., Oak Ridge, 1970). p. 794.

    Google Scholar 

  46. W. Beyer, J. Stuke: In Proc. 5th Intern. Conf. Amorphous and Liquid Semiconductors, Garmisch, 1973 (Taylor and Francis, London, 1974), p. 251.

    Google Scholar 

  47. M. H. Brodsky, R. J. Gambino, J. E. Smith, Jr., Y. Yacoby: Phys. Stat. Sol. (b) 52, 609 (1972).

    ADS  Google Scholar 

  48. E. Finkman, A. P. Defonzo, J. Tauc: In Proc. 12th Intern. Conf. on the Physics of Semiconductors, Stuttgart (1974), p. 1022.

    Google Scholar 

  49. A. Solin, R. J. Kobliska: In Proc. 15th Inter. Conf. Liquid and Amorphous Semiconductors, Garmisch, 1973 (Taylor and Francis, London, 1974), p. 1251.

    Google Scholar 

  50. J. F. Morhange, R. Beserman, J. C. Bourgoin, P. R. Brosius, Y. H. Lee, L. J. Cheng, J. W. Corbett: Proc. Intern. Conf. Ion Implantation, Kyoto (1974)

    Google Scholar 

  51. M. I. Nathan, J. E. Smith, Jr., K. N. Tu: J. Appl. Phys. 45, 2370 (1974).

    ADS  Google Scholar 

  52. R. Alben, D. Weaire, J. E. Smith, Jr., M. H. Brodsky: In Proc. 5th Intern. Conf. Amorphous and Liquid Semiconductors, Garmisch, 1973 (Taylor and Francis, London, 1974), p. 1231.

    Google Scholar 

  53. R. Alben, D. Weaire, J. E. Smith, Jr., M. H. Brodsky: Phys. Rev. B11, 2271 (1975).

    ADS  Google Scholar 

  54. P. N. Keating: Phys. Rev. 145, 637 (1966).

    ADS  Google Scholar 

  55. R. H. Wentorf, Jr., J. S. Kasper: Science 139, 338 (1963).

    ADS  Google Scholar 

  56. M. F. Thorpe: Phys. Rev. B8, 5352 (1973).

    ADS  Google Scholar 

  57. R. Zallen: Phys. Rev. 113, 824 (1968).

    ADS  Google Scholar 

  58. M. F. Thorpe: In Proc. Intern. Conf. Tetrahedrally Bonded Amorphous Semiconductors, Yorktown, 1974 (American Institute of Physics, New York, 1974), p. 267.

    Google Scholar 

  59. M. Born: Ann. Phys. (Leipzig) 44, 605 (1914).

    ADS  Google Scholar 

  60. S. S. Mitra, D. K. Paul, Y. F. Tsay, B. Bendow: In Proc. Intern. Conf. Tetrahedrally Bonded Amorphous Semiconductors, Yorktown, 1974 (American Institute of Physics, New York, 1974), p. 284.

    Google Scholar 

  61. D. Weaire, R. Alben: Phys. Rev. Lett. 29, 1505 (1972).

    ADS  Google Scholar 

  62. D. Weaire, M. F. Thorpe: Phys. Rev. B4, 2508 (1971).

    ADS  Google Scholar 

  63. M. F. Thorpe, D. Weaire, R. Alben: Phys. Rev. B7, 3777 (1972).

    ADS  Google Scholar 

  64. R. Alben, D. Weaire, P. Steinhardt: J. Phys. C6, L384 (1973).

    ADS  Google Scholar 

  65. R. Alben: In Proc. Intern. Conf. Tetrahedrally Bonded Amorphous Semiconductors, Yorktown, 1974 (American Institute of Physics, New York, 1974), p. 249.

    Google Scholar 

  66. G. A. N. Connell: In Proc. 12th Intern. Conf. Physics of Semiconductors, Stuttgart (1974), p. 1003.

    Google Scholar 

  67. J. S. Lannin: In Proc. Intern. Conf. Tetrahedrally Bonded Amorphous Semiconductors, Yorktown, 1974 (American Institute of Physics, New York, 1974), p. 260.

    Google Scholar 

  68. M. Gorman, S. A. Solin: Solid State Comm. 15, 761 (1974).

    ADS  Google Scholar 

  69. N. J. Shevchik, J. S. Lannin, J. Tejeda: Phys. Rev. B7, 3987 (1973).

    ADS  Google Scholar 

  70. J. Mort: In Proc. 5th Intern. Conf. Amorphous and Liquid Semiconductors, Garmisch, 1973 (Taylor and Francis, London, 1974), p. 1361.

    Google Scholar 

  71. A. R. Hilton: Appl. Optics 5, 1877 (1966).

    ADS  Google Scholar 

  72. S. R. Ovshinsky: J. Non-Cryst. Solids 2, 99 (1970).

    ADS  Google Scholar 

  73. G. Lucovsky, R. M. Martin: J. Non-Cryst. Solids 8–10, 185 (1972).

    ADS  Google Scholar 

  74. G. Lucovsky, R. M. White: Phys. Rev. B8, 660 (1973).

    ADS  Google Scholar 

  75. G. Lucovsky, R. M. Martin: To be published.

    Google Scholar 

  76. J. E. Smith, Jr., M. H. Brodsky, R. J. Gambino: Bull. Am. Phys. Soc. II 17, 336 (1972).

    Google Scholar 

  77. A. T. Ward: J. Phys. Chem. 72, 4133 (1968).

    Google Scholar 

  78. I. Srb, A. Vasko: Czech. J. Phys. B 13, 827 (1963).

    ADS  Google Scholar 

  79. A. Anderson, Y. T. Loh: Canad. J. Chem. 44, 879 (1969).

    Google Scholar 

  80. R. Zallen: Phys. Rev. B9, 4485 (1974).

    ADS  Google Scholar 

  81. H. Gerding, R. Westrik: Recueil Trav. Chim. Pays-Bas 62, 68 (1943).

    Google Scholar 

  82. G. Lucovsky, A. Mooradian, W. Taylor, G. B. Wright, R. C. Keezer: Solid State Comm. 5, 113 (1967).

    ADS  Google Scholar 

  83. G. Lucovsky: In Physics of Selenium and Tellurium, ed. by W. C. Cooper (Pergamon Press, Oxford, 1964), p. 255.

    Google Scholar 

  84. A. Mooradian, G. B. Wright: In Physics of Selenium and Tellurium, ed. by W. C. Cooper (Pergamon Press, Oxford, 1969), p. 169.

    Google Scholar 

  85. J. Schottmiller, M. Tabak, G. Lucovsky, A. Ward: J. Non-Cryst. Solids 4, 80 (1970).

    ADS  Google Scholar 

  86. G. Brielieb: Z. Phys. Chem. A144, 321 (1929).

    Google Scholar 

  87. A. Eisenberg, A. V. Tobalsky: J. Polym. Sci. 46, 19 (1960).

    ADS  Google Scholar 

  88. R. M. Martin, G. Lucovsky: In Proc. Ylth Intern. Conf. Physics of Semiconductors, Stuttgart (1974).

    Google Scholar 

  89. N. B. Zakharova, Yu. A. Chekasov: Sov. Phys. -Solid State 12, 1572 (1971).

    Google Scholar 

  90. A. S. Pine, G. Dresselhaus: Phys. Rev. B4, 356 (1971).

    ADS  Google Scholar 

  91. R. Zallen, M. L. Slade, A. T. Ward: Phys. Rev. B3, 4257 (1971).

    ADS  Google Scholar 

  92. R. Zallen, M. Slade: Phys. Rev. B9, 1629 (1974).

    ADS  Google Scholar 

  93. I. G. Austin, E. S. Garbett: Phil. Mag. 23, 17 (1971).

    ADS  Google Scholar 

  94. A. T. Ward, M. B. Myers: J. Phys. Chem. 73, 1374 (1969).

    Google Scholar 

  95. G. Lucovsky: Phys. Rev. B6, 1480 (1972).

    ADS  Google Scholar 

  96. R. J. Kobliska, S. A. Solin: Solid State Somm. 10, 231 (1972).

    ADS  Google Scholar 

  97. R. J. Kobliska, S. A. Solin: J. Non-Cryst. Solids 8–10, 91 (1972).

    Google Scholar 

  98. R. J. Kobliska, S. A. Solin: Phys. Rev. B8, 756 (1973).

    ADS  Google Scholar 

  99. Yu. F. Markov, N. B. Reshetnyak: Fiz. Tverd. Tela 14, 1242 (1972), translated Sov. Phys. -Solid State 14, 1063 (1972).

    Google Scholar 

  100. E. Finkman, A. Defonzo, J. Tauc: In Proc. 5th Intern. Conf Amorphous and Liquid Semiconductors, Garmisch, 1973 (Taylor and Francis, London, 1974), p. 1275.

    Google Scholar 

  101. R. O. Pohl, W. F. Love, R. B. Stephens: In Proc. 5th Intern. Conf. Amorphous and Liquid Semiconductors, Garmisch, 1973 (Taylor and Francis, London, 1974), p. 1121.

    Google Scholar 

  102. D. C. Taylor, S. G. Bishop, D. L. Mitchell: Phys. Rev. Letters 27, 414 (1973).

    ADS  Google Scholar 

  103. J. P. de Neufville: In Proc. 5th Intern. Conf. Amorphous and Liquid Semiconductors, Garmisch, 1973 (Taylor and Francis, London, 1974), p. 1351.

    Google Scholar 

  104. G. Lucovsky, J. P. de Neufville, F. L. Galeener: Phys. Rev. B9, 1591 (1974).

    ADS  Google Scholar 

  105. G. Lucovsky, F. L. Galeener, R. C. Keezer, R. H. Geils, H. A. Six: Phys. Rev. B10, 5134(1974).

    ADS  Google Scholar 

  106. P. Tronc, M. Bensoussan, A. Brenac, C. Sebenne: Phys. Rev. B8, 5947 (1973).

    ADS  Google Scholar 

  107. G. B. Fisher, J. Tauc, Y. Verhelle: In Proc. 5th Intern. Conf. Liquid and Amorphous Semiconductors, Garmisch, 1973 (Taylor and Francis, London, 1974), p. 1259.

    Google Scholar 

  108. S. C. Rowland, S. Narasimhan, A. Bienenstock: J. Appl. Phys. 43, 2741 (1972).

    ADS  Google Scholar 

  109. L. Cervinka, A. Hruby: In Proc. 5th Intern. Conf. Liquid and Amorphous Semiconductors, Garmisch, 1973 (Taylor and Francis, London, 1974), p. 431.

    Google Scholar 

  110. R. L. Mozzi, B. E. Warren: J. Appl. Cryst. 2, 164 (1969).

    Google Scholar 

  111. H. Phillip: J. Non-Cryst. Solids 8–10, 627 (1972).

    ADS  Google Scholar 

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Brodsky, M.H. (1975). Raman Scattering in Amorphous Semiconductors. In: Cardona, M. (eds) Light Scattering in Solids. Topics in Applied Physics, vol 8. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-37568-5_5

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  • DOI: https://doi.org/10.1007/978-3-540-37568-5_5

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