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Analytical Performance Characteristics

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Analytical Chemistry
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References

  • AMC (1995) The Analytical Methods Committee: Uncertainty of measurement — implications for its use in analytical science. Analyst 120:2303

    Article  Google Scholar 

  • Arnold SF (1990) Mathematical statistics. Prentice-Hall, Englewood Cliffs, NJ

    Google Scholar 

  • Bergmann G, von Oepen B, Zinn P (1987) Improvement in the definitions of sensitivity and selectivity. Anal Chem 59:2522

    Article  CAS  Google Scholar 

  • Björn E, Frech W, Hoffmann E, Lüdke C (1998) Investigation and quantification of spectroscopic interferences from polyatomic species in inductively coupled plasma mass spectrometry using electrothermal vaporization or pneumatic nebulization for sample introduction. Spectrochim Acta 53B:1766

    Google Scholar 

  • Boumans PWJM (1991) Measuring detection limits in inductively coupled plasma emission spectrometry using the “SBR-RSDB approach” — I. A tutorial discussion of the theory. Spectrochim Acta 46B:431

    CAS  Google Scholar 

  • Boumans PWJM (1994) Detection limits and spectral interferences in atomic emission spectrometry. Anal Chem 66:459A

    CAS  Google Scholar 

  • Burns DT, Danzer K, Townshend A (2005) IUPAC, Analytical Chemistry Division: Use of the terms “Robust” and “Rugged” and the associated characteristics of “Robustness” and “Ruggedness” in descriptions of analytical procedures. Draft 2005

    Google Scholar 

  • Currie LA (1992) In pursuit of accuracy: nomenclature, assumtions, and standards. Pure Appl Chem 64:455

    CAS  Google Scholar 

  • Currie LA (1995) IUPAC, Analytical Chemistry Division, Commission on Analytical Nomenclature: Nomenclature in evaluation of analytical methods including detection and quantification capabilities. Pure Appl Chem 67:1699

    CAS  Google Scholar 

  • Currie LA (1997) Detection: International update, and some emerging dilemmas involving calibration, the blank, and multiple detection decisions. Chemometrics Intell Lab Syst 37:151

    Article  CAS  Google Scholar 

  • Danzer K (1975) Zur Ermittlung der Informationsmenge bei spektrochemischen Analysenverfahren. Z Chem 15:158

    CAS  Google Scholar 

  • Danzer K (1990) Problems of calibration in trace-, in-situ-micro-, and surface analysis. Fresenius J Anal Chem 337:794

    Article  CAS  Google Scholar 

  • Danzer K (2001) Selectivity and specificity in analytical chemistry. General considerations and attempt of a definition and quantification. Fresenius J Anal Chem 369:397

    Article  CAS  Google Scholar 

  • Danzer K (2004) A closer look at analytical signals. Anal Bioanal Chem 380:376

    Article  CAS  Google Scholar 

  • Danzer K, Fischbacher C, Jagemann K-U, Reichelt KJ (1998) Near-infrared diffuse reflection spectroscopy for non-invasive blood-glucose monitoring. LEOS Newsletter 12:2–9

    Google Scholar 

  • Danzer K, Schubert M, Liebich V (1991) Information theory in analytical chemistry. III. Distribution-analytical investigations. Fresenius J Anal Chem 341:511

    Article  CAS  Google Scholar 

  • Danzer K, Than E, Molch D, Küchler L (1987) Analytik — Systematischer Überblick, 2nd edn. Akademische Verlagsgesellschaft Geest & Portig, Leipzig/Wissenschaftliche Verlagsgesellschaft, Stuttgart

    Google Scholar 

  • Danzer K, Wagner M (1993) Multisignal calibration in optical emission spectroscopy. Fresenius J Anal Chem 346:520

    Article  CAS  Google Scholar 

  • Danzer K, Venth K (1994) Multisignal calibration in spark-and ICP-OES. Fresenius J Anal Chem 350:339

    Article  CAS  Google Scholar 

  • Davies OL, Goldsmith PL (1984) Statistical methods in research and production. Longman, London

    Google Scholar 

  • De la Calle García D, Reichenbächer M, Danzer K, Hurlbeck C, Bartzsch C, Feller K-H (1998) Use of solid-phase microextraction capillary gas chromatography (SPME-CGC) for the varietal characterization of wines by means of chemometrical methods. Fresenius J Anal Chem 360:784

    Article  Google Scholar 

  • den Boef G, Hulanicki A (1983) IUPAC, Analytical Chemistry Division, Commission on Analytical Reactions and Reagents: Recommendations for the usage of selective, selectivity and related terms in analytical chemistry. Pure Appl Chem 55:553

    Google Scholar 

  • Doerffel K (1990) Statistik in der analytischen Chemie. Deutscher Verlag für Grundstof findustrie, Leipzig

    Google Scholar 

  • Doerffel K, Müller H, Ullmann M (1986) Prozessanalytik. Deutscher Verlag für Grundstof findustrie, Leipzig

    Google Scholar 

  • Doerffel K, Eckschlager K, Henrion G (1990) Chemometrische Strategien in der Analytik. Deutscher Verlag für Grundstoffindustrie, Leipzig

    Google Scholar 

  • Eckschlager K, Danzer K (1994) Information theory in analytical chemistry. Wiley, New York

    Google Scholar 

  • Ehrlich G (1969) Entwicklung und gegenwärtiger Stand der Bemühungen um eine objektive Charakterisierung des Nachweisvermögens analytischer Verfahren. Wiss Z TH Leuna-Merseburg 11:22

    Google Scholar 

  • Ehrlich G, Danzer K (2006) Nachweisvermögen von Analysenverfahren. Objektive Bewertung und Ergebnisinterpretation. Springer, Berlin Heidelberg New York

    Google Scholar 

  • EURACHEM (1995) Quantifying uncertainty in analytical measurement. Teddington

    Google Scholar 

  • EURACHEM (1998) The fitness for purpose of analytical methods. Teddington

    Google Scholar 

  • Fleming J, Albus H, Neidhart B, Wegscheider W (1997a) Glossary of analytical terms (VII). Accr Qual Assur 2:51

    Article  Google Scholar 

  • Fleming J, Albus H, Neidhart B, Wegscheider W (1997b) Glossary of analytical terms (VIII). Accr Qual Assur 2:160

    Article  Google Scholar 

  • Fleming J, Neidhart B, Tausch C, Wegscheider W (1996a) Glossary of analytical terms (I). Accr Qual Assur 1:41

    Article  Google Scholar 

  • Fleming J, Albus H, Neidhart B, Wegscheider W (1996b) Glossary of analytical terms (II). Accr Qual Assur 1:87

    Article  Google Scholar 

  • Fleming J, Neidhart B, Albus H, Wegscheider W (1996c) Glossary of analytical terms (III). Accr Qual Assur 1:135

    Article  Google Scholar 

  • Fujiwara K, McHard JA, Foulk SJ, Bayer S, Winefordner JD (1980) Evaluation of selectivity in atomic absorption and atomic emission spectrometry. Canadian J Spectrosc 25:18

    CAS  Google Scholar 

  • Geiß S, Einax JW (2001) Comparison of detection limits in environmental analysis — is it possible? An approach on quality assurance in the lower working range by verification. Fresenius J Anal Chem 370:673

    Article  Google Scholar 

  • Gottschalk G (1975) Standardisierung quantitativer Analysenverfahren — I. Allgemeine Grundlagen. Fresenius Z Anal Chem 275:1

    Article  CAS  Google Scholar 

  • Graf U, Henning H-U, Stange K, Wilrich P-Th (1987) Formeln und Tabellen der angewandten mathematischen Statistik. Springer, Berlin Heidelberg New York (3. Aufl)

    Google Scholar 

  • Hendricks MMWB, de Boer AH, Smilde AK (1996) Robustness of analytical chemical methods and pharmaceutical technological products. Elsevier, Amsterdam

    Google Scholar 

  • Horn R (2000) Kopplung einer elektrothermischen Verdampfungseinheit mit einem ICP-Massenspektrometer zur Verbesserung der Nachweisgrenze und der Spezifität. Diploma Thesis, Friedrich Schiller University of Jena

    Google Scholar 

  • Horwitz W, Kamps LR, Boyer KW (1980) Quality assurance in the analysis of foods for trace constituents. J Assoc Off Anal Chem 63:1344

    CAS  Google Scholar 

  • Huber PJ (1981) Robust statistics. Wiley, New York

    Book  Google Scholar 

  • ICH (1994) ICH Topic Q2A (ICH Harmonised Tripartite Guideline): Validation of analytical methods: Definitions and terminology (CPMP/ICH/381/95), ICH, London

    Google Scholar 

  • ICH (1996) ICH Topic Q2B (ICH Harmonised Tripartite Guideline): Validation of analytical methods: Methodology (CPMP/ICH/281/95), ICH, London

    Google Scholar 

  • Inczédy J, Lengyiel JT, Ure AM, Geleneser A, Hulanicki A (Eds) (1997) Compendium of analytical nomenclature, 3rd edn (IUPAC Orange Book), Blackwell, Oxford

    Google Scholar 

  • ISO 3534-1 (1993), International Organization for Standardization (BIPM, IEC, IFCC, ISO, IUPAC, IUPAP, OIML), International vocabulary of basis and general terms in metrology. Geneva

    Google Scholar 

  • ISO 78-2 (1999) International Organisation for Standarization: Layout for standards — 2. Methods of chemical analysis. Geneva

    Google Scholar 

  • IUPAC Orange Book (1997, 2000) — printed version: Compendium of analytical nomenclature (Definitive Rules 1997); see Inczédy et al. (1997) — web version (from 2000 on): www.iupac.org/publications/analytical compendium/

    Google Scholar 

  • IUPAC (1995) Analytical Chemistry Division, Commission on Analytical Nomenclature: Nomenclature in evaluation of analytical methods including detection and quantification capabilities, prepared for publication by LA Currie, Pure Appl Chem 67:1699

    Google Scholar 

  • Jochum C, Jochum P, Kowalski BR (1981) Error propagation and optimal performance in multicomponent analysis. Anal Chem 53:85

    CAS  Google Scholar 

  • Kaiser H (1965) Zum Problem Nachweisgrenze. Fresenius Z Anal Chem 209:1

    Article  CAS  Google Scholar 

  • Kaiser H (1966) Zur Definition der Nachweisgrenze, der Garantiegrenze und der dabei benutzten Begriffe. Fresenius Z Anal Chem 216:80

    Article  CAS  Google Scholar 

  • Kaiser H (1970) Quantitation in elemental analysis. Part I. Anal Chem 42(2):24A, Part II. 42(4):26A

    CAS  Google Scholar 

  • Kaiser H (1972) Zur Definition von Selektivität, Spezifität und Empfindlichkeit von Analysenverfahren. Fresenius Z Anal Chem 260:252

    Article  CAS  Google Scholar 

  • Kaiser H, Specker H (1956) Bewertung und Vergleich von Analysenverfahren. Fresenius Z Anal Chem 149:46

    Article  CAS  Google Scholar 

  • Kateman G, Buydens L (1993) Quality control in analytical chemistry, 2nd edn. Wiley, New York

    Google Scholar 

  • Kellner R, Mermet J-M, Otto M, Widmer HM (eds) (1998) Analytical chemistry. Wiley-VCH, Weinheim

    Google Scholar 

  • Lieck G (1998) Nachweisgrenze und Rauschen. LaborPraxis 22/June:62

    Google Scholar 

  • Long GL, Winefordner JD (1983) Limit of detection. A closer look at the IUPAC Definition. Anal Chem 55:712A

    CAS  Google Scholar 

  • Massart DL, Vandeginste BGM, Deming SN, Michotte Y, Kaufman L (1988) Chemometrics: a textbook. Elsevier, Amsterdam

    Google Scholar 

  • O’Rangers JJ, Condon RJ (2000) In: Kay JP, MacNeil JD, O’Rangers JJ (eds), Current issues in regulatory chemistry. (AOAC Int., Gaithersburg, MD, p 207

    Google Scholar 

  • Persson B-A, Vessman J (1998) Generating selectivity in analytical chemistry to reach the ultimate — specifity. Trends Anal Chem 17:117

    Article  CAS  Google Scholar 

  • Persson B-A, Vessman J (2001) The use of selectivity in analytical chemistry — some considerations. Trends Anal Chem 20:526

    Article  CAS  Google Scholar 

  • Prichard E, Green J, Houlgate P, Miller J, Newman E, Phillips G, Rowley A (2001) Analytical measurement terminology — handbook of terms used in quality assurance of analytical measurement. LGC, Teddington, Royal Society of Chemistry, Cambridge

    Google Scholar 

  • Rodriguez LC, Garcia RB, Garcia Campana AM, Bosque Sendra JM (1998) A new approach to a complete robustness test of experimental nominal conditions of chemical testing procedures for internal analytical quality assessment. Chemom Intell Lab Syst 41:57

    Article  CAS  Google Scholar 

  • Sachs L (1992) Angewandte Statistik, 7th edn. Springer, Berlin Heidelberg New York [1383]

    Google Scholar 

  • Sharaf MA, Illman DL, Kowalski BR (1986) Chemometrics. Wiley, New York

    Google Scholar 

  • St John PA, McCarthy WJ, Winefordner JD (1966) Application of signal-to-noise theory in molecular luminescence spectrometry. Anal Chem 38:1828

    Article  CAS  Google Scholar 

  • St John PA, McCarthy WJ, Winefordner JD (1967) A statistical method for evaluation of limiting detectable sample concentrations. Anal Chem 39:1495

    Article  CAS  Google Scholar 

  • Streck S (2004) Die schnelle und effiziente analytische Bestimmung von Mengen-, Spuren-und Ultraspurenelementen im Blutplasma von Patienten mit unterschiedlichen Erkrankungen und der statistische Vergleich mit einer Kontrollgruppe. Doctoral thesis, Friedrich Schiller University of Jena

    Google Scholar 

  • Sturgeon RE, Lam JW (1999) The ETV as a thermochemical reactor for ICP-MS sample introduction. J Anal Atomic Spectrom 14:785

    Article  CAS  Google Scholar 

  • Taylor JK [1983] Validation of analytical methods. Anal Chem 55:600A

    CAS  Google Scholar 

  • Thiel G, Danzer K (1997) Direct analysis of mineral components in wine by inductively coupled plasma optical emission spectrometry (ICP-OES). Fresenius J Anal Chem 357:553

    Article  CAS  Google Scholar 

  • Thompson M (1995) Uncertainty in an uncertain world. Analyst 120:117N

    Article  CAS  Google Scholar 

  • Thompson M, Statistical Subcommittee of the Analytical Method Committee (2004) The amazing Horwitz function. AMC Techn Brief 17

    Google Scholar 

  • Trullols E, Ruisanchez I, Rius FX (2004) Validation of qualitative analytical methods. Trends Anal Chem 23:137

    Article  CAS  Google Scholar 

  • USP 23-NF18 (1995) The US pharmacopoeia & the national formulary. US Pharmacopeial Convention Inc, Rockville, MD

    Google Scholar 

  • USP 24-NF19 (2000) The US pharmacopoeia & the national formulary. US Pharmacopeial Convention Inc, Rockville, MD

    Google Scholar 

  • Valcarcel M (2000) Principles of analytical chemistry. Springer, Berlin Heidelberg New York

    Google Scholar 

  • Venth K, Danzer K, Kundermann G, Blaufuß K-H (1996) Multisignal evaluation in ICPMS. Determination of trace elements in Mo-Zr-alloys. Fresenius J Anal Chem 354:811

    CAS  Google Scholar 

  • Vessman J, Stefan RI, van Staden JF, Danzer K, Lindner W, Burns DT, Fajgelj A, Müller H (2001) IUPAC, Analytical Chemistry Division, Commission on General Aspects of Analytical Chemistry: Selectivity in analytical chemistry. Pure Appl Chem 73:1381

    CAS  Google Scholar 

  • Wahlich JC, Carr GP (1990) Chromatographic system suitability tests — what should we be using? J Pharmac Biomed Anal 8:619

    Article  CAS  Google Scholar 

  • Wildner H, Wünsch G (1997) Neue Ansätze zur Quantifizierung der Robustheit als Güutekennzahl analytischer Systeme im Hinblick auf Bewertbarkeit und Vergleichbarkeit. J prakt Chem 339:107

    Article  CAS  Google Scholar 

  • Winefordner JD, Vickers TJ (1964) Calculation of limit of detectability in atomic absorption flame spectrometry. Anal Chem 36:1947

    Article  CAS  Google Scholar 

  • Winefordner JD, Parsons ML, Mansfield JM, McCarthy WJ (1967) Derivation of expressions for calculation of limiting detectable atomic concentration in atomic fluorescence flame spectrometry. Anal Chem 39:436

    Article  CAS  Google Scholar 

  • Wünsch G (1994) Robustheit und Anfälligkeit als Kenngrößen zur Bewertung analytischer Systeme. J Prakt Chem 339:107

    Google Scholar 

  • Zeaiter M, Roger J-M, Bellon-Maurel V, Rutledge DN (2004) Robustness of models developed by multivariate calibration. Part I. The assessment of robustness. Trends Anal Chem 23:157

    Article  CAS  Google Scholar 

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(2007). Analytical Performance Characteristics. In: Analytical Chemistry. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-35990-6_7

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