Zusammenfassung
pro memoria:
Ein Katalysator erhöht die Geschwindigkeit einer thermodynamisch möglichen Reaktion durch Eröffnung eines Weges niedriger Aktivierungsenergie. Existieren mehrere Reaktionswege, so kann ein Katalysator erhöhte Produktspezifität bewirken, indem er nur eine der konkurrierenden Reaktionsfolgen beschleunigt.
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Literatur
C.A.TOLMAN, Chem. Soc. Rev. 1 (1972) 337
The 16 and 18 Electron Rule in Organometallic Chemistry and Homogeneous Catalysis
F.R.HARTLEY, Reidel, Dordrecht (1985)
Supported Metal Complexes. A New Generation of Catalysts
J.K.KOCHI, Academic Press, New York (1978)
Organometallic Mechanisms and Catalysis
J.K.KOCHI, J. Organomet. Chem. 300 (1986) 139
Electron Transfer and Transient Radicals in Organometallic Chemistry
D.ASTRUC, Angew. Chem. 100 (1988) 662
Elektrokatalyse in der Organoübergangsmetallchemie
K.C.BISHOP III, Chem. Rev. 76 (1976) 461
Transition Metal Catalysed Rearrangements of Small Ring Organic Molecules
G.W.PARSHALL, J. Mol. Catal. 4 (1978) 243
Industrial Applications of Homogeneous Catalysis. A Review
C.MASTERS, Chapman and Hall, London (1981) Homogeneous Transition-Metal Catalysis - a Gentle Art
J.FALBE, H.BAHRMANN, Chem. Unserer Zeit 15 (1981) 37 Homogene Katalyse in der Technik
F.G.A STONE, R.WEST, Eds., Adv. Organomet. Chem. 17 (1979) 1-492
Catalysis and Organic Synthesis
J.F.WALLER, J. Mol. Catal. 31 (1985) 123
Recent Achievements, Trends and Prospects in Homogeneous Catalysis
C.P.CASEY, Ed., J. Chem. Ed. 63 (1986) 188
Symposium: Industrial Applications of Organometallic Chemistry and Catalysis
R.F.HECK, Acc. Chem. Res. 12 (1979) 146 Palladium-Catalysed Reactions of Organic Halides with Olefins
J.-L. HERRISON, Y.CHAUVIN, Makromol. Chem. 141 (1970) 161 Catalyse de transformation des Oléfines par les Complexes de tungstène
T.J.KATZ, Adv. Organomet. Chem. 16 (1977) 283 The Olefin Metathesis Reaction
R.H.GRUBBS, Comprehensive Organometallic Chemistry 8 (1982) 499 Alkene and Alkyne Metathesis Reactions
R.R.SCHROCK, J. Organomet. Chem. 300 ( 1986) 249 On the Trail of Metathesis Catalysts
P.W.JOLLY, G.WILKE, Academic Press, New York (1974, 1975 ) The Organic Chemistry of Nickel, Vol. 1, 2
H.SINN, W.KAMINSKY, Adv. Organomet. Chem. 18 (1980) 99 Ziegler-Natta Catalysis
R.F.JORDAN, J. Chem. Ed. 65 (1988) 285
Cationic Metal-Alkyl Olefin Polymerisation Catalysts
J.E.BÄCKVALL, B.AKERMARK, S.O.LJUNGGREN, J. Am. Chem. Soc. 101 (1979) 2411
Stereochemistry and Mechanism for the Palladium(II)-Catalysed Oxidation of Ethene in Water (the WACKER-Process)
J.E.BÄCKVALL, Acc. Chem. Res. 16 (1983) 335
Palladium in some Selective Oxidation Reactions
H.BRUNNER, Chem. Unserer Zeit 14 (1980) 177 Asymmetrische Katalyse mit Rhodium-Phosphan-Komplexen
W.S.KNOWLES, Acc. Chem. Res. 16 (1983) 106
Asymmetric Hydrogenation
B.S.BOSNICH, Topics Stereochem. 12 (1981) 119
Asymmetric Synthesis Mediated by Transition Metal Complexes
B.BOSNICH, Chem. Br. 20 (1984) 808
Asymmetric Catalysis
H.BRUNNER, J. Organomet. Chem. 300 (1986) 39
Enantioselective Catalysis with Transition Metal Complexes
R.NOYORI, Science 248 (1990) 1194
Chiral Metal Complexes as Discriminating Molecular Catalysts
M.NOGRADI, VCH, Weinheim (1987)
Stereoselective Synthesis
E.L.MUETTERTIES, J.STEIN, Chem. Rev. 79 (1979) 479
Mechanistic Features of Catalytic Carbon Monoxide Hydrogenation Reactions
P.C.FORD, A.ROKOCKI, Adv. Organomet. Chem. 28 (1988) 139 Nucleophilic Activation of Carbon Monoxide: Applications to Homogeneous Catalysis by Metal Carbonyls of the Water Gas Shift and Related Reactions
A.BEHR, Angew. Chem. 100 (1988) 681
Kohlendioxid als alternativer Ci-Baustein: Aktivierung durch Übergangs-metallkomplexe
P.BRAUNSTEIN, Chem. Rev. 88 (1988) 681
Reactions of Carbon Dioxide with Carbon-Carbon Bond Formation Catalysed by Transition-Metal Complexes
S.HENDERSON, R.A.HENDERSON, Adv. Phys. Org. Chem. 23 (1987) 1 The Nucleophilicity of Metal-Complexes Toward Organic Molecules
C.A.TOLMAN, J. Chem. Ed. 63 (1986) 199
Hydrocyanation
E.C.CONSTABLE, Polyhedron 3 (1984) 1037
Cyclometallated Complexes Incorporating a Heterocyclic Donor Atom
R.G.BERGMAN, Science 223 (1984) 902
Activation of Alkanes with Organotransition Metal Complexes
J.-Y.SAILLARD, R.HOFFMANN, J. Am. Chem. Soc. 106 (1984) 2006 C-H and H-H Activation in Transition Metal Complexes and on Surfaces
J.HALPERN, Inorg. Chim. Acta 100 (1985) 41
Activation of C-H Bonds by Metal Complexes: Mechanistic, Kinetic and Thermodynamic Considerations
R.H.CRABTREE, Chem. Rev. 85 (1985) 245
Organometallic Chemistry of Alkanes
M.BROOKHART, M.L.H.GREEN, Prog. Inorg. Chem. 36 (1988) 1
Carbon-Hydrogen-Transition Metal Bonds
P.L.WATSON, G.W.PARSHALL, Acc. Chem. Res., 18 (1985) 51
Organolanthanoids in Catalysis
G.J.KUBAS, Acc. Chem. Res. 21 (1988) 120
Molecular Hydrogen Complexes: Coordination of a -bond to Transition Metals
A.D.RYABOV, Chem. Rev. 90 (1990) 403
Mechanisms of Intramolecular Activation of C-H Bonds in Transition-Metal Complexes
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Elschenbroich, C., Salzer, A. (1988). Metallorganische Katalyse. In: Organometallchemie. Teubner Studienbücher Chemie. Vieweg+Teubner Verlag, Wiesbaden. https://doi.org/10.1007/978-3-322-96804-3_17
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