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Namen- und Schlagwort-Reaktionen der Organischen Chemie pp 72–75Cite as

Cope-Eliminierung

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Zusammenfassung

Aminoxide 2 die durch Oxidation von Aminen 1 zugänglich sind, reagieren beim Erhitzen zu Olefinen 3 sowie Hydroxylamin-Derivaten 4. Diese Reaktion wird als Cope-Eliminierung 1–3) bezeichnet und stellt eine Alternative zum →Hofmann-Abbau quartärer Ammonium-Salze dar.

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Literatur

  1. A. C. Cope, T. T. Foster, P. H. Towle, J. Am. Chem. Soc. 1949, 71, 3929–3935.

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  2. A. C. Cope, E. R. Trumbull, Org. React. 1960, 11, 317–493.

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  3. C. H. DePuy, R. W. King, Chem. Rev. 1960, 60, 431–457.

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Authors and Affiliations

  1. Braunschweig, Deutschland

    Dr. rer. nat. Thomas Laue & Dr. rer. nat. Andreas Plagens

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  1. Dr. rer. nat. Thomas Laue
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  2. Dr. rer. nat. Andreas Plagens
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© 1998 B. G. Teubner Stuttgart

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Laue, T., Plagens, A. (1998). Cope-Eliminierung. In: Namen- und Schlagwort-Reaktionen der Organischen Chemie. Teubner Studienbücher Chemie. Vieweg+Teubner Verlag, Wiesbaden. https://doi.org/10.1007/978-3-322-94077-3_24

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  • DOI: https://doi.org/10.1007/978-3-322-94077-3_24

  • Publisher Name: Vieweg+Teubner Verlag, Wiesbaden

  • Print ISBN: 978-3-519-23526-2

  • Online ISBN: 978-3-322-94077-3

  • eBook Packages: Springer Book Archive

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