Absorption Studies of Optically Nonlinear Side-Chain Polymer and Polymer-Dye Films oriented by Corona Poling

Part of the TEUBNER-TEXTE zur Physik book series (TTZP)


Spectroscopic absorption measurements in the wavelength range from 700 to 300 nm are used to study the orientation of optically nonlinear side-chain groups in an acrylic polymer and dye guest molecules in a polymer matrix by corona poling process. The time stability and the annealing behaviour of these films are measured. The poling process produces efficient orientational order at room temperature of the acrylic side-chain polymers. With stepwise annealing up to poling conditions the orientation order was measured. The guest-host systems show a different behaviour.


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  1. [HAM 90]
    Hampsch, H.L.; Yang, J.; Wong, G.K.; Torkelson, J.M.: Dopant orientation dynamics in doped second order nonlinear optical amorphous polymers. 2. Effects of physical aging on poled films. Macromolecules, 23, 15, (1990) 3648–3654CrossRefGoogle Scholar
  2. [HIL 89]
    Hill, J. R.; Pantelis, P.; Dunn, P. L.; Davies, G. J.: Organic polymer films for second order nonlinear applications, Proc. SPIE, 1147, (1989) 165–176CrossRefGoogle Scholar
  3. [MOR 89]
    Mortazavi, M. A.; Knoesen, A.; Kowel, S. T.; Higgins, B. G.; Dienes, A.: Second-harmonic generation and absorption studies of polymer-dye films oriented by corona-onset poling at elevated temperatures, J. Opt. Soc. Am. B, 4, (1989) 733–741CrossRefGoogle Scholar
  4. [PAG 90]
    Page, R. H.; Jurich, M. C.; Reck, B.; Sen, A.; Twieg, R. J.; Swalen J. D.; Bjorklund, G. C.; Willson, C. G.: Electrochromic and optical waveguide studies of corona-poled electro-optic polymer films, J. Opt. Soc. Am., 7 (1990) 1239–1250CrossRefGoogle Scholar
  5. [SIN 86]
    Singer, K.D.; Sohn, I. E.; Lalama, S.I.: Second harmonic generation in poled polymer films, Appl. Phys. Lett., 49, (1986) 248–250Google Scholar
  6. [TAU 91]
    Tauer, K.; Morozova, A.; Wedel, A.: Synthese von nitrogruppenhaltigen Copolymeren durch radikalische Copolymerisation, submitted to Macromol. Chem.Google Scholar

Copyright information

© B. G. Teubner Verlagsgesellschaft Leipzig 1993

Authors and Affiliations

  1. 1.Fraunhofer-Establishment of Applied Polymer ResearchTeltow-SeehofGermany
  2. 2.University of PotsdamTeltow-SeehofGermany
  3. 3.Max-Planck-Institut für Kolloid- und GrenzflächenforschungTeltow-SeehofGermany

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