Abstract
The use of neoteric solvents to substitute organic molecular solvents offers new opportunities to develop more environmentally friendly synthetic organic chemistry to access to new molecules, materials or processes. Most known and investigated neoteric solvents (NS) remain nowadays supercritical fluids (SCF), room temperature ionic liquids (RTILS) and deep eutectic solvents (DES). Each of them offers several advantages over organic molecular solvents but also display inherent drawbacks. In order to tackle the latter moving forward to safer and faster processes, ultrasound technology was recently coupled synergistically with these new media. These three categories of NS are hereafter briefly introduced together with their own remarkable properties permitting their use as alternative benign solvents. Insights of striking developed applications with ultrasound will be then given in order to unleash the promising potential of coupling ultrasound technology with neoteric solvents.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Adams DJ, Dyson PJ, Tavener SJ (2004) Chemistry in alternative reaction media. John Wiley & Sons, Chichester, UK
Bakht MA, Ansari MJ, Riadi Y, Ajmal N, Ahsan MJ, Yar MS (2016) Physicochemical characterization of benzalkonium chloride and urea based deep eutectic solvent (DES): a novel catalyst for the efficient synthesis of isoxazolines under ultrasonic irradiation. J Mol Liq 224:1249–1255
Bakirtzi C, Triantafyllidou K, Makris DP (2016) Novel lactic acid-based natural deep eutectic solvents: efficiency in the ultrasound-assisted extraction of antioxidant polyphenols from common native Greek medicinal plants. J Appl Res Med Aromat Plants 3:120–127
Chatel G, MacFarlane DR (2014) Ionic liquids and ultrasound in combination: synergies and challenges. Chem Soc Rev 43:8132–8149
Deshmukh RR, Rajagopal R, Srinivasan KR (2001) Ultrasound promoted C-C bond formation: Heck reaction at ambient conditions in room temperature ionic liquids. Chem Commun 17:1544–1545
Dominguez de Maria P (2013) Recent trends in (ligno)cellulose dissolution using neoteric solvents: switchable, distillable and bio-based ionic liquids. J Chem Technol Biotechnol (wileyonlinelibrary.com) https://doi.org/10.1002/jctb.4201
Han D, Row KH (2010) Recent applications of ionic liquids in separation technology. Molecules 15:2405–2426
Khaw KY, Parat M-O, Shaw PN, Falconer JR (2017) Solvent supercritical fluid technologies to extract bioactive compounds from natural sources: a review
Khezeli T, Daneshfar A (2017) Synthesis and application of magnetic deep eutectic solvents: novel solvents for ultrasound assisted liquid-liquid microextraction of thiophene. Ultrason Sonochem 38:590–597
Kim SH, Yang ST, Kim J, Ahn WS (2011) Sonochemical synthesis of Cu3(BTC)2 in a deep eutectic mixture of choline chloride/dimethylurea. Bull Korean Chem Soc 32:2783–2786
Leveque JM, Luche JL, Petrier C, Roux R, Bonrath W (2002) An improved preparation of ionic liquids by ultrasound. Green Chem 4:357–360
Lores H, Romero V, Costas I, Bendicho C, Lavilla I (2017) Natural deep eutectic solvents in combination with ultrasonic energy as a green approach for solubilisation of proteins: application to gluten determination by immunoassay. Talanta 162:453–459
Maleki A, Agahie M (2017) Ultrasonic-assisted environmentally-friendly synergetic synthesis of nitroaromatic compounds in core/shell nanoreactor: a green protocol. Ultrason Sonochem 39:534–539
Namboodiri VV, Varma RS (2002) Solvent-freen sonochemical preparation of ionic liquids. Org Lett 4:3161–3163
Oxley JD, Prozorov T, Suslick KS (2003) Sonochemistry and sonoluminescence of room-temperature ionic liquids. J Am Chem Soc 125:11138–11139
Passos H, Freire MG, Coutinho JAP (2014) Ionic liquid solutions as extractive solvents for value-added compounds from biomass. Green Chem 16:4786–4815
Petkovic M, Ferguson JL, Gunaratne HQN, Ferreira R, Leitao MC, Seddon KR, Rebelo LPN, Silva Pereira C (2010) Novel biocompatible cholinium-based ionic liquids—toxicity and biodegradability. Green Chem 12:643–649
Sanap AK, Shankarling GS (2014) Eco-friendly and recyclable media for rapid synthesis of tricyanovinylated aromatics using biocatalyst and deep eutectic solvent. Cat Com 49:58–62
Singh BS, Lobo HR, Pinjari DV, Jarag KJ, Pandit AB, Shankarling GS (2013) Comparative material study and synthesis of 4-(4-nitrophenyl)oxazol-2-amine via sonochemical and thermal method. Ultrason Sonochem 20:633–639
Smith EL, Abbott AP, Ryder KS (2014) Deep eutectic solvents (DESs) and their applications. Chem Rev 114:11060–11082
Trofimov TI, Samsonov MD, Lee SC, Smart NG, Wai CM (2001) Ultrasound enhancement of dissolution kinetics of uranium owides in supercritical carbon dioxide. J Chem Technol Biotechnol 76:1223–1226
Yadav UN, Shankarling GS (2014) Synergistic effect of ultrasound and deep eutectic solvent choline chloride–urea as versatile catalyst for rapid synthesis of β-functionalized ketonic derivatives. J Mol Liq 195:188–193
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
Copyright information
© 2018 The Author(s), under exclusive licence to Springer Nature Switzerland AG
About this chapter
Cite this chapter
Lévêque, JM., Cravotto, G., Delattre, F., Cintas, P. (2018). Sonication in Neoteric Solvents. A Further Look at Synthetic Plans. In: Organic Sonochemistry. SpringerBriefs in Molecular Science(). Springer, Cham. https://doi.org/10.1007/978-3-319-98554-1_3
Download citation
DOI: https://doi.org/10.1007/978-3-319-98554-1_3
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-98553-4
Online ISBN: 978-3-319-98554-1
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)