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Toughening Mechanisms on Recycled Rubber Modified Epoxy Based Composites Reinforced with Graphene Nanoplatelets

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Mechanics of Composite, Hybrid and Multifunctional Materials, Volume 5

Abstract

Recycling is a subject undergoing intense study in terms of sustainable development. In every area, recycling is strongly encouraged by governments due to the international agreements on environmental issues. For example, many industrial manufacturers have a tendency to find clean and cost-efficient solutions by utilizing recycled materials to produce new components. In this regard, rubbers have very wide usage in aeronautic and automotive industries both in structural and in interior body components. Rubbers are also used to modify brittle polymer components in the existence of hard, resistant fillers. In this study, fresh scrap EPDM rubbers are used to manufacture novel composites by modifying epoxy resin with the inclusion of graphene nano platelets (GnPs). Rather than micro sized particles, nanoparticles have high surface area, which means that a low content of these nanoparticles may enhance the material’s properties more efficiently. Besides, due to its superior structural, thermal and physical characteristics, addition of graphene promises improved mechanical properties if they can be dispersed homogeneously. This paper is focused on the fracture characteristics and toughening mechanisms of epoxy – fresh scrap rubber composites. The mechanical and physical properties of these composite systems are studied in the present work. Mechanical properties are examined by means of three-point bending tests with smooth and single edge notched beam specimens (SENB). Also, nano indentation tests were realized to see the creep compliance and viscoelastic properties. Finally, scanning electron microscope (SEM) was used to observe the fracture surfaces and the microstructure.

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References

  1. Adhikari, B., De, D., Maiti, S.: Reclamation and recycling of waste rubber. Prog. Polym. Sci. 25, 909–948 (2000). https://doi.org/10.1016/S0079-6700(00)00020-4

    Article  Google Scholar 

  2. Fiksel, J., Bakshi, B.R., Baral, A., Guerra, E., Dequervain, B.: Comparative life cycle assessment of beneficial applications for scrap tires. Clean Techn. Environ. Policy. 13, 19–35 (2011). https://doi.org/10.1007/s10098-010-0289-1

    Article  Google Scholar 

  3. Fang, Y., Zhan, M., Wang, Y.: The status of recycling of waste rubber. Mater. Des. 22, 123–128 (2001). https://doi.org/10.1016/S0261-3069(00)00052-2

    Article  Google Scholar 

  4. De, S.K., Isayev, A., Khait, K.: Rubber Recycling. CRC Press, Boca Raton (2005)

    Book  Google Scholar 

  5. May, C.: Epoxy Resins: Chemistry and Technology, 2nd edn. CRC Press, Boca Raton (1987)

    Google Scholar 

  6. Wang, Q.: The effect of nano size fillers on electrical performance of epoxy resin. Phd. University of Southampton (2012)

    Google Scholar 

  7. Ochi, M., Takahashi, R.: Phase structure and thermomechanical properties of primary and tertiary amine-cured epoxy/silica hybrids. J. Polym. Sci. B Polym. Phys. 39, 1071–1084 (2001). https://doi.org/10.1002/polb.1084

    Article  Google Scholar 

  8. Okazaki, M., Murota, M., Kawaguchi, Y., Tsubokawa, N.: Curing of epoxy resin by ultrafine silica modified by grafting of hyperbranched polyamidoamine using dendrimer synthesis methodology. J. Appl. Polym. Sci. 80, 573–579 (2001). https://doi.org/10.1002/1097-4628(20010425)80:4<573::AID-APP1132>3.0.CO;2-E

    Article  Google Scholar 

  9. Wichmann, M.H.G., Schulte, K., Wagner, H.D.: On nanocomposite toughness. Compos. Sci. Technol. 68, 329–331 (2008). https://doi.org/10.1016/j.compscitech.2007.06.027

    Article  Google Scholar 

  10. Liang, Y.L., Pearson, R.A.: Toughening mechanisms in epoxy–silica nanocomposites (ESNs). Polymer. 50, 4895–4905 (2009). https://doi.org/10.1016/j.polymer.2009.08.014

    Article  Google Scholar 

  11. Srivastava, I., Koratkar, N.: Fatigue and fracture toughness of epoxy nanocomposites. JOM. 62, 50–57 (2010). https://doi.org/10.1007/s11837-010-0032-8

    Article  Google Scholar 

  12. Novoselov, K.S., Geim, A.K.: The rise of graphene. Nat. Mater. 6, 183–191 (2007)

    Article  Google Scholar 

  13. Superior thermal conductivity of single-layer graphene – Nano Letters (ACS Publications): https://pubs.acs.org/doi/abs/10.1021/nl0731872. Accessed 21 Feb 2018

  14. Effective Elastic Mechanical Properties of Single Layer Graphene Sheets – IOPscience: http://iopscience.iop.org/article/10.1088/0957-4484/20/6/065709/meta. Accessed 21 Feb 2018

  15. Wang, F., Drzal, L.T., Qin, Y., Huang, Z.: Enhancement of fracture toughness, mechanical and thermal properties of rubber/epoxy composites by incorporation of graphene nanoplatelets. Compos. A: Appl. Sci. Manuf. 87, 10–22 (2016). https://doi.org/10.1016/j.compositesa.2016.04.009

    Article  Google Scholar 

  16. Pathak, A.K., Borah, M., Gupta, A., Yokozeki, T., Dhakate, S.R.: Improved mechanical properties of carbon fiber/graphene oxide-epoxy hybrid composites. Compos. Sci. Technol. 135, 28–38 (2016). https://doi.org/10.1016/j.compscitech.2016.09.007

    Article  Google Scholar 

  17. The Effect of Graphene and Natural Rubber Content on Mechanical and Electrical Conductivity Properties of Epoxy/Natural Rubber/Graphene Conductive Materials. https://www.scientific.net/MSF.888.209. Accessed 21 Feb 2018

  18. Ladani, R.B., Wu, S., Kinloch, A.J., Ghorbani, K., Zhang, J., Mouritz, A.P., et al.: Multifunctional properties of epoxy nanocomposites reinforced by aligned nanoscale carbon. Mater. Des. 94, 554–564 (2016). https://doi.org/10.1016/j.matdes.2016.01.052

    Article  Google Scholar 

  19. Kuo, W.-S., Tai, N.-H., Chang, T.-W.: Deformation and fracture in graphene nanosheets. Compos. A: Appl. Sci. Manuf. 51, 56–61 (2013). https://doi.org/10.1016/j.compositesa.2013.03.020

    Article  Google Scholar 

  20. Irez, A.B., Miskioglu, I., Bayraktar, E.: Mechanical characterization of epoxy–scrap rubber based composites reinforced with nano graphene. In: Mechanics of Composite and Multi-functional Materials, vol. 6, pp. 45–57. Springer, Cham (2018)

    Google Scholar 

  21. Tranchida, D., et al.: Mechanical characterization of polymers on a nanometer scale through nanoindentation. A study on pile-up and viscoelasticity. Macromolecules. 40(4), 1259–1267 (2007)

    Article  Google Scholar 

  22. Lagoudas, D.C., Thakre, P.R., Amine Benzerga, A.: Nanoindentation of cnt reinforced epoxy nanocomposites. In: Fracture of Nano and Engineering Materials and Structures, pp. 649–650. Springer, Dordrecht (2006)

    Chapter  Google Scholar 

  23. Tranchida, D., et al.: Accurately evaluating Young’s modulus of polymers through nanoindentations: A phenomenological correction factor to the Oliver and Pharr procedure. Appl. Phys. Lett. 89(17), 171905 (2006)

    Article  Google Scholar 

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Acknowledgments

Authors acknowledge to Dr. H-A. ALHAS-Airbus Space-London/UK for supporting this project. During our collaboration when he was in Airbus – Helicopter in Paris, he has supported and participated partially to discussion for application of GnPs to epoxy resin modified rubber based composited.

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Correspondence to E. Bayraktar .

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Irez, A.B., Miskioglu, I., Bayraktar, E. (2019). Toughening Mechanisms on Recycled Rubber Modified Epoxy Based Composites Reinforced with Graphene Nanoplatelets. In: Thakre, P., Singh, R., Slipher, G. (eds) Mechanics of Composite, Hybrid and Multifunctional Materials, Volume 5. Conference Proceedings of the Society for Experimental Mechanics Series. Springer, Cham. https://doi.org/10.1007/978-3-319-95510-0_35

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  • DOI: https://doi.org/10.1007/978-3-319-95510-0_35

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