Abstract
Pyrometallurgy is an important sector of modern industrial society actively participating in solving current environmental, economic, materials scarcity and other challenges. Recent advances in analytical methods, experimental techniques, thermodynamic, phase equilibria and process modelling tools provide new opportunities to increase the productivity of pyrometallurgical reactors, the treatment of complex feeds and metal recoveries. Fundamental theoretical models can now be used to make a significant next step towards the development and implementation of computerised models describing real industrial processes—Virtual Reactors, and computer-aided smart-decision-making systems that may be called Pyro-GPS by analogy to GPS; these developments can facilitate knowledge-based improvement and optimisation strategies. The implementation of these improvements require ongoing collaboration between researchers, industry and government.
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Jak E, Shishin D, Hawker W, Vaughan J, Hayes PC (2018) Improved copper smelter and converter productivity through the use of a novel high-grade feed. In: 7th International symposium on advances in sulfide smelting, Extraction 2018, Ottawa, Canada
Jak E, Nicol S, Hidayat T, Shishin D, Hayes PC (2016) The potential for energy savings, increased productivity and recovery in copper smelting, converting and recycling through implementation of experimental and thermodynamic modelling research, Copper 2016, Kobe, Japan, November 2016
Henao HM, Ushkov LA, Jak E (2012) Thermodynamic predictions and experimental investigation of slag liquidus and minor element partitioning between slag and matte in support of the copper Isasmelt smelting process commissioning and optimisation at Kazzinc. In: The 9th international conference on molten slags, fluxes and salts, Molten 12, Beijing, China, May 2012, paper w78
Chen J, Allen CM, Azekenov T, Ushkov L, Hayes PC, Jak E (2016) Quantitative determination of partitioning of trace/ultra trace elements between slag and matte generated in copper smelting process using microanalysis techniques, Copper 2016, Kobe, Japan, November 2016
Jak E, Lee HG, Hayes PC (1995) Improved methodologies for the determination of high temperature phase equilibria. Korean IMM J 1:1–8
Fallah-Mehrjardi A, Hidayat T, Hayes P, Jak E Experimental investigation of gas/slag/matte/tridymite in the Cu–Fe–O–S–Si system in controlled atmospheres: T = 1523 K (1250 ˚C) and P(SO2) = 0.25 atm. Metall. Mater. Trans. B (submitted)
Jak E (2012) Integrated experimental and thermodynamic modelling research methodology for copper and other metallurgical slags. In: The 9th international conference on molten slags, fluxes and salts, Beijing, China, May 2012, paper w77. Keynote Invited Lecture, MOLTEN 12
Avarmaa K, Yliaho S, Taskinen P (2018) Recoveries of rare elements Ga, Ge, In and Sn from waste electric and electronic equipment through secondary copper smelting. Waste Manag 71:400–410
Hidayat T, Fallah Mehrjardi A, Hayes P, Jak E (2016) Experimental study of slag/matte/spinel equilibria and minor elements partitioning in the Cu–Fe–O–S–Si system. In: Molten 2016, 10th International conference on molten slags, fluxes and salts, May 2016, Seattle, Washington, USA, pp 1207–1220
Jak E, Hidayat T, Shishin D, Fallah Mehrjardi A, Chen J, Hayes P (2016) Integrated experimental phase equilibria and thermodynamic modelling studies for copper pyrometallurgy, Copper 2016, Kobe, Japan
MTDATA: Teddington, UK. www.npl.co.uk
Thermo-Calc: Stockholm, Sweden. www.thermocalc.com
FactSage: Montreal, Canada. www.factsage.com
Bale CW, Belisle E, Chartrand P, Decterov SA, Eriksson G, Gheribi AE, Hack K, IH. 13. Jung, Y.B. Kang, J. Melancon, A.D. Pelton, S. Petersen, C. Robelin, J. Sangster, P. Spencer, M.A. Van Ende (2016) FactSage thermochemical software and databases, 2010–2016. CALPHAD 54: 35–53
Cao W, Chen SL, Zhang F, Wu K, Yang Y, Chang YA, Schmid-Fetzer R, Oates WA (2009) PANDAT software with PanEngine, PanOptimizer and PanPrecipitation for multi-component phase diagram calculation and materials property simulation. Calphad 33(2):328–342. PanDat: Middleton, USA. www.computherm.com
Pelton AD, Decterov SA, Eriksson G, Robelin C, Dessureault Y (2000) The modified quasichemical Model. I—binary solutions. Metall Mater Trans B 31:651–659
Pelton AD, Chartrand P (2001) The modified quasichemical model. II—multicomponent solutions. Metall Mater Trans A 32:1355–1360
Chartrand P, Pelton AD (2001) The modified quasichemical model. III—two sublattices. Metall Mater Trans A 32:1397–1407
Pelton AD, Chartrand P, Eriksson G (2001) The modified quasichemical model. IV—two sublattice quadruplet approximation. Metall Mater Trans A 32:1409–1415
Hillert M, Jansson B, Sundman B (1988) Application of the compound-energy model to oxide systems. Z Metallkd 79:81–87
Hillert M (2001) The compound energy formalism. J Alloys Compd 320:161–176
CEQCSI: Maizières, France. www.arcelormittal.com
Chen C (2015) Application of MPE model to iron ore sintering, ironmaking and steelmaking processes. Steel Res Int 86(6):612–618. MPE: Clayton, Australia. www.csiro.au
Decterov SA (2018) Thermodynamic database for multicomponent oxide systems. Chimica Techno Acta 5(1)
Jak E, Decterov SA, Zhao B, Pelton AD, Hayes PC (2000) Coupled experimental and thermodynamic modelling studies for metallurgical smelting and coal combustion slag systems. Metall Mater Trans B 31:621–630
Jak E, Hayes P, Bale CW, Decterov SA (2007) Application of FactSage thermodynamic modeling of recycled slags (Al2O3–CaO–FeO–Fe2O3–SiO2–PbO–ZnO) in the treatment of wastes from end-of-life-vehicles. Int J Mater Res 98:872–878
Decterov SA, Kang Y-B, Jung I-H (2009) Thermodynamic database for the Al–Ca–Co–Cr–Fe–Mg–Mn–Ni–Si–O–P–S system and applications in ferrous process metallurgy. J Phase Equilib Diffus 30:443–461
Paek M-K, Do K-H, Kang Y-B, Jung I-H, Pak J-J (2016) Aluminum deoxidation equilibria in liquid iron: part III—experiments and thermodynamic modeling of the Fe–Mn–Al–O system. Metall Mater Trans B 47:2837–2847
Jung I-H (2010) Overview of the applications of thermodynamic databases to steelmaking processes. CALPHAD 34:332–362
Deschênes-Allard F, Robelin C, Zanghi D, Bouvet S, Ory S, Véron E, Machado K, Bessada C, Chartrand P (2017) Experimental and thermodynamic assessment of the fluoride-rich region in the Cu–O–F system. Thermochimica Acta
Jung I-H, Zhu Z, Kim J, Wang J, Chartrand P, Pelton A (2017) Recent progress on the factsage thermodynamic database for new Mg alloy development. JOM 69:1052–1059
Gisby P, Taskinen J, Pihlasalo Z, Li M, Tyrer J, Pearce K, Avarmaa P, Björklund H, Davies M, Korpi S, Martin L, Pesonen J (2017) Robinson, MTDATA and the prediction of phase equilibria in oxide systems: 30 years of industrial collaboration. Metall Mater Trans B 48:91–98
Jak E, Hidayat T, Shishin D, Fallah Mehrjardi A, Chen J, Decterov S, Hayes P (2016) Integrated experimental and modelling research for non-ferrous smelting and recycling systems. In: 10th international conference on molten slags, fluxes and salts, Molten 2016, May 2016, Seattle, Washington, USA, pp 947–959
Jak E, Hidayat T, Shishin D, Fallah Mehrjardi A, Chen J, Hayes P (2017) Experimental and modelling research in support of energy savings and improved productivity in non-ferrous metal production and recycling. In: Proceedings of EMC 2017, Leipzig, Germany
Hidayat T, Hayes PCC, Jak E (2018) Microanalysis and experimental techniques for the determination of multicomponent phase equilibria for non-ferrous smelting and recycling systems. In: Peter Hayes symposium on pyrometallurgical processing, Extraction 2018, Ottawa, Canada
Shevchenko M, Hayes PC, Jak E (2018) Development of a thermodynamic database for the multicomponent PbO–“Cu2O”–FeO–Fe2O3–ZnO–CaO–SiO2 system for pyrometallurgical smelting and recycling. In: Peter Hayes symposium on pyrometallurgical processing, Extraction 2018, Ottawa, Canada
Shishin D, Hayes PC, Jak E (2018) Multicomponent thermodynamic databases for complex non-ferrous pyrometallurgical processes. In: Peter Hayes symposium on pyrometallurgical processing, extraction 2018, Ottawa, Canada
Hidayat T, Fallah-Mehrjardi A, Hayes P, Jak E (2017) Experimental investigation of gas/slag/matte/spinel equilibria in the Cu–Fe–O–S–Si system at 1473 K (1200 °C) and P(SO2) = 0.25 atm. Metall. Mater. Trans. B. (Accepted for publication on 8 Dec 2017)
Hidayat T, Hayes PC, Jak E (2018) Phase equilibria in the ZnO–”FeO”–SiO2 system in reducing atmosphere and in the ZnO–”FeO”–SiO2–”Cu2O” system in equilibrium with liquid copper metal at 1250℃ (1523 K). Metall Mater Trans B (in press)
Chen J, Jak E, Hayes P (2009) Factors affecting nickel extraction from reduction roasting of saprolite ore in the Caron process. In: Liu J et al (ed) International symposium pyrometallurgy of nickel and cobalt 2009, Met Soc CIM, Sudbury, Canada, pp 449–462
Xu X, Henao HM, Hayes PC, Jak E (2013) Phase equilibria in the “SnO”–SiO2–“FeO” system in equilibrium with tin-iron alloy at fixed oxygen partial pressures at 1473K. Int J Mater Res 104(11):1079–1087
Haccuria E, Hayes PC, Jak E (2014) Phase equilibria studies of Mn–Al–Si–O systems in equilibrium with manganese alloy. Part 1: Development of the technique and determination of isothermal sections at 1150 ℃ and 1200 ℃. Zeitschrift für Metallkunde: Int J Mater Res 105(10):941–952
Shevchenko M, Hidayat T, Hayes P, Jak E (2016) Liquidus of “FeO”–SiO2–PbO slags in equilibrium with air and with metallic lead. In: 10th International conference on molten slags, fluxes and salts, Molten 2016, May 2016, Seattle, Washington, USA, pp 1221–1228
ANSYS Fluent: Caninsburg, PA, USA. www.ansys.com
Chibwe DK, Akdogan G, Taskinen P, Eksteen JJ (2015) Modelling of fluid flow phenomena in Peirce-Smith copper converters and analysis of combined blowing concept. J South Afr Inst Min Metall 115:363–374
White M, Haywood R, Ranasinghe DJ, Chen S (2015) The development and application of a CFD model of copper flash smelting. In: 11th International conference on CFD in the minerals and process industries, Australia
Aspen Plus, Bedfort, MA, USA. www.aspentech.com
SysCAD, Perth, Australia. www.syscad.net
METSIM, Proware, Tucson, AZ, USA. www.metsim.com
Jak E (2018) Modelling metallurgical furnaces—making the most of modern research and development techniques. In: 7th International symposium on advances in sulfide smelting, Extraction 2018, Ottawa, Canada
Nikolic S, Shishin D, Hayes PC, Jak E (2018) Case study on the application of research to operations—calcium ferrite slags. In: 7th International symposium on advances in sulfide smelting, Extraction 2018, Canada
Van Camp M, Campforts M, Vasseur K, Meskers C, Hennebel T, Apelian D (2015) Towards a resource resilient society via the triple helix concept, COM 2015, Toronto, Canada
Acknowledgements
The author would like to thank many industrial sponsors including Umicore, Aurubis, Kazzinc Glencore, Nyrstar, BHP Billiton Olympic Dam Operation, Outotec (Espoo and Melbourne), PASAR Glencore, Anglo American Platinum , Atlantic Copper , Rio Tinto’s Kennecott operation, Altonorte Glencore and many others, as well as Australian Research Council Linkage program for the financial and technical support for this research. The author would like to acknowledge help of colleagues in preparation of this paper including Prof. P. C Hayes, Prof. Decterov, Dr Shishin, Dr Hidayat and others. Special acknowledgement and thanks to Prof. Hayes for the initiation and tireless continuous significant input over many decades into the research and education in the metallurgy sector.
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Jak, E. (2018). The Role of Research in Pyrometallurgy Technology Development—From Fundamentals to Process Improvements—Future Opportunities. In: Davis, B., et al. Extraction 2018. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-319-95022-8_2
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