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Chemicals and Fuels Production from Agro Residues: A Biorefinery Approach

  • Desikan RameshEmail author
  • Iniya Kumar Muniraj
  • Kiruthika Thangavelu
  • Subburamu Karthikeyan
Chapter
Part of the Biofuel and Biorefinery Technologies book series (BBT, volume 7)

Abstract

Alternative fuel production technology in order to combat the present scenario of climate change issues has been in the transition stage of generating high-value low volume chemicals, fuels and low-value high volume bulk products (biofuels). This concept of biorefinery is the future of biomass processing technologies where complete utilization of biomass and zero release of waste can be achieved. The agro residue biorefinery aims in sustainable approach which provides a good solution for sustainable ways of utilizing agricultural residues. Agro residues are by-products of agricultural crop production and processing, which are abundantly available at lower price. Agro residues are one of the major resources of unexploited potential lignocellulosic feedstocks. It includes straws, leaves and plant materials left in the field after harvesting of the crop. Its characteristics would vary with crops, species and environmental conditions. Annual agro residue production potential in India is ca. 550 MT. Currently, most of the residues are underutilized or burnt in situ, creating serious environmental pollutions. In order to utilize and effective disposal of these wastes, several methods are tried for tapping the energy/bioproducts from various crop residues via biochemical or thermochemical conversion routes. Biorefinery technologies can offer a platform for production of high-value chemicals and fuels from these residues, which are value-added products as well as provide more income for agriculturists. This chapter aims in bringing out sources of agro residues, the current state of the art of biomass processing and conversion viable technologies, and recent developments in the biorefinery of agro residues, and finally sheds light on commercialization of agro residue biorefinery.

Keywords

Biorefinery Biochemicals Thermochemical conversion technologies Paddy straw 

References

  1. Adney WS, Rivard CJ, Ming SA, Himmel ME (1991) Anaerobic digestion of lignocellulosic biomass and wastes. Cellulases and related enzymes. Appl Biochem Biotechnol 30:165–183CrossRefGoogle Scholar
  2. Ahring BK, Westermann P (2007) Coproduction of bioethanol with other biofuels. Adv Biochem Eng Biotechnol 108:289–302.  https://doi.org/10.1007/10_2007_067CrossRefGoogle Scholar
  3. Asadullah M, Rahman MA, Ali MM, Motin MA, Sultan MB, Alam MR et al (2008) Jute stick pyrolysis for bio-oil production in fluidized bed reactor. Bioresour Technol 99:44–50CrossRefGoogle Scholar
  4. Ballesteros I, Negro M, Oliva JM, Cabanas A, Manzanares P, Ballesteros M (2006) Ethanol production from steam explosion pretreated wheat straw. Appl Biochem Biotechnol 130:278–288CrossRefGoogle Scholar
  5. Beller HR, Lee TS, Katz L (2015) Natural products as biofuels and bio-based chemicals: fatty acids and isoprenoids. Nat Prod Rep 32:1508–1526.  https://doi.org/10.1039/c5np00068hCrossRefGoogle Scholar
  6. Bertero M, de la Puente G, Sedran U (2012) Fuels from bio-oils: bio-oil production from different residual sources, characterization and thermal conditioning. Fuel 95:263–271CrossRefGoogle Scholar
  7. Bharathiraja B, Jayamuthunagai J, Sudharsanaa T, Bharghavi A, Praveenkumar R, Chakravarthy M, Yuvaraj D (2017) Biobutanol—an impending biofuel for future: a review on upstream and downstream processing techniques. Renew Sustain Energy Rev 68:788–807CrossRefGoogle Scholar
  8. De Bhowmick G, Sarmah AK, Sen R (2018) Lignocellulosic biorefinery as a model for sustainable development of biofuels and value added products. Bioresour Technol 247:1144–1154.  https://doi.org/10.1016/j.biortech.2017.09.163CrossRefGoogle Scholar
  9. Bilal M, Asgher M, Iqbal HM, Hu H, Zhang X (2017a) Biotransformation of lignocellulosicGoogle Scholar
  10. Bilal M, Asgher M, Iqbal HM, Hu H, Zhang X (2017b) Biotransformation of lignocellulosic materials into value-added products—a review. Int J BiolMacromol 98:447–458CrossRefGoogle Scholar
  11. Binod P, Sindhu R, Singhania RR, Vikram S, Devi L, Nagalakshmi S, Kurien N, Sukumaran RK, Pandey A (2010) Bioethanol production from rice straw: an overview. Bioresour Technol 101:4767–4774CrossRefGoogle Scholar
  12. Biomass Knowledge Portal. http://biomasspower.gov.in/. (as per May 20, 2016)
  13. Bouaid A, Martinez M, Aracil J (2010) Biorefinery approach for coconut oil valorisation: a statistical study. Bioresour Technol 101:4006–4012CrossRefGoogle Scholar
  14. Braga RM, Melo DMA, Aquino FM, Freitas JCO, Melo MAF, Barros JMF, Fontes MSB (2013) Characterization and comparative study of pyrolysis kinetics of the rice husk and the elephant grass. J Therm Anal Calor. 115:1915–1920CrossRefGoogle Scholar
  15. Butler E, Devlin G, Meier D, McDonnell K (2013) Characterisation of spruce, salix, miscanthus & wheat straw for pyrolysis applications. Bioresour Technol 131:202–209CrossRefGoogle Scholar
  16. Byun J, Han J (2016) Catalytic production of biofuels (butene oligomers) and biochemicals (tetrahydrofurfuryl alcohol) from corn stover. Bioresour Technol 211:360–366.  https://doi.org/10.1016/j.biortech.2016.03.123CrossRefGoogle Scholar
  17. Cabeza A, Piqueras CM, Sobron F, Garcia-Serna J (2016) Modeling of biomass fractionation in a lab-scale biorefinery: solubilization of hemicellulose and cellulose from holm oak wood using subcritical water. Bioresour Technol 200:90–102.  https://doi.org/10.1016/j.biortech.2015.09.063CrossRefGoogle Scholar
  18. Caglar A, Demirbas A (2001) Conversion of cotton cocoon shell to liquid products by supercritical fluid extraction and low pressure pyrolysis in the presence of alkalis. Energy Convers Manage 42:1095–1104CrossRefGoogle Scholar
  19. Cai J, He Y, Yu X, Banksb Scott W, Yang Y, Zhang X, Yu Y, Liu R, Bridgwater Anthony V (2017) Review of physicochemical properties and analytical characterization of lignocellulosic biomass. Renew Sustain Energy Rev 76:309–322CrossRefGoogle Scholar
  20. Chen D, Cen K, Jing X, Gao J, Li C, Ma Z (2017) An approach for upgrading biomass and pyrolysis product quality using a combination of aqueous phase bio-oil washing and torrefaction pretreatment. Bioresour Technol 233:150–158.  https://doi.org/10.1016/j.biortech.2017.02.120CrossRefGoogle Scholar
  21. Chen WH, Pen BL, Yuz CT, Hwang WS (2011a) Pretreatment efficiency and structural characterization of rice straw by an integrated process of dilute-acid and steam explosion for bioethanol production. Bioresour Technol 102:2916–2924CrossRefGoogle Scholar
  22. Chen WH, Pen BL, Yu CT, Hwang WS (2011b) Pretreatment efficiency and structural characterization of rice straw by an integrated process of dilute-acid and steam explosion for bioethanol production. Bioresour Technol 102:2916–2924CrossRefGoogle Scholar
  23. Chen G, Yao J, Yang H, Yan B, Chen H (2015) Steam gasification of acid-hydrolysis biomass CAHR for clean syngas production. Bioresour Technol 179:323–330.  https://doi.org/10.1016/j.biortech.2014.12.039CrossRefGoogle Scholar
  24. Christopher M, Mathew AK, Kiran Kumar M, Pandey A, Sukumaran RK (2017) A biorefinery-based approach for the production of ethanol from enzymatically hydrolysed cotton stalks. Bioresour Technol .  https://doi.org/10.1016/j.biortech.2017.03.190CrossRefGoogle Scholar
  25. de Jong E, Jungmeier G (2015) Biorefinery concepts in comparison to petrochemical refineries. In: Industrial biorefineries & white biotechnology, pp 3–33Google Scholar
  26. Dhyani V, Bhaskar T (2017) A comprehensive review on the pyrolysis of lignocellulosic biomass. Renew EnergyGoogle Scholar
  27. Diaz AB, Moretti MMD, Bezerra-Bussoli C, Nunes CDCC, Blandino A, da Silva R et al (2015) Evaluation of microwave-assisted pretreatment of lignocellulosic biomass immersed in alkaline glycerol for fermentable sugars production. Bioresour Technol 185:316–323CrossRefGoogle Scholar
  28. Dodson JR, Li X, Zhou X, Zhao K, Sun N, Atahan P (2013) Origin and spread of wheat in China. Quatern Sci Rev 72:108–111Google Scholar
  29. Dominguez E, Romani A, Alonso JL, Parajo JC, Yanez R (2014) A biorefinery approach based on fractionation with a cheap industrial by-product for getting value from an invasive woody species. Bioresour Technol 173:301–308.  https://doi.org/10.1016/j.biortech.2014.09.104CrossRefGoogle Scholar
  30. ECN - Phyllis2 Database for biomass and waste (www.ecn.nl/phyllis2)
  31. Esteghlalian A, Hashimoto AG, Fenske JJ, Penner MH (1997) Modeling and optimization of the dilute sulfuric acid pretreatment of corn stover, poplar and switchgrass. BioresourTechnol 59:129–136CrossRefGoogle Scholar
  32. Eynde EV, Lenaerts B, Tytgat T, Blust R, Lenaerts S (2016) Valorization of flue gas by combining photocatalytic gas pretreatment with microalgae production. Environ Sci Technol 50:2538–2545.  https://doi.org/10.1021/acs.est.5b04824CrossRefGoogle Scholar
  33. Friedl A, Padouvas E, Rotter H, Varmuza K (2005) Prediction of heating values of biomass fuel from elemental composition. Anal Chim Acta 544:191–198CrossRefGoogle Scholar
  34. Gao H, Chen X, Wei J, Zhang Y, Zhang L, Chang J et al (2016) Decomposition dynamics and changes in chemical composition of wheat straw residue under anaerobic and aerobic conditions. PLoS ONE 11(7):e0158172CrossRefGoogle Scholar
  35. Garcia-Cubero MT, González-Benito G, Indacoechea I, Coca M, Bolado S (2009) Effect of ozonolysis pretreatment on enzymatic digestibility of wheat and rye straw. Bioresour Technol 100:1608–1613CrossRefGoogle Scholar
  36. Gaurava N, Sivasankarib S, Kiranc GS, Ninawea A, Selvinb J (2017) Utilization of bioresources for sustainable biofuels: a review. Renew Sustain Energy Rev 73:205–214CrossRefGoogle Scholar
  37. Hellier P, Purton S, Ladommatos N (2015) Molecular structure of photosynthetic microbial biofuels for improved engine combustion and emissions characteristics. Front Bioeng Biotechnol 3:49.  https://doi.org/10.3389/fbioe.2015.00049CrossRefGoogle Scholar
  38. Henry RJ (2018) Biofuels from crop plants. Encyclopedia of applied plant sciences, 2nd edn, vol 3, pp 177–179. http://dx.doi.org/10.1016/B978-0-12-394807-6.00169-6CrossRefGoogle Scholar
  39. Hiloidhari M, Baruah D (2011a) Crop residue biomass for decentralized electrical power generation in rural areas (part 1): investigation of spatial availability. Renew Sustain Energy Rev 15:1885–1892CrossRefGoogle Scholar
  40. Hiloidhari M, Baruah DC (2011b) Rice straw residue biomass potential for decentralized electricity generation: a GIS based study in Lakhimpur district of Assam, India. Energy Sustain Dev 15:214–222CrossRefGoogle Scholar
  41. Hiloidhari M, Das D, Baruah DC (2014) Bioenergy potential from crop residue biomass in India. Renew Sustain Energy Rev 32:504–512CrossRefGoogle Scholar
  42. IARI (2012) Crop residues management with conservation agriculture: potential, constraints and policy needs. Indian Agricultural Research Institute, New Delhi, vii + 32 pGoogle Scholar
  43. Jekayinfa SO, Scholz V (2009) Potential availability of energetically usable crop residues in Nigeria. Energy Sources Part A Recovery Utilization Environ Eff 31:687–697CrossRefGoogle Scholar
  44. Kargbo F, Xing J, Zhang Y (2010) Property analysis and pretreatment of rice straw for energy use in grain drying: a review. Agric Biol J North Am 1(3):195–200CrossRefGoogle Scholar
  45. Kis D, Sucic B, Guberac V, Voca N, Rozman V, Sumanovac L (2009) Soybean biomass as a renewable energy resource. Agric Conspec Sci 74:201–203Google Scholar
  46. Laghari SM, Isa MH, Laghari AJ (2016) Delignification of palm fiber by microwave assisted chemical pretreatment for improving energy efficiency. Malays J Sci 35:8–14CrossRefGoogle Scholar
  47. Le DM, Sørensen HR, Knudsen NO, Schjoerring JK, Meyer AS (2014) Biorefining of wheat straw: accounting for the distribution of mineral elements in pretreated biomass by an extended pretreatment-severity equation. Biotechnol Biofuels 7(1):141Google Scholar
  48. Ludueña L, Fasce D, Alvarez VA, Stefani PM (2011) Nanocellulose from rice husk following alkaline treatment to removesilica. BioResources 6:1440–1453Google Scholar
  49. Mani S, Tabil LG, Sokhansanj S (2006a) Effects of compressive force, particle size and moisture content on mechanical properties of biomass pellets from grasses. Biomass Bioenergy 30:648–654CrossRefGoogle Scholar
  50. Mani S, Tabil LG, Sokhansanj S (2006b) Effects of compressive force, particle size and moisture content on mechanical properties of biomass pellets from grasses. Biomass Bioenergy 30:648–654CrossRefGoogle Scholar
  51. McKendry P (2002) Energy production from biomass (part 1): overview of biomass. Bioresour Technol 83(1):37–46CrossRefGoogle Scholar
  52. Minowa T, Kondo T, Sudirjo ST (1998) Thermochemical liquefaction of Indonesian biomass residues. Biomass Bioenergy 14:517–524CrossRefGoogle Scholar
  53. Motte JC, Escudie R, Beaufils N, Steyer JP, Bernet N, Delgenes JP, Dumas C (2014) Morphological structures of wheat straw strongly impacts its anaerobic digestion. Ind Crops Prod 52:695–701CrossRefGoogle Scholar
  54. National Renewable Energy Laboratory (2009) Renewable energy data book: energy efficiency & renewable energyGoogle Scholar
  55. Nigam PS, Gupta N, Anthwal A (2009) Pre-treatment of agro-industrial residues. In: Nigam PS, Pandey A (eds) Biotechnology for agro-industrial residues utilization, 1 edn. Springer, Netherlands, pp 13–33Google Scholar
  56. Nordin R, Said CMS, Ismail H (2007) Properties of rice husk powder/natural rubber composite. Solid State Sci Technol 15:83–91Google Scholar
  57. Octave S, Thomas D (2009) Biorefinery: toward an industrial metabolism. Biochimie 91:659–664CrossRefGoogle Scholar
  58. Phan BMQ, Duong LT, Nguyen VD, Tran TB, Nguyen MHH, Nguyen LH, Nguyen DA, Luu LC (2014) Evaluation of the production potential of bio-oil from Vietnamese biomass resources by fast pyrolysis. Biomass Bioenergy 62:74–81CrossRefGoogle Scholar
  59. Pilon G (2007) Utilization of Arecanut (Areca catechu) husk for gasification. [MSc. thesis]. Department of Bioresource Engineering, McGill University, MontrealGoogle Scholar
  60. Prassad S, Singh A, Joshi HC (2007a) Ethanol as an alternative fuel from agricultural, industrial and urban residues. Resourc Conserv Recycl 50:1–39CrossRefGoogle Scholar
  61. Prassad S, Singh A, Joshi HC (2007b) Ethanol as an alternative fuel from agricultural, industrial and urban residues. Resourc Conserv Recycl 50:1–39CrossRefGoogle Scholar
  62. Rahman MT (2006) Green energy development model in the St.Martin’s Island and energy from coconut palm biomass, ISBN: 984-8323-02-3Google Scholar
  63. Rai SN, Walli TK, Gupta BN (1989) The chemical composition and nutritive value of rice straw after treatment with urea or Coprinus fimetarius in a solidstate fermentation system. Anita Feed Sci Technol 26:81–92CrossRefGoogle Scholar
  64. Raman S, Mohr A, Helliwell R, Ribeiro B, Shortall O, Smith R, Millar K (2015) Integrating social and value dimensions into sustainability assessment of lignocellulosic biofuels. Biomass Bioenergy 82:49–62.  https://doi.org/10.1016/j.biombioe.2015.04.022CrossRefGoogle Scholar
  65. Raveendran K, Ganesh A, Khilar C (1995) Influence of mineral matter on biomass pyrolysis characteristics. Fuel 74:1812–1822CrossRefGoogle Scholar
  66. Saini JK, Saini R, Tewari L (2015) Lignocellulosic agriculture wastes as biomass feedstocks for second-generation bioethanol production: concepts and recent developments. Biotech 5:337–353Google Scholar
  67. Sanchez C (2009) Lignocellulosic residues: biodegradation and bioconversion by fungi. Biotechnol Adv 27:185–194CrossRefGoogle Scholar
  68. Sarnklong C, Cone JW, Pellikaan W, Hendriks WH (2010) Utilization of rice straw and different treatments to improve its feed value for ruminants: a review. Asian Aust J Anim Sci 23(5):680–692CrossRefGoogle Scholar
  69. Singh G, Ahuja N, Batish M, Capalash N, Sharma P (2008a) Biobleaching of wheat straw-rich soda pulp with alkalophilic laccase from gamma-proteobacterium JB: optimization of process parameters using response surface methodology. Bioresour Technol 99:7472–7479.  https://doi.org/10.1016/j.biortech.2008.02.023CrossRefGoogle Scholar
  70. Singh J, Panesar BS, Sharma SK (2008b) Energy potential through crop biomass using geographical information system—a case study of Punjab. Biomass Bioenergy 32:301–307Google Scholar
  71. Singh RP, Dhaliwal HS, Sidhu HS, Manpreet-Singh YS, Blackwell J (2008c) Economic assessment of the Happy Seeder for rice-wheat systems in Punjab, India. In: Conference Paper, AARES 52nd Annual conference. ACT, Canberra. AustraliaGoogle Scholar
  72. Sokhansanj S, Hess JR (2009) Biomass supply logistics and infrastructure. In: Biofuels, Humana Press, Totowa, NJ, pp 1–25Google Scholar
  73. State of Indian Agriculture (2015–2016) Ministry of Agriculture & Farmers Welfare, Government of IndiaGoogle Scholar
  74. Sun Y, Cheng JJ (2005) Dilute acid pretreatment of rye straw and Bermuda grass for ethanol production. Bioresour Technol 96:1599–1606CrossRefGoogle Scholar
  75. Tao L, Aden A, Elander RT (2013) Economics of pretreatment for biological processing. In: Aqueous pretreatment of plant biomass for biological and chemical conversion to fuels and chemicals. Wiley, Hoboken, pp 311–333.  https://doi.org/10.1002/9780470975831.ch15CrossRefGoogle Scholar
  76. Thomas P, Soren N, Rumjit NP, James JG, Saravanakumar MP (2017) Biomass resources and potential of anaerobic digestion in Indian scenario. Renew Sustain Energy Rev 77:718–730CrossRefGoogle Scholar
  77. WBA Global Bioenergy Statistics (2017). www.worldbioenergy.org. (accessed on 31.1.2018)
  78. Wang MJ, Huang YF, Chiueh PT, Kuan WH, Lo SL (2012) Microwave-induced torrefaction of rice husk and sugarcane residues. Energy 37:177–184CrossRefGoogle Scholar
  79. Wilaipon P (2009) The effects of briquetting pressure on banana-peel briquette and the banana waste in Northern Thailand. Am J App Sci 6:167–171CrossRefGoogle Scholar
  80. World Energy Outlook (2002) International Energy Agency, IEA/OECD, ParisGoogle Scholar
  81. Xu J, Xiong P, He B (2016) Advances in improving the performance of cellulase in ionic liquids for lignocellulose biorefinery. Bioresour Technol 200:961–970.  https://doi.org/10.1016/j.biortech.2015.10.031CrossRefGoogle Scholar
  82. Zabaniotou A, Ioannidou O, Antonakou E, Lappas A (2008) Experimental study of pyrolysis for potential energy, hydrogen and carbon material production from lignocellulosic biomass. Int J Hydrogen Energy 33:2433–2444CrossRefGoogle Scholar
  83. Zhang M, Xie L, Yin Z, Khanal SK, Zhou Q (2016) Biorefinery approach for cassava-based industrial wastes: current status and opportunities. Bioresour Technol 215:50–62.  https://doi.org/10.1016/j.biortech.2016.04.026CrossRefGoogle Scholar

Copyright information

© Springer International Publishing AG, part of Springer Nature 2019

Authors and Affiliations

  • Desikan Ramesh
    • 1
    Email author
  • Iniya Kumar Muniraj
    • 2
  • Kiruthika Thangavelu
    • 3
  • Subburamu Karthikeyan
    • 3
  1. 1.Horticultural College & Research Institute for WomenTamil Nadu Agricultural UniversityTiruchirappalliIndia
  2. 2.Kumaraguru Institute of AgricultureErodeIndia
  3. 3.Agricultural Engineering College and Research InstituteTamil Nadu Agricultural UniversityCoimbatoreIndia

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