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One-Particle Green’s Function

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Book cover Many-Body Methods for Atoms, Molecules and Clusters

Part of the book series: Lecture Notes in Chemistry ((LNC,volume 94))

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Abstract

The one-particle Green’s function or electron propagator, which we shall introduce in this chapter, is the first and simplest member in the hierarchy of many-body Green’s functions Migdal, Theory of Finite Fermi Systems, Wiley-Interscience, New York, 1967, [1], Abrikosov, Gorkov, Dzyaloshinski, Methods of Quantum Field Theory in Statistical Physics, Prentice-Hall, Englewood Cliffs, 1963, [2], Thouless, The Quantum Mechanics of Many-Body Systems. Academic Press, New York, 1961, [3]. While the formal definition looks rather abstract and even forbidding, the benefits afforded by an approach based on the electron propagator should become clear after the theory has been more fully described. Before working through the various derivations, the reader might take a first look at Eqs. (3.24), (3.25) in which the essence of the electron propagator is apparent: Its elements are matrix elements of the many-body resolvent operator taken with respect to states of \(N\!+\!1\) or \(N\!-\!1\) electrons. This indicates that the physics conveyed by the electron propagator relates to excitations of the system following the addition of one electron (electron attachment) or the removal of one electron (ionization). We shall refer exclusively to the electron propagator in much of the book, that is, when we develop the formalism of diagrammatic perturbation theory in Chaps. 47 and establish practical approximation methods in Chaps. 812. The polarization propagator and the physics of N-electron excitations will be considered in the Chap. 1315 of Part IV.

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References

  1. Migdal AB (1967) Theory of finite Fermi systems. Wiley-Interscience, New York

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  2. Abrikosov AA, Gorkov LP, Dzyaloshinski IE (1963) Methods of quantum field theory in statistical physics. Prentice-Hall, Englewood Cliffs

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  3. Thouless DJ (1961) The quantum mechanics of many-body systems. Academic Press, New York

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Correspondence to Jochen Schirmer .

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Schirmer, J. (2018). One-Particle Green’s Function. In: Many-Body Methods for Atoms, Molecules and Clusters. Lecture Notes in Chemistry, vol 94. Springer, Cham. https://doi.org/10.1007/978-3-319-93602-4_3

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