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ADC and ISR Approaches to the Polarization Propagator

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Many-Body Methods for Atoms, Molecules and Clusters

Part of the book series: Lecture Notes in Chemistry ((LNC,volume 94))

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Abstract

The direct adc  procedure presented in Chap. 10 for the \(\varvec{G}^{\pm }(\omega )\) parts of the electron propagator can essentially be transferred to the polarization propagator, where it suffices to deal with \(\varvec{\Pi }^+(\omega )\) due to the redundancy of the two parts. This will be demonstrated in the following. Moreover, in analogy to Chap. 11, the intermediate-state representation (isr), here based on the correlated excited N-electron states, will be established and discussed.

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References

  1. Trofimov AB, Stelter G, Schirmer J (1999) J Chem Phys 111:9982

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  2. Trofimov AB, Stelter G, Schirmer J (2002) J Chem Phys 117:6402

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  3. Harbach PHP, Wormit M, Dreuw A (2014) J Chem Phys 141:064113

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  4. Schirmer J, Trofimov AB (2004) J Chem Phys 120:11449

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Correspondence to Jochen Schirmer .

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Schirmer, J. (2018). ADC and ISR Approaches to the Polarization Propagator. In: Many-Body Methods for Atoms, Molecules and Clusters. Lecture Notes in Chemistry, vol 94. Springer, Cham. https://doi.org/10.1007/978-3-319-93602-4_14

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