Abstract
Recent studies have confirmed the important role of halogens (Cl, F) for the transport of metals in ore deposits related to igneous rocks. New data presented in this Chapter suggest that the halogen contents of mica phenocrysts from high-K igneous suites can be used, with due caution, as a measure of gold-copper mineralization potential in continental, post-collisional, and late oceanic island arcs worldwide. The threshold value for Cl concentration for such micas is about 0.04 wt% or 400 ppm, but F is a poor discriminant, being enriched up to about 4.0 wt% in potassic rocks from both mineralized and un-mineralized environments.
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsReferences
Allan JF, Carmichael ISE (1984) Lamprophyric lavas in the Colima graben, SW Mexico. Contrib Miner Petrol 88:203–216
Anderson AT (1974) Chlorine, sulfur and water in magmas and oceans. Bull Am Geol Society 85:1485–1492
Aoki K, Ishiwaka K, Kanisawa S (1981) Fluorine geochemistry of basaltic rocks from continental and oceanic regions and petrogenetic application. Contrib Miner Petrol 76:53–59
Audetat A, Pettke T (2003) The magmatic-hydrothermal evolution of two barren granites: a melt and fluid inclusion study of the Rito del Medio and Canada Pinabete plutons in southern New Mexico (USA). Geochim Cosmochim Acta 67:97–122
Audétat A, Li W (2017) The genesis of Climax-type porphyry Mo deposits: insights from fluid inclusions and melt inclusions. Ore Geol Rev 88:436–460
Ayati F, Yavuz F, Noghreyan M, Haroni HA, Yavuz A (2008) Chemical characteristics and composition of hydrothermal biotite from the Dalli porphyry copper prospect, Arak, central province of Iran. Mineral Petrol 94:107–122
Bailey DK, Hampton CM (1990) Volatiles in alkaline magmatism. Lithos 26:157–165
Baker DR, Alletti M (2012) Fluid saturation and volatile partitioning between melts and hydrous fluids in crustal magmatic systems: the contribution of experimental measurements and solubility models. Earth Sci Rev 114:298–324
Bao B, Webster JD, Zhang DH, Goldoff BA, Zhang RZ (2016) Compositions of biotite, amphibole, apatite and silicate melt inclusions from the Tongchang mine, Dexing porphy deposit, SE China: implications for the behaviour of halogens in mineralized porphyry systems. Ore Geol Rev 79:443–462
Barnes JD, Manning CE, Scambelluri M, Selverstone J (2018) The behavior of halogens during subduction-zone processes. In: Harlov D, Aranovich L (eds) The role of halogens in terrestrial and extraterrestrial geochemical processes. Springer Verlag Cham, Springer Geochemistry, pp 545–590
Bénard A, Koga KT, Shimizu N, Kendrick MA, Ionov DA, Nebel O, Arculus RJ (2017) Chlorine and fluorine partition coefficients and abundances in sub-arc mantle xenoliths (Kamchatka, Russia): implications for melt generation and volatile recycling processes in subduction zones. Geochim Cosmochim Acta 199:324–350
Bonham HF, Giles DL (1983) Epithermal gold/silver deposits: the geothermal connection. Geotherm Resour Counc Spec Rep 13:257–262
Bonifacie M, Busigny V, Mével C (2008) Chlorine isotopic composition in seafloor serpentinites and high-pressure metaperidotites. Insights into oceanic serpentinization and subduction processes. Geochim Cosmochim Acta 72:126–139
Bonin B, Tatu M (2016) Cl-rich hydrous mafic mineral assemblages in the Highiș massif, Apuseni Mountains, Romania. Mineral Petrol 110:447–469
Botcharnikov RE, Behrens H, Holtz F, Koepke J, Sato H (2004) Sulfur and chlorine solubility in Mt. Unzen rhyodacitic melt at 850 ℃ and 200 MPa. Chem Geol 213:207–225
Botcharnikov RE, Linnen RL, Holtz F (2010) Solubility of Au in Cl- and S-bearing hydrous silicate melts. Geochim Cosmochim Acta 74:2396–2411
Boudreau AE, Mathez EA, McCallum IS (1986) Halogen geochemistry of the Stillwater and Bushveld complexes: evidence for transport of the platinum-group elements by Cl-rich fluids. J Petrol 27:967–986
Bowman JR, Parry WT, Kropp WP, Kruer SA (1987) Chemical and isotopic evolution of hydrothermal solutions at Bingham, Utah. Econ Geol 82:395–428
Brandt FE, Holm PM, Hansteen TH (2018) Volatile (Cl, F and S) and major element constraints on subduction-related mantle metasomatism along the alkaline basaltic backarc, Payenia. Contributions to Mineralogy and Petrology (in press), Argentina
Brenan JM, Bennett NR, Zajacz Z (2016) Experimental results on fractionation of the highly siderophile elements (HSE) at variable pressures and temperatures during planetary and magmatic differentiation. Rev Mineral Geochem 81:1–87
Campbell IH, Compston DM, Richards JP, Johnson JP, Kent AJR (1998) Review of the application of isotopic studies to the genesis of Cu–Au mineralization at Olympic Dam and Au mineralization at Porgera, the Tennant Creek district and Yilgarn Craton. Aust J Earth Sci 45:201–218
Candela PA, Holland HD (1984) The partitioning of copper and molybdenum between silicate melts and aqueous fluids. Geochim Cosmochim Acta 48:373–380
Candela PA (1989) Felsic magmas, volatiles, and metallogenesis. In: Whitney JA, Naldrett AJ (eds) Ore deposition associated with Magmas. Rev Econ Geol 4:223–233
Candela PA (1997) A review of shallow, ore-related granites: textures, volatiles, and ore metals. J Petrol 38:1619–1633
Cao M, Li G, Qin K, Seitmuratova EY, Liu Y (2011) Major and trace element characteristics of apatites in granitoids from central Kazakhstan: implications for petrogenesis and mineralization. Resour Geol 62:63–83
Carmichael ISE, Ghiorso MS (1986) Oxidation-reduction relations in basic magma: a case for homogeneous equilibria. Earth Planet Sci Lett 78:200–210
Carten RB (1987) Evolution of immiscible Cl- and F-rich liquids from ore magmas, Henderson porphyry molybdenum deposit Colorado. Geol Soc Am Abstr 19:613
Chambefort I, Dilles JH, Longo AA (2013) Amphibole geochemistry of the Yanacocha volcanics, Peru: evidence for diverse sources of magmatic volatiles related to gold ores. J Petrol 54:1017–1046
Chavrit D, Burgess R, Sumino H, Teagle DAH, Droop G, Shimizu A, Ballentine CJ (2016) The contribution of hydrothermally altered ocean crust to the mantle halogen and noble gas cycles. Geochim Cosmochim Acta 183:106–124
Chelle-Michou C, Rottier B, Caricchi L, Simpson G (2017) Tempo of magma degassing and the genesis of porphyry copper deposits. Sci Rep 7. https://doi.org/10.1038/srep40566
Chelle-Michou C, Chiaradia M (2018) Amphibole and apatite insights into the evolution and mass balance of Cl and S in magmas associated with porphyry copper deposits. Contrib Mineral Petrol (in press)
Chen JL, Xu JF, Wang BD, Yang ZM, Ren JB, Yu HX, Liu H, Feng Y (2015) Geochemical differences between subduction- and collision-related copper-bearing porphyries and implications for metallogenesis. Ore Geol Rev 70:424–437
Chevychelov VY, Botcharnikov RE, Holtz F (2008) Partitioning of Cl and F between fluid and hydrous phonolitic melt of Mt. Vesuvius at 850–1000 & #xB0; C and 200 MPa. Chem Geol 256:172–184
Cline JS, Bodnar RJ (1991) Can economic porphyry copper mineralization be generated by a typical calc-alkaline melt? J Geophys Res 96:8113–8126
Cocco G, Fanfani L, Zanazzi PF (1972) Potassium. In: Wedepohl KH (ed) Handbook of geochemistry volume II-2. Springer, Berlin
Cooke DR, Kitto PA, Harris AC, Chang Z, Wilkinson JJ, Wilkinson CC, Hollings P, Webster JD (2009) Magma fertility and mineralization. In: Williams PJ (ed) Smart science for exploration and mining. Proceedings of the tenth Biannial SGA Meeting, Townsville, 8–10
Coulson IM, Dipple GM, Raudsepp M (2001) Evolution of HF and HCl activity in magmatic volatiles of the gold-mineralized Emerald Lake pluton, Yukon Territory, Canada. Mineral Depos 36:594–606
Denis CMM, Demouchy S, Alard O (2018) Heterogeneous hydrogen distribution in orthopyroxene from veined mantle peridotite (San Carlos, Arizona): impact of melt-rock interactions. Lithos 303:298–311
Dilles JH, Kent AJR, Wooden JL, Tosdal RM, Koleszar A, Lee RG, Farmer LP (2015) Zircon compositional evidence for sulphur-degassing from ore-forming arc magmas. Econ Geol 110:241–251
Dixon TH, Batiza R (1979) Petrology and chemistry of recent lavas in the N-Marianas: implications for the origin of island-arc basalts. Contrib Miner Petrol 70:167–181
Dixon JE, Clague DA, Wallace P, Poreda R (1997) Volatiles in alkali basalts from the North Arch volcanic field, Hawaii: extensive degassing of deep submarine-erupted alkali series lavas. J Petrol 38:911–939
Duan DF, Jiang SY (2018) Using apatite to discriminate synchronous ore-associated and barren granitic rocks: a case study from the Edong metallogenic district, South China. Lithos (in press)
Edgar AD, Arima M (1985) Fluorine and chlorine contents of phlogopites crystallized from ultrapotassic rock compositions in high pressure experiments: implications for halogen reservoirs in source regions. Am Mineral 70:529–536
Edgar AD, Charbonneau HE (1991) Fluorine-bearing phases in lamproites. Miner Petrol 44:125–149
Edgar AD, Lloyd FE, Vukadinovic D (1994) The role of fluorine in the evolution of ultrapotassic magmas. Miner Petrol 51:173–193
Foley SF (1992) Petrological characterization of the source components of potassic magmas: geochemical and experimental constraints. Lithos 28:187–204
Foley SF (1994) Geochemische und experimentelle Untersuchungen zur Genese der kalireichen Magmatite. Neues Jb Mineralogie Abh 167:1–55
Franz L, Becker KP, Kramer W, Herzig PM (2002) Metasomatic mantle xenoliths from the Bismarck Microplate (Papua New Guinea)—Thermal evolution, geochemistry and extent of slab-induced metasomatism. J Petrol 43:315–343
Fuge R, Andrews MJ, Johnson CC (1986) Chlorine and iodine, potential pathfinder elements in exploration geochemistry. Appl Geochem 1:111–116
Gaillard N, Williams-Jones AE, Clark JR, Lypaczewski P, Salvi S, Perrouty S, Piette-Lauzière N, Guilmette C, Linnen RL (2018) Mica composition as a vector to gold mineralization: deciphering hydrothermal and metamorphic effects in the Malartic district, Quebec. Ore Geol Rev 95:789–820
Gammons CH, Williams-Jones AE (1997) Chemical mobility of gold in the porphyry-epithermal environment. Econ Geol 92:45–59
Gibert F, Pascal ML, Pichavant M (1998) Gold solubility and speciation in hydrothermal solutions: experimental study of the stability of hydrosulphide complex of gold (AuHS0) at 350 to 450 ℃ and 500 bars. Geochimica Cosmochimica Acta 62:2931–2947
Green TH, Adam J (2003) Experimentally-determined trace element characteristics of aqueous fluid from partially dehydrated mafic oceanic crust at 3.0 GPa, 650–700 ℃. Eur J Mineral 15:815–830
Grondahl C, Zajacz S (2017) Magmatic controls on the genesis of porphyry Cu–Mo–Au deposits: the Bingham Canyon example. Earth Planetary Sci Letters 480:53–65
Gunow AJ, Ludington S, Munoz JL (1980) Fluorine in micas from the Henderson molybdenite deposit, Colorado. Econ Geol 75:1127–1136
Hayashi KI, Ohmoto H (1991) Solubility of gold in NaCl- and H2S-bearing aqueous solutions at 250–350 ℃. Geochim Cosmochim Acta 55:2111–2126
Hayba DO, Bethke PM, Heald P, Foley NK (1985) Geologic, mineralogic and geochemical characteristics of volcanic-hosted precious-metal deposits. In: Berger BR, Bethke PM (eds) Geology and geochemistry of epithermal systems. Rev Econ Geol 2:129–167
Heald P, Foley NK, Hayba DO (1987) Comparative anatomy of volcanic-hosted epithermal deposits: acid-sulfate and adularia-sericite types. Econ Geol 82:1–24
Heinrich CA (2005) The physical and chemical evolution of low-salinity magmatic fluids at the porphyry to epithermal transition: a thermodynamic study. Mineral Deposita 39:864–889
Hermann J, Spandler CJ (2008) Sediment melts at sub-arc depths: an experimental study. J Petrol 49:717–740
Hezarkhani A, Williams-Jones AE (1998) Controls of alteration and mineralization in the Sungun porphyry copper deposit, Iran; evidence from fluid inclusions and stable isotopes. Econ Geol 93:651–670
Holland HD (1972) Granites, solutions, and base-metals. Econ Geol 67:281–301
Iveson AA, Webster JD, Rowe MC, Neill OK (2017) Major element and halogen (F, Cl) mineral-melt-fluid partitioning in hydrous rhyodacitic melts at shallow crustal conditions. J Petrol 58:2465–2492
Izraeli ES, Harris JW, Navon O (2001) Brine inclusions in diamonds: a new upper mantle fluid. Earth Planet Sci Lett 187:323–332
Jenner FE, O´Neill HSC (2012) Analysis of 60 elements in 616 ocean floor basaltic glasses. Geochem, Geophys, Geosystems 13. https://doi.org/10.1029/2011gc004009
Jensen EP (2003) Magmatic and hydrothermal evolution of the Cripple Creek gold deposit, Colorado, and comparisons with regional and global magmatic-hydrothermal systems associated with alkaline magmatism. Unpublished Ph.D. thesis, The University of Arizona, Tucson
Jiang SY, Palmer MR, Xue CJ, Li YH (1994) Halogen-rich scapolite-biotite rocks from the Tongmugou Pb–Zn deposit, Qinling, northwestern China: implications for the ore-forming processes. Miner Mag 58:543–552
Jin C, Gao XY, Chen WT, Zhao TP (2018) Magmatic-hydrothermal evolution of the Donggou porphyry Mo deposit at the southern margin of the North China Craton: evidence from chemistry of biotite. Ore Geol Rev 92:84–96
John T, Scambelluri M, Frische M, Barnes JD, Bach W (2011) Dehydration of subducting serpentinite: implications for halogen mobility in subduction zones and the deep halogen cycle. Earth Planet Sci Lett 308:65–76
Kelley KD, Ludington S (2002) Cripple Creek and other alkaline-related gold deposits in the southern Rocky Mountains, USA: influence of regional tectonics. Mineral Depos 37:38–60
Keppler H (2017) Fluids and trace element transport in subduction zones. Am Miner 102:5–20
Kesler SE, Issigonis MJ, Brownlow AH, Damon PE, Moore WJ, Northcote KE, Preto VA (1975) Geochemistry of biotites from mineralized and barren intrusive systems. Econ Geol 70:559–567
Kilinc IA, Burnham CW (1972) Partitioning of chloride between a silicate melt and coexisting aqueous phase from 2 to 8 kilobars. Econ Geol 67:231–235
Kobayashi M, Sumino H, Nagao K, Ishimaru S, Arai S, Yoshikawa M, Kawamoto T, Kumagai Y, Kobayashi T, Burgess R, Ballentine CJ (2017) Slab-derived halogens and noble gases illuminate closed system processes controlling volatile element transport into the mantle wedge. Earth Planet Sci Lett 457:106–116
Kouzmanov K, Pokrovski GS (2012) Hydrothermal controls on metal distribution in porphyry Cu (-Mo-Au) systems. Econ Geol Special Publ 16:573–618
Kravchuk IF, Keppler H (1994) Distribution of chloride between aqueous fluids and felsic melts at 2 kbar and 800 ℃. Eur J Mineral 6:913–923
Krneta S, Ciobanu CL, Cook NJ, Ehrig K, Kontonikas-Charos A (2016) Apatite at Olympic Dam, South Australia: a petrogenetic tool. Lithos 262:470–485
Kroll T, Müller D, Seifert T, Herzig PM, Schneider A (2002) Petrology and geochemistry of the shoshonite-hosted Skouries porphyry Cu–Au deposit, Chlalkidiki, Greece. Mineral Depos 37:137–144
Kullerud K (1995) Chlorine, titanium and barium-rich biotites: factors controlling biotite composition and the implications for garnet-biotite geothermometry. Contrib Miner Petrol 120:42–59
Large RR, Huston DL, McGoldrick PJ, Ruxton PA (1989) Gold distribution and genesis in Australian volcanogenic massive sulphide deposits and their significance for gold transport models. In: Keays RR, Ramsay WRH, Groves DI (eds) The geology of gold deposits: the perspective in 1988. Econ Geol Monogr 6:520–536
Lee RG (2008) Genesis of the EI Salvador porphyry copper deposit, Chile and distribution of epithermal alteration at Lassen Peak, California. Unpupl. PhD Thesis, Oregon State University, Corvallis, USA
Lesne P, Kohn SC, Blundy J, Witham F, Botcharnikov RE, Behrens H (2011) Experimental simulation of closed-system degassing in the system basalt-H2O–CO2–S–Cl. J Petrol 52:1737–1762
Li Y, Audetat A (2013) Gold solubility and partitioning between sulfide liquid, monosulfide solid solution and hydrous mantle melts: implications for the formation of Au-rich magmas and crust-mantle differentiation. Geochim Cosmochim Acta 118:247–262
Li H, Hermann J (2017) The effect of fluorine and chlorine on trace element partitioning between apatite and sediment melt at subduction zone conditions. Chem Geol 473:55–73
Li X, Zhang C, Behrens H, Holtz F (2017) Fluorine partitioning between titanite and silicate melt and its dependence on melt composition: experiments at 50–200 MPa and 875–925 ℃. Eur J Mineral 29:1–12
Li JX, Qin KZ, Li GM, Evans NJ, Zhao JX, Yue YH, Xie J (2018) Volatile variations in magmas related to porphyry Cu-Au deposits: insights from amphibole geochemistry, Duolong district, central Tibet. Ore Geol Rev 95:649–662
Liang Y, Hoshino K (2015) Thermodynamic calculations of AuxAg1-x—fluid equilibria and their applications for ore-forming conditions. Appl Geochem 52:109–117
Liu J, Li Y, Zhou ZH, OuYang HG (2017a) The Ordovician igneous rocks with high Sr/Y at the Tongshan porphyry copper deposit, satellite of the Duobaoshan deposit, and their metallogenic role. Ore Geol Rev 86:600–614
Liu XL, Li WC, Zhang N, Yang FC (2017b) Geochemistry and petrogenesis of Triassic mineralized porphyries in the Geza of the Sanjiang orogenic belt, southwestern China. Int Geol Rev 59:965–980
Lofersky PJ, Ayuso RA (1995) Petrography and mineral chemistry of the composite Deboullie pluton, northern Maine, USA: implications for the genesis of Cu–Mo mineralization. Chem Geol 123:89–105
Lowenstern JB (1994) Dissolved volatile concentrations in an ore-forming magma. Geology 22:893–896
Lyubetskaya T, Korenaga J (2007) Chemical composition of Earth’s primitive mantle and its variance: 1. Methods and results. J Geophys Res 112. http://dx.doi.org/10.1029/2005JB004223
Magenheim AJ, Spivack AJ, Michael PJ, Gieskes JM (1995) Chlorine stable isotope composition of the oceanic crust: implications for Earth’s distribution of chlorine. Earth Planet Sci Lett 131:427–432
Mair P, Tropper P, Harlov DE, Manning CE (2017) The solubility of apatite in H2O, KCl–H2O, NaCl–H2O at 800 ℃ and 1.0 GPa: implications for REE mobility in high-grade saline brines. Chem Geol 470:180–192
Mao M, Rukhlov AS, Rowins SM, Spence J, Coogan LA (2016) Apatite trace element compositions: a robust new tool for mineral exploration. Econ Geol 111:1187–1222
Mavrogenes JA, Scaillet B, Pichavant M, England RN (2006) The connection between high-K melts and Au deposits: evidence from natural and experimental systems. Geochim Cosmochim Acta 70:A404
Melluso L, de Gennaro R, Fedele L, Franciosi L, Morra V (2012) Evidence of crystallization in residual, Cl–F-rich, agpaitic, trachyphonolitic magmas and primitive Mg-rich basalt-trachyphonolite interaction in the lava domes of the Phlegrean Fields (Italy). Geol Mag 149:532–550
Metrich N, Rutherford MJ (1992) Experimental study of chlorine behavior in hydrous silicic melts. Geochim Cosmochim Acta 56:607–616
Müller D (1993) Shoshonites and potassic igneous rocks: indicators for tectonic setting and mineralization potential of modern and ancient terranes. Unpublished Ph.D. thesis, The University of Western Australia, Perth
Müller D, Groves DI (1993) Direct and indirect associations between potassic igneous rocks, shoshonites and gold-copper deposits. Ore Geol Rev 8:383–406
Müller D, Morris BJ, Farrand MG (1993) Potassic alkaline lamprophyres with affinities to lamproites from the Karinya Syncline, South Australia. Lithos 30:123–137
Müller D, Heithersay PS, Groves DI (1994) The shoshonite porphyry Cu–Au association in the Goonumbla district, N.S.W Australia. Miner Petrol 51:299–321
Müller D, Franz L, Herzig PM, Hunt S (2001) Potassic igneous rocks from the vicinity of epithermal gold mineralization, Lihir Island, Papua New Guinea. Lithos 57:163–186
Müller D, Herzig PM, Scholten JC, Hunt S (2002) Ladolam gold deposit, Lihir Island, Papua New Guinea: gold mineralization hosted by alkaline rocks. Econ Geol Spec Publ 9:367–382
Müller D, Franz L, Petersen S, Herzig PM, Hannington MD (2003) Comparison between magmatic activity and gold mineralization at Conical Seamount and Lihir Island, Papua New Guinea. Miner Petrol 79:259–283
Munoz JL (1984) F–OH and Cl–OH exchange in micas with applications to hydrothermal ore deposits. In: Bailey SW (ed) Micas. American mineralogical society. Michigan, Rev Mineral 13:469–493
Munoz JL (2008) Calculation of HF and HCL fugacities from biotite compositions: revised equations. Goel Soc Am Abs Programs 24:A221
Nadeau O, Stix J, Williams-Jones AE (2016) Links between arc volcanoes and porphyry-epithermal ore deposits. Geology 44:11–14
Naumov VB, Kovalenko VI, Dorofeeva VA (1998) Fluorine concentration in magmatic melts: evidence from inclusions in minerals. Geochem Int 36:117–127
Pagé L, Hattori K, De Hoog JCM, Okay AI (2016) Halogen (F, Cl, Br, I) behaviour in subducting slabs: a study of lawsonite blueschists in western Turkey. Earth Planet Sci Lett 442:133–142
Parry WT, Ballantyne GH, Wilson JC (1978) Chemistry of biotites and apatites from a vesicular quartzlatite porphyry plug at Bingham, Utah. Econ Geol 73:1308–1314
Peach CL, Mathez EA, Keays RR, Reeves SJ (1994) Experimentally determined sulphide melt-silicate melt partition coefficients for iridium and palladium. Chem Geol 117:361–377
Philippot P, Selverstone J (1991) Trace-element-rich brines in eclogitic veins: implications for fluid composition and transport during subduction. Contrib Miner Petrol 106:417–430
Richards JP (1990a) Petrology and geochemistry of alkaline intrusive at the Porgera gold deposit, Papua New Guinea. J Geochem Explor 35:141–199
Richards JP (1990b) The Porgera gold deposit, Papua New Guinea: geology, geochemistry and geochronology. Unpublished Ph.D. thesis, The Australian National University, Canberra
Richards JP (1995) Alkalic-type epithermal gold deposits—a review. In: Thompson JFH (ed) Magmas, fluids, and ore deposits, vol 23. Mineralogical Association of Canada, Toronto, Short Course Handbook, pp 367–400
Richards JP (2009) Postsubduction porphyry Cu–Au and epithermal Au deposits: products of remelting of subduction-modified lithosphere. Geology 37:247–250
Richards JP (2011) High Sr/Y arc magmas and porphyry Cu ± Mo ± Au deposits: just add water. Econ Geol 106:1075–1081
Richards JP, McCulloch MT, Chappell BW, Kerrich R (1991) Sources of metals in the Porgera gold deposit, Papua New Guinea: evidence from alteration, isotope, and noble metal geochemistry. Geochim Cosmochim Acta 55:565–580
Righter K, Dyar MD, Delaney JS, Vennemann TW, Hervig RL, King PL (2002) Correlations of octahedral cations with OH-, O2-, Cl-, and F- in biotite from volcanic rocks and xenoliths. Am Miner 87:142–153
Riker J, Humphreys MCS, Brooker RA, De Hoog JCM (2018) First measurements of OH-C exchange and temperature-dependent partitioning of OH and halogens in the system apatite-silicate melt. Am Miner 103:260–270
Roberge M, Bureau H, Bolfan-Casanova N, Frost DJ, Raepsaet C, Surble S, Khodja H, Auzende AL, Fiquet G (2015) Is the transition zone a deep reservoir for fluorine? Earth Planet Sci Lett 429:25–32
Rock NMS, Groves DI (1988) Do lamprophyres carry gold as well as diamonds? Nature 332:253–255
Rock NMS, Duller P, Haszeldine S, Groves DI (1987) Lamprophyres as potential gold exploration targets: some preliminary observations and speculations. In: Ho SE, Groves DI (eds) Recent advances in understanding Precambrian gold deposits, vol 11. Geology Department and University Extension, The University of Western Australia Publication, pp 271–286
Roedder E (1984) Fluid inclusions. Mineral Soc Am, Rev Mineral 12:1–644
Roegge JS, Logsdon MJ, Young HS, Barr HB, Borcsik M, Holland HD (1974) Halogens in apatites from the Providencia area, Mexico. Econ Geol 69:229–240
Runyon SE, Steele-MacInnis M, Seedorff E, Lecumberri-Sanchez P, Mazdab FK (2017) Coarse muscovite veins and alteration deep in the Yerington batholith, Nevada: insights into fluid exsolution in the roots of porphyry copper systems. Miner Deposita 52:463–470
Sarjoughian F, Kananian A, Ahmadian J, Murata M (2015) Chemical composition of biotite from the Kuh-e Dom pluton, central Iran: implications for granitoid magmatism and related Cu–Au mineralization. Arab J Geosci 8:1521–1533
Satsukawa T, Godard M, Demouchy S, Michibayashi K, Ildefonse B (2017) Chemical interactions in the subduction factory: new insights from an in situ trace element and hydrogen study of the Ichinomegata and Oki-Dogo mantle xenoliths (Japan). Geochim Cosmochim Acta 208:234–267
Selby D, Nesbitt BE (2000) Chemical composition of biotite from the Casino porphury Cu-Au-Mo mineralization, Yukon, Canada: evaluation of magmatic and hydrothermal fluid chemistry. Chem Geol 171:77–93
Shabani AAT, Lalonde A, Whalen JB (2003) Composition of biotite from granitic rocks of the Canadian Appalachian orogen: a potential tectonomagmatic indicator? Can Mineral 41:1381–1396
Shannon RD (1976) Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallogr A 32:751–767
Shinohara H (1994) Exsolution of immiscible vapour and liquid phases from a crystallizing silicate melt: implications for chlorine and metal transport. Geochim Cosmochim Acta 58:5215–5221
Shinohara H (2009) A missing link between volcanic degassing and experimental studies on chloride partitioning. Chem Geol 263:51–59
Shishkina TA, Portnyagin MV, Botcharnikov RE, Almeev RR, Simonyan AV, Garbe-Schönberg D, Schuth S, Oeser M, Holtz F (2018) Experimental calibration and implications of olivine-melt vanadium oxybarometry for hydrous basaltic arc magmas. Am Miner 103:369–383
Siahcheshm K, Calagari AA, Abedini A, Lentz DR (2012) Halogen signatures of biotites from the Maher-Abad porphyry copper deposit, Iran: characterization of volatiles in syn- to post-magmatic hydrothermal fluids. Int Geol Rev 54:1353–1368
Sillitoe RH (2002) Some metallogenic features of gold and copper deposits related to alkaline rocks and consequences for exploration. Min Depos 37:4–13
Sliwinski JT, Ellis BS, Dávila-Harris P, Wolff JA, Olin PH, Bachmann O (2017) The use of biotite trace element compositions for fingerprinting magma batches at Las Cañadas volcano Tenerife. Bull Volcanol 79:1. https://doi.org/10.1007/s00445-016-1088-2
Solomon M, Groves DI (1994) The geology and origin of Australia’s mineral deposits, vol 24. Clarendon Press, New York, Oxford Monographs in Geology and Geophysics, 951 pp
Spear JA (1984) Micas in igneous rocks. In: Bailey SW (ed) Micas. American Mineralogical Society, Michigan. Rev Mineral 13:299–349
Spooner ETC (1993) Magmatic sulphide/volatile interaction as a mechanism for producing chalcophile element-enriched, Archaean Au-quartz hydrothermal ore fluids. Ore Geol Rev 7:359–379
Stanton RL (1994) Ore elements in arc lavas, vol 29. Clarendon Press, New York, Oxford Mono Geol Geophys, 391 pp
Stock MJ, Humphreys MCS, Smith VCS, Isaia R, Brooker RA, Pyle DM (2018) Tracking volatile behaviour in sub-volcanic plumbing systems using apatite. J Petrol (in press)
Stollery G, Borcsik M, Holland HD (1971) Chlorine in intrusions: a possible prospecting tool. Econ Geol 66:361–367
Sullivan NA, Zajacz Z, Brenan JM (2018) The solubility of Pd and Au in hydrous intermediate silicate melts: the effect of oxygen fugacity and the addition of Cl and S. Geochimica et Cosmochimica Acta 231:15–29
Sun W, Arculus RJ, Kamenetsky VS, Binns RA (2004) Release of gold-bearing fluids in convergent margin magmas prompted by magnetite crystallization. Nature 431:975–978
Sun WD, Liang HY, Ling MX, Zhan MZ, Ding X, Zhang H, Yang XY, Li YL, Ireland TR, Wei QR, Fan WM (2013) The link between reduced porphyry copper deposits and oxidized magmas. Geochim Cosmochim Acta 103:263–275
Sun X, Lin H, Fu Y, Li D, Hollings P, Yang T, Liu Z (2017a) Trace element geochemistry of magnetite from the giant Beiya gold-polymetallic deposit in Yunnan Province, southwest China and its implications for the ore forming processes. Ore Geol Rev 91:477–490
Sun X, Zheng Y, Xu J, Huang L, Guo F, Gao S (2017b) Metallogenesis and ore controls of Cenozoic porphyry Mo deposits in the Gangdese belt of southern Tibet. Ore Geol Rev 81:996–1014
Sun Y, Liu J, Zeng Q, Wang J, Wang Y, Hu R, Zhou L, Wu G (2017c) Mo-mineralized porphyries are relatively hydrous and differentiated: insights from the Permian-Triassic granitic complex in the Baituyingzi Mo–Cu district, eastern Inner Mongolia, NE China. Miner Deposita 52:799–821
Tao R, Zhang L, Liu X, Bader T, Fei Y (2017) Phase relations and formation of K-bearing Al-10 Å phase in the MORB + H2O system: implications for H2O- and K-cycles in subduction zones. Am Miner 102:1922–1933
Tapster S, Condon DJ, Naden J, Noble SR, Petterson MG, Roberts NMW, Saunders AD, Smith DJ (2016) Rapid thermal rejuvenation of high-crystallinity magma linked to porphyry copper deposit formation; evidence from the Koloula porphyry prospect, Solomon Islands. Earth Planet Sci Lett 442:206–217
Tatsumi Y, Koyaguchi T (1989) An absarokite from a phlogopite lherzolite source. Contrib Miner Petrol 102:34–40
Taylor BE (2007) Epithermal gold deposits. In: Goodfellow WD (Ed) Mineral deposits of Canada: a synthesis of major deposit-types, district metallogeny, the evolution of geological provinces, and exploration methods. Geol Assoc Can, Mineral Deposits Division, Special Publications 5:113–139
Taylor WR, Rock NMS, Groves DI, Perring CS, Golding SD (1994) Geochemistry of Archaean shoshonitic lamprophyres from the Yilgarn Block, Western Australia: Au abundance and association with gold mineralization. Appl Geochem 9:197–222
Teiber H, Scharrer M, Marks MAW, Arzamastev AA, Wenzel T, Markl G (2015) Equilibrium partitioning and subsequent re-distribution of halogens among apatite-biotite-amphibole assemblages from mantle-derived plutonic rocks: complexities revealed. Lithos 223:221–237
Thompson TB, Trippel AD, Dwelley PC (1985) Mineralized veins and breccias of the Cripple Creek District, Colorado. Econ Geol 80:1669–1688
Till CB (2017) A review and update of mantle thermobarometry for primitive arc magmas. Am Miner 102:931–947
Touret JLR (2001) Fluids in metamorphic rocks. Lithos 55:1–25
Ulrich T, Mavrogenes J (2008) An experimental study of the solubility of molybdenum in H2O and KCl–H2O solutions from 500 ℃ to 800 ℃, and 150 to 300 MPa. Geochim Cosmochim Acta 72:2316–2330
Urann BM, Le Roux V, Hammond K, Marschall HR, Lee CTA, Monteleone BD (2018) Fluorine and chlorine in mantle minerals and the halogen budget of the earth’s mantle. Contrib Miner Petrol (in press)
Valente DL (2008) The geology, geochemistry and geochronology of the EI Abra mine, Chile, and the adjacent Pajonal–EI Abra suite of intrusions. Unpl. PhD Thesis, Australian National University, Canberra, Australia
Van den Bleeken G, Koga KT (2015) Experimentally determined distribution of fluorine and chlorine upon hydrous slab melting, and implications for F-Cl cycling through subduction zones. Geochim Cosmochim Acta 171:353–373
Vigneresse JL (2009) Evaluation of the chemical reactivity of the fluid phase through hard-soft acid-base concepts in magmatic intrusions with applications to ore generation. Chem Geol 263:69–81
Vigneresse JL, Truche L, Chattaraj PK (2014) Metal (copper) segregation in magmas. Lithos 209:462–470
Vukadinovic D, Edgar AD (1993) Phase relations in the phlogopite-apatite system at 20 kbar—implications for the role of fluorine in mantle melting. Contrib Miner Petrol 114:247–254
Wallace PJ (2005) Volatiles in subduction zone magmas: concentrations and fluxes based on melt inclusion and volcanic gas data. J Volcanol Geoth Res 140:217–240
Wang L, Marks MAW, Keller J, Markl G (2014) Halogen variations in alkaline rocks from the Upper Rhine Graben (SW Germany): insights into F, Cl and Br behavior during magmatic processes. Chem Geol 380:133–144
Webster JD (1992) Water solubility and chlorine partitioning in Cl-rich granitic systems: effects of melt composition at 2 kbar and 800 ℃. Geochim Cosmochim Acta 56:679–687
Webster JD (1997) Chloride solubility in felsic melts and the role of chloride in magmatic degassing. J Petrol 38:1793–1807
Webster JD (2004) The exsolution of magmatic hydrosaline chloride liquids. Chem Geol 210:33–48
Webster JD, Holloway JR (1988) Experimental constraints on the partitioning of Cl between topaz rhyolite melt and H2O and H2O + CO2 fluids: implications for granitic differentiation and ore deposition. Geochim Cosmochim Acta 52:2091–2105
Webster JD, Holloway JR (1990) Partitioning of F and Cl between magmatic hydrothermal fluids and highly evolved granitic magmas. In: Stein HJ, Hannah JL (eds) Ore-bearing granite systems; petrogenesis and mineralizing processes. Geol Soc Am Spec Pap 246:21–33
Webster JD, Tappen CM, Mandeville CW (2009) Partitioning behavior of chlorine and fluorine in the system apatite-melt-fluid. II: felsic silicate systems at 200 MPa. Geochim Cosmochim Acta 73:559–581
Webster JD, Goldoff B, Sintoni MF, Shimizu N, Vivo BD (2014) C-O–H–Cl–S–F volatile solubilities, partitioning, and mixing in phonolithic-trachytic melts and aqueous-carbonic vapor ± saline liquid at 200 MPa. J Petrol 55:2217–2248
Webster JD, Baker DR, Aiuppa A (2018) Halogens in mafic and intermediate-silica content magmas. In: Harlov D, Aranovich L (eds) The role of halogens in terrestrial and extraterrestrial geochemical processes. Springer Verlag Cham, pp 307–430
White WH, Bookstrom AA, Kamilli RJ, Ganster MW, Smith RP, Ranta DE, Steininger RC (1981) Character and origin of Climax-type molybdenum deposits. Econ Geol 75th Anniversary Volume, pp 270–316
Williams-Jones AE, Heinrich CA (2005) Vapor transport of metals and the formation of magmatichydrothermal ore deposits. Econ Geol 100:1287–1312
Wu J, Koga KT (2013) Fluorine partitioning between hydrous minerals and aqueous fluid at 1GPa and 770–947 ℃: a new constraint on slab flux. Geochim Cosmochim Acta 119:77–92
Wyman D, Kerrich R (1989) Archaean lamprophyre dykes of the Superior Province, Canada: distribution, petrology and geochemical characteristics. J Geophys Res 94:4667–4696
Xie F, Tang J, Chen Y, Lang X (2018) Apatite and zircon geochemistry of Jurassic porphyries in the Xiongcun district, southern Gangdese porphyry copper belt: implications for petrogenesis and mineralization. Ore Geol Rev (in press)
Yang K, Bodnar RJ (1994) Magmatic-hydrothermal evolution in the “bottoms” of porphyry copper systems: evidence from silicate melt and aqueous fluid inclusions in granitoid intrusions in the Gyeongsang Basin, South Korea. Int Geo Rev 36:608–628
Yang XM, Lentz DR (2005) Chemical composition of rock-forming minerals in gold-related granitoid intrusions, southwestern New Brunswick, Canada: implications for crystallization conditions, volatile exsolution, and fluorine-chlorine activity. Contrib Miner Petrol 150:287–305
Zajacz Z, Seo JH, Candela PA, Piccoli PM, Heinrich CA, Guillong M (2010) Alkali metals control the release of gold from volatile-rich magmas. Earth Planet Sci Lett 297:50–56
Zajacz Z, Seo JH, Candela PA, Piccoli PM, Tossell JA (2011) The solubility of copper in high-temperature magmatic vapors: a quest for the significance of various chloride and sulfide complexes. Geochim Cosmochim Acta 75:2811–2827
Zajacz Z, Candela PA, Piccoli PM, Wälle M, Sanchez-Valle C (2012) Gold and copper in volatile saturated mafic to intermediate magmas: solubilities, partitioning, and implications for ore deposit formation. Geochim Cosmochim Acta 91:140–159
Zellmer GF, Edmonds M, Straub SM (2015) The role of volatiles in the genesis, evolution and eruption of arc magmas. Geol Soc Spec Publ 410:292 pp
Zhang D, Audetat A (2017) Chemistry, mineralogy and crystallization conditions of porphyry Mo-forming magmas at Urad-Henderson and Silver Creek, Colorado, USA. J Petrol 58:277–296
Zhang M, Suddaby P, Thompson RN, Thirlwall MF, Menzies MA (1995) Potassic volcanic rocks in NE China: geochemical constraints on mantle source and magma genesis. J Petrol 36:1275–1303
Zhang W, Lentz DR, Thorne KG, McFarlane C (2016) Geochemical characteristics of biotite from felsic intrusive rocks around the Sisson Brook W–Mo–Cu deposit, west-central New Brunswick: an indicator of halogen and oxygen fugacity of magmatic systems. Ore Geol Rev 77:82–96
Zhong S, Feng C, Seltmann R, Dai Z (2018) Geochemical contrasts between late Triassic ore-bearing and barren intrusions in the Weibao Cu–Pb–Zn deposit, east Kunlun Mountains, NW China: constraints from accessory minerals (zircon and apatite). Miner Deposita (in press)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
Copyright information
© 2019 Springer International Publishing AG, part of Springer Nature
About this chapter
Cite this chapter
Müller, D., Groves, D.I. (2019). Halogen Contents of Mineralized Versus Unmineralized Potassic Igneous Rocks. In: Potassic Igneous Rocks and Associated Gold-Copper Mineralization. Mineral Resource Reviews. Springer, Cham. https://doi.org/10.1007/978-3-319-92979-8_9
Download citation
DOI: https://doi.org/10.1007/978-3-319-92979-8_9
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-92978-1
Online ISBN: 978-3-319-92979-8
eBook Packages: Earth and Environmental ScienceEarth and Environmental Science (R0)