Abstract
Polymer electrolyte fuel cells (PEFCs) have received a great deal of attention for their utility in applications such as transportation, portable devices, and combined heat and power systems due to their energy efficiency and scalability. The cost and scarcity of platinum is a major obstacle to the globalization of PEFCs; therefore, it is necessary to develop non-precious metal (NPM) cathode catalysts. This chapter provides an overview of the recent progress on the research and development of NPM oxygen reduction reaction (ORR) catalysts for PEFCs. The first half describes carbon-based Fe/N/C and N/C cathode catalysts, which are prepared by pyrolyzing Fe, N, and C-containing precursors. Nanocarbon with Fe and N-based active sites, which are synthesized in the pyrolysis of polyimide nanoparticles, are of particular interest. The second half of the chapter describes the research on cathode catalysts prepared by combining group 4 and 5 oxides with nanocarbons. In this catalyst design, the nanocarbon plays an important role in increasing the electrical conductivity of the catalyst layers while the oxide contributes to the ORR.
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Acknowledgements
The majority of the authors’ research described in this chapter was financially supported by the New Energy and Industrial Technology Development Organization (NEDO).
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Nabae, Y., Ishihara, A. (2019). Recent Progress in Non-precious Metal Fuel Cell Catalysts. In: Nakashima, N. (eds) Nanocarbons for Energy Conversion: Supramolecular Approaches. Nanostructure Science and Technology. Springer, Cham. https://doi.org/10.1007/978-3-319-92917-0_11
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