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Recent Progress in Non-precious Metal Fuel Cell Catalysts

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Part of the book series: Nanostructure Science and Technology ((NST))

Abstract

Polymer electrolyte fuel cells (PEFCs) have received a great deal of attention for their utility in applications such as transportation, portable devices, and combined heat and power systems due to their energy efficiency and scalability. The cost and scarcity of platinum is a major obstacle to the globalization of PEFCs; therefore, it is necessary to develop non-precious metal (NPM) cathode catalysts. This chapter provides an overview of the recent progress on the research and development of NPM oxygen reduction reaction (ORR) catalysts for PEFCs. The first half describes carbon-based Fe/N/C and N/C cathode catalysts, which are prepared by pyrolyzing Fe, N, and C-containing precursors. Nanocarbon with Fe and N-based active sites, which are synthesized in the pyrolysis of polyimide nanoparticles, are of particular interest. The second half of the chapter describes the research on cathode catalysts prepared by combining group 4 and 5 oxides with nanocarbons. In this catalyst design, the nanocarbon plays an important role in increasing the electrical conductivity of the catalyst layers while the oxide contributes to the ORR.

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References

  1. Jasinski R (1964) A new fuel cell cathode catalyst. Nature 201:1212–1213

    Article  Google Scholar 

  2. Masa J, Ozoemena KI, Schuhmann W, Zagal JH (2013) Fundamental studies on the electrocatalytic properties of metal macrocyclics and other complexes for the electroreduction of O2. Springer, London, pp 157–212

    Google Scholar 

  3. Jahnke H, Schönborn M, Zimmermann G (1976) Organic dyestuffs as catalysts for fuel cells. Top Curr Chem 61:133–181

    Article  Google Scholar 

  4. Dodelet J-P (2013) The controversial role of the metal in Fe- or Co-based electrocatalysts for the oxygen reduction reaction in acid medium. Springer, London, pp 271–338

    Google Scholar 

  5. Elbaz L, Wu G, Zelenay P (2013) Heat-treated non-precious-metal-based catalysts for oxygen reduction. Springer, London, pp 213–246

    Google Scholar 

  6. Damjanovic A, Genshaw MA, Bockris JO (1966) Distinction between intermediates produced in main and side electrodic reactions. J Chem Phys 45:4057

    Article  Google Scholar 

  7. Olson TS, Pylypenko S, Fulghum JE, Atanassov P (2010) Bifunctional oxygen reduction reaction mechanism on non-platinum catalysts derived from pyrolyzed porphyrins. J Electrochem Soc 157:B54

    Article  Google Scholar 

  8. Nallathambi V, Lee J-W, Kumaraguru SP et al (2008) Development of high performance carbon composite catalyst for oxygen reduction reaction in PEM Proton Exchange Membrane fuel cells. J Power Sources 183:34–42

    Article  Google Scholar 

  9. Serov A, Artyushkova K, Atanassov P (2014) Fe-N-C oxygen reduction fuel cell catalyst derived from carbendazim: synthesis, structure, and reactivity. Adv Energy Mater 4:1301735

    Article  Google Scholar 

  10. Iwazaki T, Obinata R, Sugimoto W, Takasu Y (2009) High oxygen-reduction activity of silk-derived activated carbon. Electrochem Commun 11:376–378

    Article  Google Scholar 

  11. Muthukrishnan A, Nabae Y (2016) Estimation of the inherent kinetic parameters for oxygen reduction over a Pt-free cathode catalyst by resolving the quasi-four-electron reduction. J Phys Chem C 120:22515–22525

    Article  Google Scholar 

  12. Lefvre M, Dodelet JP, Bertrand P (2002) Molecular oxygen reduction in PEM fuel cells: evidence for the simultaneous presence of two active sites in Fe-based catalysts molecular oxygen reduction in PEM fuel cells: evidence for the simultaneous presence of two active sites in Fe-based catalysts. J Phys Chem B 106:8705–8713

    Article  Google Scholar 

  13. Chung HT, Cullen DA, Higgins D et al (2017) Direct atomic-level insight into the active sites of a high-performance PGM-free ORR catalyst. Science 357:479–484

    Article  Google Scholar 

  14. Wu J, Nabae Y, Muthukrishnan A, Ohsaka T (2016) Electrochemical deposition and dissolution of Fe species for N-doped carbon to understand the degradation mechanism of Pt-free oxygen reduction catalysts. Electrochim Acta 214:307–312

    Article  Google Scholar 

  15. Guo D, Shibuya R, Akiba C et al (2016) Active sites of nitrogen-doped carbon materials for oxygen reduction reaction clarified using model catalysts. Science 351:361–365

    Article  Google Scholar 

  16. Wang X, Lee JS, Zhu Q et al (2010) Ammonia-treated ordered mesoporous carbons as catalytic materials for oxygen reduction reaction. Chem Mater 22:2178–2180

    Article  Google Scholar 

  17. Yu D, Zhang Q, Dai L (2010) Highly-efficient metal-free growth of nitrogen-doped single-walled carbon nanotubes on plasma-etched substrates for oxygen reduction. J Am Chem Soc 132:15127–15129

    Article  Google Scholar 

  18. Sidik RA, Anderson AB, Subramanian NP et al (2006) O2 reduction on graphite and nitrogen-doped graphite: experiment and theory. J Phys Chem B 110:1787–1793

    Google Scholar 

  19. Ikeda T, Boero M, Huang SF et al (2008) Carbon alloy catalysts: active sites for oxygen reduction reaction. J Phys Chem C 112:14706–14709

    Article  Google Scholar 

  20. Park J, Nabae Y, Hayakawa T, Kakimoto M (2014) Highly selective two-electron oxygen reduction catalyzed by mesoporous nitrogen-doped carbon. ACS Catal 4:3749–3754

    Article  Google Scholar 

  21. Muthukrishnan A, Nabae Y, Okajima T, Ohsaka T. A kinetic approach to investigate the mechanistic pathways of oxygen reduction reaction on Fe-containing N-doped carbon catalysts. ACS Catal 5:5194–5202

    Google Scholar 

  22. Nabae Y, Sonoda M, Yamauchi C et al (2014) Highly durable Pt-free fuel cell catalysts prepared by multi-step pyrolysis of Fe phthalocyanine and phenolic resin. Catal Sci Technol 4:1400

    Article  Google Scholar 

  23. Matter PH, Wang E, Millet J-MM, Ozkan US (2007) Characterization of the iron phase in CNx-based oxygen reduction reaction catalysts. J Phys Chem C 111:1444–1450

    Article  Google Scholar 

  24. Nabae Y, Kuang Y, Chokai M et al (2014) High performance Pt-free cathode catalysts for polymer electrolyte membrane fuel cells prepared from widely available chemicals. J Mater Chem A 2:11561–11564

    Article  Google Scholar 

  25. Nabae Y, Nagata S, Hayakawa T et al (2016) Pt-free carbon-based fuel cell catalyst prepared from spherical polyimide for enhanced oxygen diffusion. Sci Rep 6:23276

    Article  Google Scholar 

  26. Raymundo-Piñero E, Cazorla-Amorós D, Linares-Solano a et al (2002) Structural characterization of N-containing activated carbon fibers prepared from a low softening point petroleum pitch and a melamine resin. Carbon N Y 40:597–608

    Article  Google Scholar 

  27. Ikeda T, Hou Z, Chai GL, Terakura K (2014) Possible oxygen reduction reactions for graphene edges from first principles. J Phys Chem C 118:17616–17625

    Article  Google Scholar 

  28. Gottfried JM, Bai Y, Buchner F et al (2008) Direct metalation of a phthalocyanine monolayer on Ag (111) with coadsorbed iron atoms direct metalation of a phthalocyanine monolayer on Ag (111) with coadsorbed iron atoms. Society 6087–6092

    Google Scholar 

  29. Proietti E, Jaouen F, Lefevre M et al (2011) Iron-based cathode catalyst with enhanced power density in polymer electrolyte membrane fuel cells. Nat Commun 2:1–6

    Article  Google Scholar 

  30. Li J, Ghoshal S, Liang W et al (2016) Structural and mechanistic basis for the high activity of Fe–N–C catalysts toward oxygen reduction. Energy Environ Sci 9:2418–2432

    Article  Google Scholar 

  31. Chung HT, Cullen DA, Higgins D et al (2017) Direct atomic-level insight into the active sites of a high-performance PGM-free ORR catalyst. Science 80(357):479–484

    Article  Google Scholar 

  32. Ishihara A, Tamura M, Ohgi Y, Matsumoto M, Matsuzawa K, Mitsushima S, Imai H, Ota K (2013) Emergence of oxygen reduction activity in partially oxidized tantalum carbonitrides: roles of deposited carbon for oxygen-reduction-reaction-site creation and surface electron conduction. J Phys Chem C 117:18837–18844

    Article  Google Scholar 

  33. Ohgi Y, Ishihara A, Matsuzawa K, Mitsushima S, Matsumoto M, Imai H, Ota K (2013) Factors for improvements of catalytic activity for zirconium oxide-based oxygen-reduction electrocatalysts. J Electrochem Soc 160:F162–F167

    Article  Google Scholar 

  34. Imai H, Matsumoto M, Miyazaki T, Fujieda S, Ishihara A, Tanura M, Ota K (2010) Structural defects working as active oxygen-reduction sites in partially oxidized Ta-carbonitride core-shell particles probed by using surface-sensitive conversion-electron-yield x-ray absorption spectroscopy. Appl Phys Lett 96:191905

    Article  Google Scholar 

  35. Ishihara A, Chisaka M, Ohgi Y, Matsuzawa K, Mistushima S, Ota K (2015) Synthesis of nano-TaOx oxygen reduction reaction catalysts on multi-walled carbon nanotubes connected via a decomposition of oxy-tantalum phthalocyanine. Phys Chem Chem Phys 17:7643–7647

    Article  Google Scholar 

  36. Uehara N, Ishihara A, Matsumoto M, Imai H, Kohno Y, Matsuzawa K, Mitsushima S, Ota K (2015) Tantalum oxide-based electrocatalysts made from oxy-tantalum phthalocyanines as non-platinum cathodes for polymer electrolyte fuel cells. Electrochim Acta 179:146–153

    Article  Google Scholar 

  37. Uehara N, Ishihara A, Nagai T, Matsumoto M, Imai H, Kohno Y, Matsuzawa Mitsushima S, Ota K (2015) Kinetic study of oxygen reduction reaction on tantalum oxide-based electrocatalysts produced from oxy-tantalum phthalocyanines in acidic media. Electrochim Acta 182:789–794

    Article  Google Scholar 

  38. Hayashi T, Ishihara A, Nagai T, Arao M, Imai H, Kohno Y, Matsuzawa K, Mistushima S, Ota K (2016) Temperature dependence of oxygen reduction mechanism on a titanium oxide-based catalyst made from oxy-titanium tetra-pyrazino-porphyrazine using carbon nano-tubes as support in acidic solution. Electrochim Acta 209:1–6

    Article  Google Scholar 

  39. Tominaka S, Ishihara A, Nagai T, Ota K (2017) Noncrystalline titanium oxide catalysts for electrochemical oxygen reduction reactions. ACS Omega 2:5209–5214

    Article  Google Scholar 

  40. Chisaka M, Ishihara A, Morioka H, Nagai T, Yin S, Ohgi Y, Matsuzawa K, Mitsushima S, Ota K (2017) Zirconium oxynitride-catalyzed oxygen reduction reaction at polymer electrolyte fuel cell cathodes. ACS Omega 2:678–684

    Article  Google Scholar 

  41. Chisaka M, Ishihara A, Uehara N, Matsumoto M, Imai H, Ota K (2015) Nano-TaOxNy particles synthesized from oxytantalum phthalocyanine: how to prepare precursors to enhance the oxygen reduction reaction activity after ammonia pyrolysis? J Mater Chem A 3:16414–16418

    Article  Google Scholar 

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Acknowledgements

The majority of the authors’ research described in this chapter was financially supported by the New Energy and Industrial Technology Development Organization (NEDO).

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Correspondence to Akimitsu Ishihara .

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Nabae, Y., Ishihara, A. (2019). Recent Progress in Non-precious Metal Fuel Cell Catalysts. In: Nakashima, N. (eds) Nanocarbons for Energy Conversion: Supramolecular Approaches. Nanostructure Science and Technology. Springer, Cham. https://doi.org/10.1007/978-3-319-92917-0_11

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  • DOI: https://doi.org/10.1007/978-3-319-92917-0_11

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  • Publisher Name: Springer, Cham

  • Print ISBN: 978-3-319-92915-6

  • Online ISBN: 978-3-319-92917-0

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