Abstract
The emerging field of developing nanomaterials with stimuli responsive smart surfaces allows one to tune the surface properties for various useful applications such as self-cleaning surfaces, energy, oil/water separation, tunable optical lenses, microfluidics, and sensors etc. Such materials with smart surfaces having reversible switching properties between superhydrophilicity and superhydrophobicity, have shown strong capability for oil/water separation and been investigated extensively in the last decade. The oil/water separation is a field of high significance as it has direct practical implementation to resolve the problems of industrial oily wastewater and other oil/water pollutions. Various factors affecting the stimuli response of these smart surfaces such as light, pH, temperature, gas, electric and magnetic field etc. have been summarized to evaluate the enhanced surface properties for oil/water separation. Beside this, dual responsive smart surfaces have also been summarized for oil/water separations. This chapter highlights the recent accomplishments carried out in the development of such smart nanomaterials surfaces for oil/water separation.
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Cao Y, Liu N, Fu C, Li K, Tao L, Feng L, Wei Y (2014) Thermo and pH dual-responsive materials for controllable oil/water separation. ACS Appl Mater Interfaces 6:2026–2030
Che H, Huo M, Peng L, Fang T, Liu N, Feng L, Wei Y, Yuan J (2015) CO2-responsive nanofibrous membranes with switchable oil/water wettability. Angew Chem Int Ed 54:8934–8938
Chen Y, Bai Y, Chen S, Ju J, Li Y, Wang T, Wang Q (2014) Stimuli-responsive composite particles as solid-stabilizers for effective oil harvesting. ACS Appl Mater Interfaces 6:13334–13338
Chen Y, Li F, Cao W, Li T (2015) Preparation of recyclable CdS photocatalytic and superhydrophobic films with photostability by using a screen-printing technique. J Mater Chem A 3:16934–16940
Cheng Z, Wang J, Lai H, Du Y, Hou R, Li C, Zhang N, Sun K (2015) pH-controllable on-demand oil/water separation on the switchable superhydrophobic/superhydrophilic and underwater low-adhesive superoleophobic copper mesh film. Langmuir 31:1393–1399
Cheng Z, Li C, Lai H, Du Y, Liu H, Liu M, Jin L, Zhang C, Zhang N, Sun K (2016) A pH-responsive superwetting nanostructured copper mesh film for separating both water-in-oil and oil-in-water emulsions. RSC Adv 6:72317–72325
Crevoisier G, Fabre P, Corpart J-M, Leibler L (1999) Switchable tackiness and wettability of a liquid crystalline polymer. Science 285:1246–1249
Dang Z, Liu L, Li Y, Xiang Y, Guo G (2016) In situ and ex situ pH-responsive coatings with switchable wettability for controllable oil/water separation. ACS Appl Mater Interfaces 8:31281–31288
Dunderdale GJ, Urata C, Miranda DF, Hozumi A (2014a) Large-scale and environmentally friendly synthesis of pH-responsive oil-repellent polymer brush surfaces under ambient conditions. ACS Appl Mater Interfaces 6:11864–11868
Dunderdale GJ, Urata C, Hozumi A (2014b) An underwater superoleophobic surface that can be activated/deactivated via external triggers. Langmuir 30:13438–13446
Fan Y, He Y, Luo P, Chen X, Yu Z, Li M (2017) Facile way in building superhydrophobic zirconium surface for controllable water-oil separation. Mater Lett 188:115–118
Feng L, Zhang Z, Mai Z, Ma Y, Liu B, Jiang L, Zhu D (2004a) A super-hydrophobic and super-oleophilic coating mesh film for the separation of oil and water. Angew Chem Int Ed 43:2012–2014
Feng X, Feng L, Jin M, Zhai J, Jiang L, Zhu D (2004b) Reversible super-hydrophobicity to super-hydrophilicity transition of aligned ZnO Nanorod films. J Am Chem Soc 126:62–63
Gao SJ, Shi Z, Zhang WB, Zhang F, Jin J (2014) Photoinduced superwetting single-walled carbon nanotube/TiO2 ultrathin network films for ultrafast separation of oil-in-water emulsions. ACS Nano 8:6344–6352
Gunatilake UB, Bandara J (2017a) Efficient removal of oil from oil contaminated water by superhydrophilic and underwater superoleophobic nano/micro structured TiO2 nanofibers coated mesh. Chemosphere 171:134–141
Gunatilake UB, Bandara J (2017b) Fabrication of highly hydrophilic filter using natural and hydrothermally treated mica nanoparticles for efficient waste oil-water separation. J Environ Manag 191:96–104
Guo F, Guo Z (2016) Inspired smart materials with external stimuli responsive wettability: a review. RSC Adv 6:36623–36641
Guo S, Li X, Zhou M, Cai Z (2017) The smart surfaces with reversible transformations from superhydrophobicity to superhydrophilicity. Mater Lett 193:13–17
Hu L, Gao S, Ding X, Wang D, Jiang J, Jin J, Jiang L (2015) Photothermal-responsive single-walled carbon nanotube-based ultrathin membranes for on/off switchable separation of oil-in-water nanoemulsions. ACS Nano 9:4835–4842
Janout V, Myers SB, Register RA, Regen SL (2007) Self-cleaning resins. J Am Chem Soc 129:5756–5759
Kim DH, Jung MC, Cho SH, Kim SH, Kim HY, Lee HJ, Oh KH, Moon MW (2015) UV-responsive nano-sponge for oil absorption and desorption. Sci Rep 5:12908
Kota AK, Kwon G, Choi W, Mabry JM, Tuteja A (2012) Hygro-responsive membranes for effective oil–water separation. Nat Commun 3:1025
Kwon G, Kota AK, Li Y, Sohani A, Mabry JM, Tuteja A (2012) On-demand separation of oil-water mixtures. Adv Mater 24:3666–3671
Lee CH, Tiwari B, Zhang D, Yap YK (2017) Water purification: oil-water separation by nanotechnology and environmental concerns. Environ Sci Nano 4:514–525
Li H, Wang X, Song Y, Liu Y, Li Q, Jiang L, Zhu D (2001) Super-“amphiphobic” aligned carbon nanotube films. Angew Chem 113:1793–1796
Li J-J, Zhou Y-N, Luo Z-H (2015) Smart fiber membrane for pH-induced oil/water separation. ACS Appl Mater Interfaces 7:19643–19650
Li G, Fan H, Ren F, Zhou C, Zhang Z, Xu B, Wu S, Hu Y, Zhu W, Li J, Zeng Y, Li X, Chu J, Wu D (2016a) Multifunctional ultrathin aluminum foil: oil/water separation and particle filtration. J Mater Chem A 4:18832–18840
Li J-J, Zhu L-T, Luo Z-H (2016b) Electrospun fibrous membrane with enhanced swithchable oil/water wettability for oily water separation. Chem Eng J 287:474–481
Li J-J, Zhou Y-N, Jiang Z-D, Luo Z-H (2016c) Electrospun fibrous mat with pH-switchable superwettability that can separate layered oil/water mixtures. Langmuir 32:13358–13366
Li T, Shen J, Zhang Z, Wang S, Wei D (2016d) A poly(2-(dimethylamino)ethyl methacrylate-co-methacrylic acid) complex induced route to fabricate a super-hydrophilic hydrogel and its controllable oil/water separation. RSC Adv 6:40656–40663
Lin X, Lu F, Chen Y, Liu N, Cao Y, Xu L, Zhang W, Feng L (2015) Electricity-induced switchable wettability and controllable water permeation based on 3D copper foam. Chem Commun 51:16237–16240
Liu C-T, Liu Y-L (2016) pH-induced switches of the oil- and water-selectivity of crosslinked polymeric membranes for gravity-driven oil-water separation. J Mater Chem A 4:13543–13548
Liu Y, Zhang K, Son Y, Zhang W, Spindler LM, Han Z, Ren L (2017) A smart switchable bioinspired copper foam responding to different pH droplets for reversible oil-water separation. J Mater Chem A 5:2603–2612
Low LE, Tey BT, Ong BH, Chan ES, Tang SY (2017) Palm olein-in-water Pickering emulsion stabilized by Fe3O4-cellulose nanocrystal nanocomposites and their responses to pH. Carbohydr Polym 155:391–399
Lü T, Zhang S, Qi D, Zhang D, Zhao H (2016) Thermosensitive poly(N-isopropylacrylamide)-grafted magnetic nanoparticles for efficient treatment of emulsified oily wastewater. J Alloys Compd 688, Part B:513–520
Lü T, Zhang S, Qi D, Zhang D, Vance GF, Zhao H (2017) Synthesis of pH-sensitive and recyclable magnetic nanoparticles for efficient separation of emulsified oil from aqueous environments. Appl Surf Sci 396:1604–1612
Luo PG, Yang F, Yang S-T, Sonkar SK, Yang L, Broglie JJ, Liua Y, Sun Y-P (2014) Carbon-based quantum dots for fluorescence imaging of cells and tissues. RSC Adv 4:10791–10807
Ma Q, Cheng H, Fane AG, Wang R, Zhang H (2016a) Recent development of advanced materials with special wettability for selective oil/water separation. Small 12:2186–2202
Ma S, Wang Y, Wang X, Li Q, Tong S, Han X (2016b) Bifunctional demulsifier of ODTS modified magnetite/reduced graphene oxide nanocomposites for oil–water separation. ChemistrySelect 1:4742–4746
Mendes PM (2008) Stimuli-responsive surfaces for bio-applications. Chem Soc Rev 37:2512–2529
Nagappan S, Moorthy MCS, Rao KM, Ha C-S (2016) Stimuli-responsive smart polymeric coatings: an overview. In: Hosseini M, Makhlouf ASH (eds) Industrial applications for intelligent polymers and coatings. Springer, Cham, pp 27–49. https://doi.org/10.1007/978-3-319-26893-4_2
Nelson A (2008) Stimuli-responsive polymers: engineering interactions. Nat Mater 7:523–525
Ou R, Wei J, Jiang L, Simon GP, Wang H (2016) Robust thermoresponsive polymer composite membrane with switchable superhydrophilicity and superhydrophobicity for efficient oil–water separation. Environ Sci Technol 50:906–914
Rodríguez-Hermida S, Tsang MY, Vignatti C, Stylianou KC, Guillerm V, Pérez-Carvajal J, Teixidor F, Viñas C, Choquesillo-Lazarte D, Verdugo-Escamilla C, Peral I, Juanhuix J, Verdaguer A, Imaz I, Maspoch D, Giner Planas J (2016) Switchable surface hydrophobicity–hydrophilicity of a metal–organic framework. Angew Chem Int Ed 55:16049–16053
Shi Z, Zhang W, Zhang F, Liu X, Wang D, Jin J, Jiang L (2013) Ultrafast separation of emulsified oil/water mixtures by ultrathin free-standing single-walled carbon nanotube network films. Adv Mater 25:2422–2427
Su X, Li H, Lai X, Zhang L, Liang T, Feng Y, Zeng X (2017) Polydimethylsiloxane-based superhydrophobic surfaces on steel substrate: fabrication, reversibly extreme wettability and oil–water separation. ACS Appl Mater Interfaces 9:3131–3141
Sun T, Wang G, Feng L, Liu B, Ma Y, Jiang L, Zhu D (2004a) Reversible switching between superhydrophilicity and superhydrophobicity. Angew Chem 116:361–364
Sun T, Wang G, Feng L, Liu B, Ma Y, Jiang L, Zhu D (2004b) Reversible switching between superhydrophilicity and superhydrophobicity. Angew Chem Int Ed 43:357–360
Tadanaga K, Katata N, Minami T (1997) Super-water-repellent Al2O3 coating films with high transparency. J Am Ceram Soc 80:1040–1042
Tadanaga K, Morinaga J, Matsuda A, Minami T (2000) Superhydrophobic−superhydrophilic micropatterning on flowerlike alumina coating film by the sol−gel method. Chem Mater 12:590–592
Taleb S, Darmanin T, Guittard F (2016) Superoleophobic/superhydrophobic PEDOP conducting copolymers with dual-responsivity by voltage and ion exchange. Mater Today Commun 6:1–8
Tang J, Berry RM, Tam KC (2016) Stimuli-responsive cellulose nanocrystals for surfactant-free oil harvesting. Biomacromolecules 17:1748–1756
Tian D, Zhang X, Wang X, Zhai J, Jiang L (2011a) Micro/nanoscale hierarchical structured ZnO mesh film for separation of water and oil. PCCP 13:14606–14610
Tian D, Zhang X, Zhai J, Jiang L (2011b) Photocontrollable water permeation on the micro/nanoscale hierarchical structured ZnO mesh films. Langmuir 27:4265–4270
Tian D, Zhang X, Tian Y, Wu Y, Wang X, Zhai J, Jiang L (2012) Photo-induced water-oil separation based on switchable superhydrophobicity-superhydrophilicity and underwater superoleophobicity of the aligned ZnO nanorod array-coated mesh films. J Mater Chem 22:19652–19657
Wang S, Song Y, Jiang L (2007) Photoresponsive surfaces with controllable wettability. J Photochem Photobiol C 8:18–29
Wang X, Shi Y, Graff RW, Lee D, Gao H (2015) Developing recyclable pH-responsive magnetic nanoparticles for oil-water separation. Polymer (UK) 72:361–367
Wang X, Yu J, Sun G, Ding B (2016) Electrospun nanofibrous materials: a versatile medium for effective oil/water separation. Mater Today 19:403–414
Wu J, Jiang Y, Jiang D, He J, Cai G, Wang J (2015) The fabrication of pH-responsive polymeric layer with switchable surface wettability on cotton fabric for oil/water separation. Mater Lett 160:384–387
Wu JD, Zhang C, Jiang DJ, Zhao SF, Jiang YL, Cai GQ, Wang JP (2016) Self-cleaning pH/thermo-responsive cotton fabric with smart-control and reusable functions for oil/water separation. RSC Adv 6:24076–24082
Xiang Y, Wang Y, Lin H, Wang Y, Xiong Z, Liu F (2015) Efficient separation of O/W and W/O micro-emulsion by thermally responsive superantiwetting PVDF membrane. React Funct Polym 97:86–95
Xu Z, Zhao Y, Wang H, Wang X, Lin T (2015) A superamphiphobic coating with an ammonia-triggered transition to superhydrophilic and superoleophobic for oil–water separation. Angew Chem Int Ed 54:4527–4530
Xu P, Wang Z, Xu Z, Hao J, Sun D (2016) Highly effective emulsification/demulsification with a CO2-switchable superamphiphile. J Colloid Interface Sci 480:198–204
Xue B, Gao L, Hou Y, Liu Z, Jiang L (2013) Temperature controlled water/oil wettability of a surface fabricated by a block copolymer: application as a dual water/oil on–off switch. Adv Mater 25:273–277
Xue Z, Cao Y, Liu N, Feng L, Jiang L (2014) Special wettable materials for oil/water separation. J Mater Chem A 2:2445–2460
Yan Q, Zhao Y (2013) CO2-stimulated diversiform deformations of polymer assemblies. J Am Chem Soc 135:16300–16303
Yan Q, Zhou R, Fu C, Zhang H, Yin Y, Yuan J (2011) CO2-responsive polymeric vesicles that breathe. Angew Chem Int Ed 50:4923–4927
Yan Q, Wang J, Yin Y, Yuan J (2013) Breathing polymersomes: CO2-tuning membrane permeability for size-selective release, separation, and reaction. Angew Chem Int Ed 52:5070–5073
Yan L, Li J, Li W, Zha F, Feng H, Hu D (2016) A photo-induced ZnO coated mesh for on-demand oil/water separation based on switchable wettability. Mater Lett 163:247–249
Ye S, Cao Q, Wang Q, Wang T, Peng Q (2016) A highly efficient, stable, durable, and recyclable filter fabricated by femtosecond laser drilling of a titanium foil for oil-water separation. Sci Rep 6:37591
Yong J, Chen F, Yang Q, Farooq U, Hou X (2015) Photoinduced switchable underwater superoleophobicity-superoleophilicity on laser modified titanium surfaces. J Mater Chem A 3:10703–10709
Yuan X, Li W, Zhu Z, Han N, Zhang X (2017) Thermo-responsive PVDF/PSMA composite membranes with micro/nanoscale hierarchical structures for oil/water emulsion separation. Colloids Surf A Physicochem Eng Asp 516:305–316
Zhang L, Zhang Z, Wang P (2012a) Smart surfaces with switchable superoleophilicity and superoleophobicity in aqueous media: toward controllable oil/water separation. NPG Asia Mater 4:e8
Zhang J, Han D, Zhang H, Chaker M, Zhao Y, Ma D (2012b) In situ recyclable gold nanoparticles using CO2-switchable polymers for catalytic reduction of 4-nitrophenol. Chem Commun 48:11510–11512
Zhang L, Zhong Y, Cha D, Wang P (2013a) A self-cleaning underwater superoleophobic mesh for oil-water separation. Sci Rep 3:2326
Zhang W, Shi Z, Zhang F, Liu X, Jin J, Jiang L (2013b) Superhydrophobic and superoleophilic PVDF membranes for effective separation of water-in-oil emulsions with high flux. Adv Mater 25:2071–2076
Zhang W, Lu X, Xin Z, Zhou C (2016) Development of a superhydrophobic polybenzoxazine surface with self-cleaning and reversible water adhesion properties. RSC Adv 6:106054–106063
Zhao X, Su Y, Liu Y, Li Y, Jiang Z (2016) Free-standing graphene oxide-palygorskite nanohybrid membrane for oil/water separation. ACS Appl Mater Interfaces 8:8247–8256
Zheng X, Guo Z, Tian D, Zhang X, Jiang L (2016) Electric field induced switchable wettability to water on the polyaniline membrane and oil/water separation. Adv Mater Interfaces 3:1600461-n/a
Zhou F, Huck WTS (2006) Surface grafted polymer brushes as ideal building blocks for “smart” surfaces. PCCP 8:3815–3823
Zhou Y-N, Li J-J, Luo Z-H (2016) Toward efficient water/oil separation material: effect of copolymer composition on pH-responsive wettability and separation performance. AICHE J 62:1758–1771
Zhou C, Cheng J, Hou K, Zhu Z, Zheng Y (2017) Preparation of CuWO4@Cu2O film on copper mesh by anodization for oil/water separation and aqueous pollutant degradation. Chem Eng J 307:803–811
Zhu H, Guo Z (2016) Understanding the separations of oil/water mixtures from immiscible to emulsions on super-wettable surfaces. J Bionic Eng 13:1–29
Zhu W, Zhai J, Sun Z, Jiang L (2008) Ammonia responsive surface wettability switched on indium hydroxide films with micro- and nanostructures. J Phys Chem C 112:8338–8342
Zhu H, Yang S, Chen D, Li N, Xu Q, Li H, He J, Lu J (2016) A robust absorbent material based on light-responsive superhydrophobic melamine sponge for oil recovery. Adv Mater Interfaces 3:1500683-n/a
Acknowledgment
RKG acknowledges financial assistance from Department of Science and Technology (DST), India, through the INSPIRE Faculty Award (Project No. IFA-13 ENG-57) and Grant No. DST/TM/WTI/2 K16/23(G). JP acknowledges DST, India for the prestigious INSPIRE faculty award (INSPIRE/04/2015/002452). DST support to the Center for Nanosciences is acknowledged.
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Prakash, J., Singh, N., Mittal, R., Gupta, R.K. (2018). Stimuli-Responsive Smart Surfaces for Oil/Water Separation Applications. In: Hozumi, A., Jiang, L., Lee, H., Shimomura, M. (eds) Stimuli-Responsive Dewetting/Wetting Smart Surfaces and Interfaces. Biologically-Inspired Systems, vol 11. Springer, Cham. https://doi.org/10.1007/978-3-319-92654-4_9
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