Abstract
Smart surfaces with tunable wetting characteristics have recently gained a lot of attention from scientists and engineers due to the interesting underlying fundamentals as well as tremendous applications in areas including microfluidics, lab-on-a-chip, bio-adhesion, oil-water separation, analytical and medical applications to name a few. Surface wettability can either be tuned by passive methods where different surface energy materials are coated on a surface depending upon the requirement. Alternatively, the surface wettability can be tuned actively where a responsive coating is coated on a surface and the wettability can be tuned with respective external stimulus e.g. light, temperature, pH, electric field, magnetic field, mechanical strain etc. Surfaces with pH responsive wetting behaviour allow control of liquids with high precision which is essentially required in many fluidic devices. Compared to other responsive wetting surfaces, pH responsive wetting surfaces are easy to fabricate and are more stable as well. They also show improved reversible transition between hydrophilic and hydrophobic states with much smaller hysteresis. In this chapter, we discuss various studies involving pH responsive wetting/dewetting system with fundamentals as well as potential applications.
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Acknowledgement
KK acknowledges financial assistance from BRNS (DAE) Young Scientist Research Award and DST, New Delhi through its Unit of Excellence on Soft Nanofabrication at IIT Kanpur.
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Pant, R., Dattatreya, S., Barman, J., Khare, K. (2018). pH Responsive Reversibly Tunable Wetting Surfaces. In: Hozumi, A., Jiang, L., Lee, H., Shimomura, M. (eds) Stimuli-Responsive Dewetting/Wetting Smart Surfaces and Interfaces. Biologically-Inspired Systems, vol 11. Springer, Cham. https://doi.org/10.1007/978-3-319-92654-4_3
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