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Structural Study of the Modified Cu0.4Co0.4Ni0.4Mn1.8O4 and Cu0.1Ni0.8Co0.2Mn1.9O4 Ceramics Using Combined Methods

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Nanochemistry, Biotechnology, Nanomaterials, and Their Applications (NANO 2017)

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Abstract

Structural peculiarities of temperature-sensitive Cu0.4Co0.4Ni0.4Mn1.8O4 ceramics caused by micro- and macro-modifications as well as Cu0.1Ni0.8Co0.2Mn1.9O4 ceramics related with monolithization processes were studied using traditional and alternative techniques. Using two-state positron trapping model, it is established that positron trapping sites are the same for macro- and micro-modified Cu0.4Co0.4Ni0.4Mn1.8O4 ceramics. Classic Tao-Eldrup model is used to calculation of the size of nanopores smaller than 2 nm using the ortho-positronium lifetime. For modified Cu0.1Ni0.8Co0.2Mn1.9O4 ceramics, it is shown that the amount of additional NiO phase extracted during sintering plays a decisive role. This effect is well revealed only in ceramics having a character fine-grain microstructure, while the monolithization of ceramics caused by great amount of transferred thermal energy reveals an opposite influence. The process of monolitization from the position of evolution of grain-pore structure was studied in these ceramics using positron annihilation lifetime spectroscopy.

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Acknowledgments

H. Klym thanks the Ministry of Education and Science of Ukraine for support (grant No 0116 U004411).

Author information

Authors and Affiliations

  1. Lviv Polytechnic National University, Lviv, Ukraine

    H. Klym, Yu. Kostiv & I. Vasylchyshyn

  2. Drohobych State Pedagogical University, Drohobych, Ukraine

    I. Hadzaman

  3. Opole University of Technology, Opole, Poland

    A. Ingram

  4. Vlokh Institute of Physical Optics, Lviv, Ukraine

    O. Shpotyuk

  5. Jan Dlugosz University in Czestochowa, Czestochowa, Poland

    O. Shpotyuk

  6. Ivan Franko National University of Lviv, Lviv, Ukraine

    I. Karbovnyk

  7. Lviv State University of Life Safety, Lviv, Ukraine

    D. Chalyy

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  1. H. Klym
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Correspondence to H. Klym .

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Editors and Affiliations

  1. National Academy of Sciences of Ukraine, Institute of Physics, Kyiv, Ukraine

    Olena Fesenko

  2. National Academy of Sciences of Ukraine, Institute of Physics, Kyiv, Ukraine

    Leonid Yatsenko

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Klym, H. et al. (2018). Structural Study of the Modified Cu0.4Co0.4Ni0.4Mn1.8O4 and Cu0.1Ni0.8Co0.2Mn1.9O4 Ceramics Using Combined Methods. In: Fesenko, O., Yatsenko, L. (eds) Nanochemistry, Biotechnology, Nanomaterials, and Their Applications. NANO 2017. Springer Proceedings in Physics, vol 214. Springer, Cham. https://doi.org/10.1007/978-3-319-92567-7_29

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