Abstract
Two case studies of calcium fatty acid salts in oil paint are presented. The first is a nineteenth-century oil on canvas painting, and the second is a decoratively painted ceiling. In both cases, the calcium soaps have formed in the lower layers of the paint systems and are associated with significant delamination and paint loss. The results of analysis of samples from the two works using FTIR, SEM-EDX, Raman, PLM, and Py-GC-MS are presented. The components of the paint and ground involved in the soap formation, the conditions that may have led to their formation, and the treatment strategies that were chosen are described.
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Notes
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In one area, on a flat, vertical surface of a hexagonal coffer, the plaster was found to be composed of gypsum.
References
Béland M (2014) D’après Le Titien. Au Musée national des beaux-arts du Québec Cap-aux-Diamants 116:50–51
Binnie N, Baker W, Moffatt E, Veal M-A, Helwig K, Poulin J (2017, in press) Investigation of paint instability and conservation requirements for decorative auditorium and library ceilings. In: Powers of ten – architectural paint research conference papers, postprints of the 6th international architectural paint research conference, New York, 15–17 Mar 2017. Archetype Publications, London
Bio-Rad Sadtler (2017) IR – Lubricant Additives 1. Accessed through Bio-Rad KnowItAll® Informatics System, vibrational spectroscopy edition. Bio-Rad Laboratories, Inc, Philadelphia. Spectra consulted: LA1X 80, 1088, 1819 and 1828
Ferreira ESB, Boon JJ, Stampanoni M, Marone F (2011) Study of the mechanism of formation of calcium soaps in an early 20th-century easel painting with correlative 2D and 3D microscopy. Preprints of 16th triennial ICOM-CC conference, Lisbon, pp 1604–1608
FHBRO Statement of Significance-100 Sussex Drive, NRC Laboratories (2016) http://www.historicplaces.ca/en/rep-reg/place-lieu.aspx?id=4030&pid=0. Accessed 16 Aug 2016
Halikia I, Soumpoulakis L, Christodoulou E, Prattis D (2001) Kinetic study of the thermal decomposition of calcium carbonate by isothermal methods of analysis. Eur J Mineral Process Environ Prot 1(2):89–102
Moffatt E, Salmon A, Poulin J, Fox A, Hay J (2015) Characterization of varnishes on nineteenth-century Canadian furniture. J Can Assoc Conserv 40:3–18
Mortimer DC (2002) 100 Sussex Drive, The Temple of Science. A concise story of the building which was the National Research Laboratories. National Research Council of Canada, Ottawa, pp 3–8
Noble P, Boon JJ (2007) Metal soap degradation of oil paintings: aggregates, increased transparency and efflorescence. AIC PSG Postprints 19:1–15
Sproatt H, Rolph E (1929) Sussex, original specifications, July 1929. Selection of pages from resource document provided by the National Research Council of Canada, Administrative Services and Property Management Branch, Ottawa, pp 86, 87, 126, 187
Vézina R (1975) Théophile Hamel, Peintre national (1817–1870), Tome I. Éditions Élysée, Ottawa, p 214
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Helwig, K. et al. (2019). The Formation of Calcium Fatty Acid Salts in Oil Paint: Two Case Studies. In: Casadio, F., et al. Metal Soaps in Art. Cultural Heritage Science. Springer, Cham. https://doi.org/10.1007/978-3-319-90617-1_17
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DOI: https://doi.org/10.1007/978-3-319-90617-1_17
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