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Blocking Temperature and Hysteresis Characteristics of Nanoparticles of Oxidated Magnetite

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Abstract

An effect of a single-phase oxidation process on the hysteresis characteristics and blocking temperature of magnetite has been carried out within the framework of the model of core-shell nanoparticle. It has been shown that an increase of the degree of oxidation of magnetite grains results in a decrease of the spontaneous magnetization and slight change of coercive field and remanent saturation magnetization to spontaneous magnetization ratio. Increase of the portion of maghemite lead to decrease of the blocking temperature. All results are in agreement with an experimental data.

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References

  • Afremov L. L., Lamash B. E., Panov A. V. The metastable states of a pseudo-single-domain ferrimagnetic grain. Izvestiya. Physics of the Solid Earth. 1998. V. 34. № 11. P. 927–931.

    Google Scholar 

  • Afremov L. L., Ilyushin I. G. // Effect of mechanical stress on magnetic states and hysteresis characteristics of a two-phase nanoparticles system, Journal of Nanomaterials, Volume 2013, 15p.

    Google Scholar 

  • Afremov L. L., Il’yushin I. G., Anisimov S. V. Modeling the implications of chemical transformations for the magnetic properties of a system of titanomagnetite nanoparticles //Izvestiya, Physics of the Solid Earth. – 2015. – V. 51. – №. 5. P. 613–621.

    Google Scholar 

  • Banerjee, S., J. King, and J. Marvin//A rapid method for magnetic granulometry with applications to environmental studies, Geophys. Res. Lett., 8(4), (1981), 333–336.

    Google Scholar 

  • Carmichael C. // Phys. Earth Planet. Inter. 1977. 13. Р. 332.

    Google Scholar 

  • Carvallo C., Ozden Ozdemir, Dunlop J.D. // Geophys.J. Int. 2004. 156. Р. 29.

    Google Scholar 

  • Draeger U., Prevot M., Poidras T., Riisager J. // Geophys. J. Int. 2006. 166. Р. 12.

    Google Scholar 

  • Dunlop D., Hale C. // J. Geophys. Res. 1976. 81. Р. 4166.

    Google Scholar 

  • Gallagher, K. // Mechanism of oxidation of magnetite to gamma-Fe2O3, Nature, 217, (1968), 1118–1121.

    Google Scholar 

  • Ge, K., W. Williams, Q. Liu, and Y. Yu // Effects of the core-shell structure on the magnetic properties of partially oxidized magnetite grains: Experimental and micromagnetic investigations, Geochem. Geophys. Geosyst., 15, (2014), 2021–2038, https://doi.org/10.1002/2014gc005265.

  • Gromm′ e S., Mankinen E., Marshall M., Coe R. //J. Geophys. Res. 1979. 84. Р. 3553.

    Google Scholar 

  • Gubin S.P., Koksharov Yu.A., Khomutov G.B., Yurkov G.Yu., Magnetic nanoparticles: preparation, structure and properties. Russian Chem. Rev., 2005, 74, pp. 489–520.

    Google Scholar 

  • Kechrakos D., Trohidou K. N., Vasilakaki M. Magnetic properties of dense nanoparticle arrays with core/shell morphology // Journal of Magnetism and Magnetic Materials. – 2007. – V. 316. – №. 2. P. e291–e294

    Google Scholar 

  • Krupichka S., Physics of ferrites and related magnetic oxides. Moscow, 1976, 2, 504 p.

    Google Scholar 

  • Liu, Q. S., S. K. Banerjee, M. J. Jackson, C. L. Deng, Y. X. Pan, and R. X. Zhu New insights into partial oxidation model of magnetites and thermal alteration of magnetic mineralogy of the Chinese loess in air, Geophys. J. Int., 158(2), (2004), 506–514.

    Google Scholar 

  • Nikiforov V.N., Ignatenko A.N., Irkhin V. Yu., Size and surface effects on the magnetism of magnetite and maghemite nanoparticles. J. Exp. Theor. Phys., 2017, 124, pp. 304–310.

    Google Scholar 

  • O’Reilly, W., Rock and Mineral Magnetism, 220 pp., Blackie Acad. and Prof, Glasgow, U. K (1984).

    Google Scholar 

  • Ozdemir, O., and D. J.// Dunlop Hallmarks of maghemitization in low-temperature remanence cycling of partially oxidized magnetite nanoparticles, J. Geophys. Res., (2010), 115, B02101, https://doi.org/10.1029/2009jb006756.

  • Perez N., Guardia P., Roca A.G., Morales M.P., Serna C.J., Iglesias O., Bartolome F., Garcia L.M., Batlle X., Labarta A., Surface anisotropy broadening of the energy barrier distribution in magnetic nanoparticles. Nanotechnology, 2008, 19, 475704.

    Google Scholar 

  • Prevot, M., A. Lecaille, and E. A. Mankinen. // Magnetic effects of maghemitization of oceanic crust, J. Geophys. Res., 86(B5), (1981) 4009–4020.

    Google Scholar 

  • Readman P.W. and W. O’Reilly Magnetic Properties of Oxidized (Cation-Deficient) Titanomagnetites (Fe, Ti,□)3O4//J. Geomag. Geoelectr., 1972, Vol. 24, pp. 69–90.

    Google Scholar 

  • Ryall P.J.C., Hall J. // Canad J. Earth. Sci. 1979. 16, Pt. 1. Р. 496.

    Google Scholar 

  • Shcherbakov V.P. The role of kinetics in the oxidation of titanomagnetite grains // Izv. AN SSSR. Ser. Physics of the Earth. 1982. № 5. P. 43–49.

    Google Scholar 

  • Shcherbakov VP, Gribov SK Theory of oxidation of titanomagnetite grains with a diffusion coefficient that depends sharply on the degree of oxidation, Izv. AN SSSR, Physics of the Earth, 1986, No. 4, pp. 105–112.

    Google Scholar 

  • Smith G., Banerjee S. // J. Geophys. Res. 1986. 91. Р. 10337.

    Google Scholar 

  • Stephenson A. // Geophys. R. J. astr. Soc. 1972. 29. Р. 91.

    Google Scholar 

  • Walderhaug H. // Geophys. J. Int. 1992. 111. Р. 335.

    Google Scholar 

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Correspondence to Ilia Iliushin .

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Iliushin, I., Afremov, L. (2019). Blocking Temperature and Hysteresis Characteristics of Nanoparticles of Oxidated Magnetite. In: Nurgaliev, D., Shcherbakov, V., Kosterov, A., Spassov, S. (eds) Recent Advances in Rock Magnetism, Environmental Magnetism and Paleomagnetism. Springer Geophysics. Springer, Cham. https://doi.org/10.1007/978-3-319-90437-5_15

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