Photochemistry pp 179-213 | Cite as

Charge and Energy Transfer Processes

Chapter
Part of the Theoretical Chemistry and Computational Modelling book series (TCCM)

Abstract

In this chapter we shall present the peculiar features of charge and excitation energy transfer processes (CT and ET) that are of basic importance in photosynthesis, photovoltaics, and other areas of biochemistry and technology. The migration of charge or excitation energy between distinct chromophores implies a dramatic change in the electronic wavefunction, so the general nonadiabatic theory we have already discussed also applies to these processes. However, some peculiar features distinguish charge and energy transfer from other nonadiabatic processes. If the two chromophores are placed in two molecules free to move in gas or liquid phase, the transition can only take place during a collision or encounter, so the kinetics of bimolecular processes plays an essential role. However, just because their interaction is a basic requirement for the process to occur, in structured biological or artificial photosystems the single units are fixed at suitable relative positions and orientations. In typical situations, such arrangements also determine easily discernable spectral features. Whenever the interaction between the involved chromophores is not too large, the initial and final electronic states of the CT or ET process constitute a physically sound diabatic representation, which allows to analyze theoretically the main features of the dynamics.

Keywords

Charge transfer Energy transfer Quenching Sensitization Exciton coupling 

Supplementary material

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© Springer International Publishing AG, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Department of Chemistry and Industrial ChemistryUniversity of PisaPisaItaly

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