Abstract
For the aim of valorization of local lignocelluloses natural residue from different activated carbon with a high surface areas were prepared by chemical activation using the phosphoric acid H3PO4 from the date stones of two locals varieties (Ghars and Mech Degla) of the regions of Biskra and El Oued in the south of Algeria and characterized by different techniques, the textural properties determined by N2 adsorption at 77 k and scanning electronic microscopy SEM. The surface function was found by the Boehm method and the elemental analysis of activated carbons was carried out.
The adsorption of the organic pollutant (COD) of wastewater from the common Sidi Khouiled (Ouargla) by the activated carbons CGB1, CGE1, CMB1 has been studied. Under the process conditions there is a maximum absorption capacity of this pollutant 62.5 mg/g for CGB1. The experimental data were well described by the isothermal equilibrium equation Langmuir type II and the calculated adsorption capacity was 71.43 mg/g comparable by models Freundlich and Temkin. The kinetics of COD adsorption obeys the intra cellular model.
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References
Dilek, A.: Production and characterization of activated carbon from sour cherry stones by zinc chloride. Fuel 115, 804–811 (2014)
Ahmad, A.A., Hameed, B.H.: Reduction of COD and color of dyeing effluent from a cotton textile mill by adsorption onto bamboo-based activated carbon. J. Hazard. Mater. 172, 1538–1543 (2009)
Allali-Hassani, M., Dusart, O., Mazet, M.: Elimination de micropolluants par adsorption sur charbon actif dans l’eau: cas d’un tensioactif non ionique; influence de co-adsorbats removal of non ionic surfactant from water onto activated carbon, influence of organic compounds. Water Res. 24, 699–708 (1990)
Auta, M., Hameed, B.H.: Preparation of waste tea activated carbon using potassium acetate as an activating agent for adsorption of Acid Blue 25 dye. Chem. Eng. J. 171, 502–509 (2011)
Belaid, O., Bebba, A.A., Sekirifa, M.L., Baameur, L., Al-Dujaili, A.H.: Preparation and characterization of chemically activated carbons from different varieties of date stones. Desalin. Water Treat. 65, 267–273 (2017)
Boehm, H.: Some aspects of the surface chemistry of carbon blacks and other carbons. Carbon 32, 759–769 (1994)
Bohli, T., Ouederni, A., Fiol, N., Villaescusa, I.: Evaluation of an activated carbon from olive stones used as an adsorbent for heavy metal removal from aqueous phases. C. R. Chim. 18, 88–99 (2015)
Danish, M., Hashim, R., Ibrahim, M.N.M., Sulaiman, O.: Optimized preparation for large surface area activated carbon from date (Phoenix dactylifera L.) stone biomass. Biomass Bioenergy 61, 167–178 (2014)
Djilani, C., Zaghdoudi, R., Djazi, F., Bouchekima, B., Lallam, A., Modarressi, A., Rogalski, M.: Adsorption of dyes on activated carbon prepared from apricot stones and commercial activated carbon. J. Taiwan Inst. Chem. Eng. 53, 112–121 (2015)
Foo, K.Y., Hameed, B.H.: An overview of dye removal via activated carbon adsorption process. Desalin. Water Treat. 19, 255–274 (2012)
Freundlich, H.: Über die adsorption in lösungen. Zeitschrift fur Physikalische Chemie 57, 385–470 (1907)
Fytianos, K., Voudrias, E., Kokkalis, E.: Sorption–desorption behaviour of 2, 4-dichlorophenol by marine sediments. Chemosphere 40, 3–6 (2000)
Hazzaa, R., Hussein, M.: Adsorption of cationic dye from aqueous solution onto activated carbon prepared from olive stones. Environ. Technol. Innov. 4, 36–51 (2015)
Ho, Y.-S., McKay, G.: Pseudo-second order model for sorption processes. Process Biochem. 34, 451–465 (1999)
Hoseinzadeh, H.R., Arami-Niya, A., Wan Daud, W.M.A., Sahu, J.N.: Comparison of oil palm shell-based activated carbons produced by microwave and conventional heating methods using zinc chloride activation. J. Anal. Appl. Pyrol. 104, 176–184 (2013)
Isah, A.U., Abdulraheem, G., Bala, S., Muhammad, S., Abdullahi, M.: Kinetics, equilibrium and thermodynamics studies of C.I. Reactive Blue 19 dye adsorption on coconut shell based activated carbon. Int. Biodeterior. Biodegrad. 102, 265–273 (2015)
Jung, S.-H., Oh, S.-J., Choi, G.-G., Kim, J.-S.: Production and characterization of microporous activated carbons and metallurgical bio-coke from waste shell biomass. J. Anal. Appl. Pyrol. 109, 123–131 (2014)
Kilic, M., Apaydin-Varol, E., Putun, A.E.: Adsorptive removal of phenol from aqueous solutions on activated carbon prepared from tobacco residues: equilibrium, kinetics and thermodynamics. J. Hazard. Mater. 189, 397–403 (2011)
Lagergren, S.: About the theory of so-called adsorption of soluble substances (1898)
Langmuir, I.: The constitution and fundamental properties of solids and liquids. Part I. solids. J. Am. Chem. Soc. 38, 2221–2295 (1916)
Liu, Y., Guo, Y., Gao, W., Wang, Z., Ma, Y., Wang, Z.: Simultaneous preparation of silica and activated carbon from rice husk ash. J. Clean. Prod. 32, 204–209 (2012)
Low, M.: Kinetics of chemisorption of gases on solids. Chem. Rev. 60, 267–312 (1960)
Rodier, J., Legube, B., Merlet, N.: Coll 2009: L’analyse de l’eau, 9 ème édn. DUNOD, Paris 1217 (2009)
Shi, Q., Zhang, J., Zhang, C., Li, C., Zhang, B., Hu, W., Xu, J., Zhao, R.: Preparation of activated carbon from cattail and its application for dyes removal. J. Environ. Sci. 22, 91–97 (2010)
Temkin, M., Pyzhev, V.: Recent modifications to Langmuir isotherms (1940)
Weber, W.J., Morris, J.C.: Kinetics of adsorption on carbon from solution. J. Sanit. Eng. Div. 89, 31–60 (1963)
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Belaid, O., Bebba, A.A., Barhoum, Z., Raache, I. (2018). Study of COD Adsorption on Deferent Activated Carbon Prepared from the Date Stones of the South of Algeria. In: Abdelbaki, B., Safi, B., Saidi, M. (eds) Proceedings of the Third International Symposium on Materials and Sustainable Development. SMSD 2017. Springer, Cham. https://doi.org/10.1007/978-3-319-89707-3_70
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