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Degradation Studies on PVC Plasticized Submitted to Gamma Radiation up to 50 KGy

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Proceedings of the Third International Symposium on Materials and Sustainable Development (SMSD 2017)

Abstract

Many of the applications require sterilization by gamma radiation. When polymeric materials are submitted to gamma radiation, changes are observed on their molecular structure. Poly (vinyl chloride) (PVC) plasticized with DOP is one of the major bulk polymers which is widely consumed in various applications.

In this study, the effect of gamma irradiation up to 50 KGy on mechanical properties (tensile strength, elongation at break and Young’s modulus) and the changes induced in the thermal analysis and morphology was investigated. The results revealed that the gamma irradiation affected considerably the PVC plasticized properties at 50 KGy. This degradation is due to the chain scission, which caused a reduction in the average molecular mass and cross-linking rate on one hand.

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References

  1. Hutzler, B.W., Machado, L.D.B., LugaÄo, A.B., Villavicencio, A.C.H.: Properties of irradiated PVC plasticized with non-endocrine disruptor. Radiat. Phy. Chem. 57, 381–384 (2000)

    Article  CAS  Google Scholar 

  2. Yagoubi, N., Baillet, A., Pellerin, F., Ferrier, D.: Beam Interactions with Materials and Atoms. 105, 340–344 (1995)

    CAS  Google Scholar 

  3. Cote, S.S., Vasconcelos, V., Senne, Jr, M., Cravalho, L.L., Rezende, D.B., Cȏrrea, R.F.: Changes in mechanical properties due to gamma irradiation of high-density polyethylene (HDPE). Braz. J. Chem. Eng. 24, 259–265 (2007)

    Article  CAS  Google Scholar 

  4. Chai, C.K., Ratnam, C.T., Abdullah, L.C., Amin, M.S.S.M., Wan Zin, W.M.: Effect of gamma radiation on the tensile properties of epoxidized natural rubber latex. Int. J. Inst. Mater. Malaysia 1, 223–232 (2013)

    Google Scholar 

  5. Byun, Y.J., Hong, S.I., Kim, K.B., Jeon, D.H., Kim, J.M., Whiteside, W.S., Park, H.J.: Physical and chemical properties of γ-irradiation EVOH film. Radiat. Phy. Chem. 76, 974–981 (2007)

    Article  CAS  Google Scholar 

  6. Ravi, H.R., Sreepad, H.R., Sajan, C.P.: Modification of dielectric and structural properties of PVC by gamma irradiation. Res. Rev. Polym. 3, 89–92 (2012)

    CAS  Google Scholar 

  7. Hutzler, B.W., Machado, L.D.B., Lugao, A.B., Villavicencio, A.C.H.: Properties of irradiated PVC plasticized with non-endovrine discruptor. Radiat. Phy. Chem. 57, 381–384 (2000)

    Article  CAS  Google Scholar 

  8. Kojima, K., Kumafuji, H., Ueno, K.: Dicoloration of plasticized PVC by irradiation. Radiat. Phys. Chem. 56, 859–863 (1981)

    Google Scholar 

  9. Saxena, A., Kalliyanakrishnan, V., Pal, V.N.: Studies on the effect of gamma irradiation on nontoxic PVC formulation. J. Appl. Polym. Sci. 34, 1727–1738 (1987)

    Article  CAS  Google Scholar 

  10. Labrosse, M.: Plastiques: essais normalisés. Technique de l’ingénieur A 3521, 1–8 (1996)

    Google Scholar 

  11. Vinhasa, G.M., Souto-Maiorb, R.M., Lapac, C.M., Bastos de Almeidad, Y.M.: Degradation studies on plasticized pvc films submitted to gamma radiation. Mater. Res. 6, 497–500 (2003)

    Article  Google Scholar 

  12. Ikhuoria, E.U., Ogundele, K.T., Osinkolu, G.A.: Effect of beta irradiation on plasticized poly (vinyl chloride). Afr. J. Pure Appl. Chem. 5, 333–338 (2011)

    CAS  Google Scholar 

  13. Mckellop, H.A.: Does gamma radiation speed or slow wear. Bull. Am. Acad. Orthop. Surg. 44, 511–523 (2006)

    Google Scholar 

  14. Premnth, V., Bellar, A., Merrill, E.W., Jasty, M., Harris, W.H.: Molecular rearrangements in ultra-high molecular weight polyethylene after irradiation and long-term storage in air. Polymer 40, 2215–2229 (1999)

    Article  Google Scholar 

  15. Jimenez, A., Lopez, J., Iannoni, A., Kenny, J.M.: Formulation and mechanical characterization of PVC plastisols based on low- toxicit additives. J. Appl. Polym. Sci. 18, 1881–1890 (2001)

    Article  Google Scholar 

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Acknowledgement

This study was funded by DGRSDT of the Ministry of Higher Education and Scientific Research (MESRS) of Algeria.

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Correspondence to N. Boutouchent-Guerfi .

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Boutouchent-Guerfi, N., Benaboura, A., Dib, A. (2018). Degradation Studies on PVC Plasticized Submitted to Gamma Radiation up to 50 KGy. In: Abdelbaki, B., Safi, B., Saidi, M. (eds) Proceedings of the Third International Symposium on Materials and Sustainable Development. SMSD 2017. Springer, Cham. https://doi.org/10.1007/978-3-319-89707-3_41

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