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The Effect of Cr-Doping on the Structure, Dielectric and Magnetic Properties of BiFeO3 and Pb(Fe0.5Sb0.5)O3 Multiferroics

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Part of the book series: Springer Proceedings in Physics ((SPPHY,volume 207))

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Abstract

X-ray diffraction and Mössbauer studies of perovskite BiFe1−xCr x O3 and PbFe0.5−xCr x Sb0.5O3 solid solution ceramics, fabricated under high pressure (4–6 GPa) have been carried out. Two morphotropic phase boundaries were revealed in the BiFe1−xCr x O3 system: one between rhombohedral (R3c) and orthorhombic (Pbam) phases at x ≈ 0.5–0.6 and the other between the orthorhombic (Pbam) and monoclinic (C2/c) phases at x ≈ 0.9. It was found out that substitution of Cr3+ for Fe3+ in BiFeO3 does not lead to the appearance of a low-spin state of Fe3+ ions, as was predicted by some first-principles calculations. A composition dependence of the magnetic phase transition temperature for BiFe1−xCr x O3 is very similar to that in the solid solutions of BiFeO3 with non-magnetic ions, implying the lack of magnetic exchange between Fe3+ and Cr3+. The reason of such behavior seems to be a difference in their electronic configuration. Addition of Cr to PbFe0.5Sb0.5O3 leads to a dramatic lowering and diffusion of the dielectric permittivity maximum and its shift to lower temperatures. Thus, Cr substitution for Fe seems to destroy both ferroelectric and magnetic long-range order in perovskite multiferroics.

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Acknowledgements

This study was partially supported by the Ministry of Education and Science of the Russian Federation (research project 3.5346.2017/BP), Russian Foundation for Basic Research (grant No 16-52-00072_Bel_a), Belarusian Republican Foundation for Basic Research (grant No T16R-079) and Research Committee of the University of Macau (Research & Development Grant for Chair Professor No RDG007/FST-CHD/2012).

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Authors and Affiliations

  1. Research Institute of Physics and Faculty of Physics, Southern Federal University, Rostov-on-Don, Russia

    S. I. Raevskaya, S. P. Kubrin, V. V. Titov, M. A. Malitskaya, I. P. Raevski, V. V. Stashenko & D. A. Sarychev

  2. Scientific-Practical Materials Research Centre of NAS of Belarus, 220072, Minsk, Belarus

    A. V. Pushkarev, N. M. Olekhnovich & Y. V. Radyush

  3. University of Macau, Macau, China

    H. Chen

  4. National Taiwan University of Science and Technology, Taipei, Taiwan, China

    C.-C. Chou

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  1. S. I. Raevskaya
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  1. I. I. Vorovich Mathematics, Mechanics and Computer Sciences Institute, Southern Federal University, Rostov-on-Don, Russia

    Ivan A. Parinov

  2. Department of Microelectronics Engineering, National Kaohsiung University of Science and Technology, Kaohsiung, Taiwan

    Shun-Hsyung Chang

  3. Indian Institute of Information Technology, Design and Manufacturing, Jabalpur, Jabalpur, Madhya Pradesh, India

    Vijay K. Gupta

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Raevskaya, S.I. et al. (2018). The Effect of Cr-Doping on the Structure, Dielectric and Magnetic Properties of BiFeO3 and Pb(Fe0.5Sb0.5)O3 Multiferroics. In: Parinov, I., Chang, SH., Gupta, V. (eds) Advanced Materials . PHENMA 2017. Springer Proceedings in Physics, vol 207. Springer, Cham. https://doi.org/10.1007/978-3-319-78919-4_16

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