Abstract
The structure and dielectric properties of a numbers of layered perovskite-like of Bi4+xSr2−xTi x Ta4−xO18 (x = 0.0, 0.5, 1.0, 1.5, 2.0) oxides with the APs structure have been studied. The temperature dependences of the relative permittivity ε/ε0(T) and tangents to the tangential dielectric losses tan δ have been measured. Single-phase and space groups (A21am, Z = 36) of the Aurivillius phases (m = 2) have been determined from X-ray powder diffraction data. The relationship between crystal lattice distortions (parameters a, b, c) and the chemical composition of synthesized compounds have been established. The temperature of the second-order phase transition from the paraelectric state to the ferroelectric state varies with the parameter x, respectively. The activation energies have been calculated.
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References
B. Aurivillius, Arkiv. Kemi 1(54), 463 (1949)
B. Aurivillius, Arkiv. Kemi 1(58), 499 (1949)
B. Aurivillius, Arkiv. Kemi 2(37), 512 (1950)
S.V. Zubkov, V.G. Vlasenko, J. Phys. Solid State 59(12), 2325 (2017)
S.V. Zubkov, V.G. Vlasenko, V.A. Shuvaeva, J. Phys. Solid State 58(1), 44 (2016)
B.H. Park, B.S. Kang, S.D. Bu, T.W. Noh, J. Lee, W. Jo, Nature 401, 682 (1999)
Y.T. Kim, C.W. Lee, Jpn. J. Appl. Phys. Part 1 35, 6153 (1996)
C.A. de Araujo, J.D. Cuchlaro, L.D. McMillan, M.C. Scott, J.F. Scott, Nature 374, 627 (1995)
K. Amanuma, T. Hase, Y. Miyasaka, Appl. Phys. Lett. 66, 221 (1995)
D. Ito, T. Yoshimura, N. Fujimura, T. Ito, Appl. Surf. Sci. 138, 159 (2000)
T. Kijima, Y. Fujisaki, H. Ishiwara, J. Appl. Phys. 40, 2977 (2001)
M. Dawber, K.M. Rabe, J.F. Scott, Rev. Mod. Phys. 77, 1083 (2005)
A.P. de Araujo, J.D. Cuchiaro, L.D. Mcmillan, M.C. Scott, J.F. Scott, Nature 374, 627 (1995)
S.B. Majumder, P.S. Dobal, S. Bhaskar, R.S. Katiyar, Ferroelectrics 241, 287 (2000)
Y. Cheol-Hoon, K. Jae-Sun, Y. Soon-Gil, Integr. Ferroelectr. 21, 475 (1998)
X. Chen, J. Xiao, Y. Xue, X. Zeng, F. Yang, P. Su, Ceram. Int. 40, 2635 (2014)
V.G. Vlasenko, V.A. Shuvaeva, S.I. Levchenkov, Ya.V. Zubavichus, S.V. Zubkov, J. Alloys Compd. 610, 184 (2014)
H. Zou, X. Hui, X. Wang, D. Peng, J. Li, Y. Li, X. Yao, J. Appl. Phys. 114, 223103 (2013)
H. Nakajima, T. Mori, S. Itoh, M. Watanabe, Solid State Commun. 129, 421 (2004)
F. Gao, G.J. Ding, H. Zhou, G.H. Wu, N. Qin, D.H. Bao, J. Electrochem. Soc. 158(5), G128 (2011)
W. Kraus, G. Nolze, Powder Cell for Windows, Version 2.3 (Federal Institute for Materials Research and Testing, Berlin, Germany, 1999)
V.M. Goldschmidt, Geochemisca Veterlun (Norske Videnkap, Oslo, 1927)
R.D. Shannon, Acta Crystallogr. Sect. A. Cryst. Phys. Diffr. Theor. Gen. Crystallogr. 32, 75 (1976)
V.A. Isupov, Zh Neorg, Khim. 39(5), 731 (1994)
V.A. Isupov, Inorg. Mater. 42(11), 1236 (2006)
E. Subbarao, Integr. Ferroelectr. 12, 33 (1996)
Y. Shimakawa, Y. Kubo, Y. Nakagawa, S. Got, T. Kamiyama, H. Asano, F. Izumi, Phys. Rev. B: Condens. Matter 61, 6559 (2001)
B. Jiménez, L. Pardo, A. Castro, P. Millán, R. Jiménez, M. Elaatmani, M. Oualla, Ferroelectrics 241, 279 (2000)
T. Sivakumar, M. Itoh, J. Mater. Chem. 21, 10865 (2011)
D.Y. Suarez, I.M. Reaney, W.E. Lee, J. Mater. Res. 16, 3139 (2001)
Acknowledgements
The work was performed with the financial support by the Ministry of Education and Science of the Russian Federation (Project No. 3.5710.2017/8.9).
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Zubkov, S.V. (2018). Structure and Dielectric Properties of Solid Solutions Bi4+xSr2−xTi x Ta4−xO18 (x = 0.0, 0.5, 1.0, 1.5, 2.0). In: Parinov, I., Chang, SH., Gupta, V. (eds) Advanced Materials . PHENMA 2017. Springer Proceedings in Physics, vol 207. Springer, Cham. https://doi.org/10.1007/978-3-319-78919-4_14
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