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Structure and Dielectric Properties of Solid Solutions Bi4+xSr2−xTi x Ta4−xO18 (x = 0.0, 0.5, 1.0, 1.5, 2.0)

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Advanced Materials (PHENMA 2017)

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Abstract

The structure and dielectric properties of a numbers of layered perovskite-like of Bi4+xSr2−xTi x Ta4−xO18 (x = 0.0, 0.5, 1.0, 1.5, 2.0) oxides with the APs structure have been studied. The temperature dependences of the relative permittivity ε/ε0(T) and tangents to the tangential dielectric losses tan δ have been measured. Single-phase and space groups (A21am, Z = 36) of the Aurivillius phases (m = 2) have been determined from X-ray powder diffraction data. The relationship between crystal lattice distortions (parameters a, b, c) and the chemical composition of synthesized compounds have been established. The temperature of the second-order phase transition from the paraelectric state to the ferroelectric state varies with the parameter x, respectively. The activation energies have been calculated.

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Acknowledgements

The work was performed with the financial support by the Ministry of Education and Science of the Russian Federation (Project No. 3.5710.2017/8.9).

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Correspondence to Sergei V. Zubkov .

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Zubkov, S.V. (2018). Structure and Dielectric Properties of Solid Solutions Bi4+xSr2−xTi x Ta4−xO18 (x = 0.0, 0.5, 1.0, 1.5, 2.0). In: Parinov, I., Chang, SH., Gupta, V. (eds) Advanced Materials . PHENMA 2017. Springer Proceedings in Physics, vol 207. Springer, Cham. https://doi.org/10.1007/978-3-319-78919-4_14

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