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Related Topics in Calorimetry

  • Lee D. Hansen
  • Mark K. Transtrum
  • Colette F. Quinn
Chapter
Part of the SpringerBriefs in Molecular Science book series (BRIEFSMOLECULAR)

Abstract

Many analytical applications of titration calorimetry were developed beginning in the 1960s when thermistors became available. Thermistors, with time constants <1 s and sufficient sensitivity to resolve a few micro-degrees, provided a convenient way to make rapid measurements of temperature that made continuous titration and single injection methods of analysis feasible with very simple equipment. These methods, variously known as thermometric titration, enthalpy titration, enthalpic injection, calorimetric titration, etc., were the forerunners to what eventually became known as isothermal titration calorimetry (ITC). In the titration methods, endpoints and thence concentrations of reactants are indicated by a change in heat production. In the injection methods, the measured amount of heat is divided by the ΔrH value to determine the amount of analyte. Several articles and reviews on analytical applications of titration calorimetry are given in the bibliography.

References

  1. Dukhopelnikov EV, Bereznyak EG, Khrebtova AS, Lantushenko AO, Zinchenko AV (2013) Determination of ligand to DNA binding parameters from two-dimensional DSC curves. J Therm Anal Calorim 111:1817–1827CrossRefGoogle Scholar
  2. Kujawa P, Winnik FM (2001) Volumetric studies of aqueous polymer solutions using pressure perturbation calorimetry: a new look at the temperature-induced phase transition of poly(N-isopropylacrylamide) in water and D2O. Macromolecules 34:4130CrossRefGoogle Scholar
  3. Lavoisier A, LaPlace P (1780) Memoire sur la chaleur, Memoires de l’Academie des Sciences, Paris (English translation: Gabriel ML, Fogel S (1955) Great experiments in biology. Prentice-Hall, Englewood Cliffs, pp 85–93)Google Scholar
  4. Randzio SL (2003) Comments on “volumetric studies of aqueous polymer solutions using pressure perturbation calorimetry . . . ” [Macromolecules 34 (2001) 4130]. Thermochim Acta 398:75–80CrossRefGoogle Scholar
  5. Randzio SL (2007) Scanning transitiometry and its applications. J Therm Anal Calorim 89(1):51–59CrossRefGoogle Scholar
  6. Wadsö L, Hansen LD (2015) Calorespirometry of terrestrial organisms and ecosystems. Methods 76:11–19CrossRefGoogle Scholar

Copyright information

© The Author(s) 2018

Authors and Affiliations

  • Lee D. Hansen
    • 1
  • Mark K. Transtrum
    • 2
  • Colette F. Quinn
    • 3
  1. 1.Department of Chemistry and BiochemistryBrigham Young UniversityProvoUSA
  2. 2.Department of Physics and AstronomyBrigham Young UniversityProvoUSA
  3. 3.TA InstrumentsLindonUSA

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