Abstract
This chapter provides an overview of in-situ application of infrared spectroscopic ellipsometry (IRSE) for the characterization of thin films on silicon (Si) prepared and modified by use of electrochemical surface treatments. In-situ IRSE investigations of Si surfaces during electrochemical grafting of ultra-thin layers via diazonium compounds (cathodic process), and thin polymeric layers of polypyrrole and polyaniline (both via anodic processes) are presented and discussed in detail. The film growth was monitored by an increase in layer specific vibrational signatures of molecules or monomers present on the surface or in the layer. Additionally, species postformed after electrochemical processing (i.e. after drying) and over-oxidation of the polymeric layer have been identified as well as the incorporation of dopants in the polymeric layer by their specific vibrational modes. The obtained results are discussed in frame of layer thickness, structure, and are compared to calculated IRSE spectra in case of very thin layers formed via cathodic reduction of diazonium compounds (nitrobenzene and maleimidobenzene) on Si.
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References
J. Rappich, A. Merson, K. Roodenko, T. Dittrich, M. Gensch, K. Hinrichs, Y. Shapira, J. Phys. Chem. B 110, 1332 (2006)
J. Rappich, K. Hinrichs, Electrochem. Commun. 11, 2316 (2009)
J.P. Busalmen, S.R.d Sánchez, D.J. Schiffrin, Appl. Environ. Microbiol. 64, 3690 (1998)
J.J. Ritter, M.J. Rodriguez, Corrosion 38, 223 (1982)
J.A. Petit, F. Dabosi, Corros. Sci. 20, 745 (1980)
J.C. Harper, R. Polsky, D.R. Wheeler, S.M. Brozik, Langmuir 24, 2206 (2008)
J.C. Harper, R. Polsky, D.R. Wheeler, D.M. Lopez, D.C. Arango, S.M. Brozik, Langmuir 25, 3282 (2009)
X. Zhang, A. Tretjakov, M. Hovestadt, G.G. Sun, V. Syritski, J. Reut, R. Volkmer, K. Hinrichs, J. Rappich, Acta Biomater. 9, 5838 (2013)
P.C.S. Hayfield, Surf. Sci. 56, 488 (1976)
M. Poksinski, H. Dzuho, H. Arwin, J. Electrochem. Soc. 150, B536 (2003)
S. Böhm, L.M. Peter, G. Schlichthörl, R. Greef, J. Electroanal. Chem. 500, 178 (2001)
K. Hinrichs, K. Roodenko, J. Rappich, Electrochem. Commun. 10, 315 (2008)
P.T. Hurley, A.E. Ribbe, J.M. Buriak, J. Am. Chem. Soc. 125, 11334 (2003)
P. Wagner, S. Nock, J.A. Spudich, W.D. Volkmuth, S. Chu, R.L. Cicero, C.P. Wade, M.R. Linford, C.E.D. Chidsey, J. Struct. Biol. 119, 189 (1997)
J. Rappich, P. Hartig, N.H. Nickel, I. Sieber, S. Schulze, T. Dittrich, Microelectron. Eng. 80, 62 (2005)
J. Rappich, X. Zhang, S. Chapel, G. Sun, K. Hinrichs, Phys. Stat. Sol. C 7, 210 (2010)
M. Gensch, K. Roodenko, K. Hinrichs, R. Hunger, A.G. Güell, A. Merson, U. Schade, Y. Shapira, Th Dittrich, J. Rappich, N. Esser, J. Vac. Sci. Technol. B 23, 1838 (2005)
G. Sun, M. Hovestaedt, X. Zhang, K. Hinrichs, D.M. Rosu, I. Lauermann, C. Zielke, A. Vollmer, H. Löchel, B. Ay, H.-G. Holzhütter, U. Schade, N. Esser, R. Volkmer, J. Rappich, Surf. Interface Anal. 43, 1203 (2010)
G. Sun, X. Zhang, C. Kaspari, K. Haberland, J. Rappich, K. Hinrichs, J. Electrochem. Soc. 159, H811 (2012)
K. Roodenko, J. Rappich, M. Gensch, N. Esser, K. Hinrichs, Appl. Phys. A 90, 175 (2008)
K. Hinrichs, M. Gensch, N. Esser, Appl. spectrosc. 59, 272A (2005)
Y.J. Chabal, P. Dumas, P. Guyot-Sionnest, G.S. Higashi, Surf. Sci. 242, 524 (1991)
J. Pinson, F. Podvorica, Chem. Soc. Rev. 34, 429 (2005)
M.M. Chehimi (ed.), Aryl Diazonium Salts: New Coupling Agents in Polymer and Surface Science (Wiley, Weinheim, 2012)
P. Allongue, M. Delamar, B. Desbat, O. Fagebaume, R. Hitmi, J. Pinson, J.-M. Saveant, J. Am. Chem. Soc. 119, 201 (1997)
P. Allongue, CHd Villeneuve, J. Pinson, F. Ozanam, J.N. Chazalviel, X. Wallart, Electrochim. Acta 43, 2791 (1998)
P. Hartig, J. Rappich, T. Dittrich, Appl. Phys. Lett. 80, 67 (2002)
P. Allongue, CHd Villeneuve, G. Cherouvrier, R. Corte‘s, M.-C. Bernard, J. Electroanal. Chem. 550/551, 161 (2003)
K. Roodenko, J. Rappich, F. Yang, X. Zhang, N. Esser, K. Hinrichs, Langmuir 25, 1445 (2009)
M. Estes, G. Moddel, Appl. Phys. Lett. 68, 1814 (1996)
J. Rappich, Phys. Stat. Sol. C 1, 1169 (2004)
W. Theiß, Surf. Sci. Rep. 29, 91 (1997)
R. Hunger, W. Jaegermann, A. Merson, Y. Shapira, C. Pettenkofer, J. Rappich, J. Phys. Chem. B 110, 15432 (2006)
R. Tomita, S. Urano, S. Kohiki, Chem. Lett. 30, 684 (2001)
J. Rappich, H.J. Lewerenz, J. Electrochem. Soc. 142, 1233 (1995)
J. Rappich, H.J. Lewerenz, Electrochim. Acta 41, 675 (1996)
A. Belaïdi, J.-N. Chazalviel, F. Ozanam, O. Gorochov, A. Chari, B. Fotouhi, M. Etman, J. Electroanal. Chem. 444, 55 (1998)
S.F. Parker, S.M. Mason, K.P.J. Williams, Spectrochim. Acta Part A Mol. Spectrosc. 46, 315 (1990)
P. Kanyong, G. Sun, F. Rösicke, V. Syritski, U. Panne, K. Hinrichs, J. Rappich, Electrochem. Commun. 51, 103 (2015)
F. Rösicke, M.A. Gluba, T. Shaykhutdinov, G. Sun, C. Kratz, J. Rappich, K. Hinrichs, N.H. Nickel, Chem. Commun. 53, 9308 (2017)
S. Asavapiriyanont, G.K. Chandler, G.A. Gunawardena, D. Pletcher, J. Electroanal. Chem. 177, 229 (1984)
G.P. Gardini, Adv. Heterocycl. Chem. 15, 67 (1973)
P. Rapta, A. Neudeck, A. Petr, L. Dunsch, J. Chem. Soc., Faraday Trans. 94, 3625 (1998)
U. Rammelt, S. Bischo, M. El-Dessouki, R. Schulze, W. Plieth, L. Dunsch, J. Solid State Electrochem. 3, 406 (1999)
C.M. Intelmann, K. Hinrichs, V. Syritski, F. Yang, J. Rappich, Jpn. J. Appl. Phys. Part I 47, 554 (2008)
C.M. Intelmann, V. Syritski, D. Tsankov, K. Hinrichs, J. Rappich, Electrochim. Acta 53, 4046 (2008)
J.P. Wang, Y. Xua, J. Wang, X. Dua, F. Xiao, J. Li, Synth. Metals 160, 1826 (2010)
Y.-C. Liu, B.-J. Hwang, W.-J. Jian, R. Santhanam, Thin Solid Films 374, 85 (2000)
P.P. Sengupta, P. Kar, B. Adhikari, Thin Solid Films 517, 3774 (2009)
S. Logothetidis, A. Laskarakis, Thin Solid Films 518, 1248 (2009)
Acknowledgements
The financial support of the European Union through the EFRE program (ProFIT grant, contract no. 10131870/1 and no. 10144388), the Senatsverwaltung für Wissenschaft, Forschung und Kultur des Landes Berlin and the Bundesministerium für Bildung, Wissenschaft, Forschung und Technologie are gratefully acknowledged. The author thanks Dr. M. Gensch, Dr. K. Roodenko, Dr. V. Syritski, and Dr. M.C. Intelmann for valuable discussions.
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Rappich, J., Hinrichs, K., Sun, G., Zhang, X. (2018). Application of In-Situ IR-Ellipsometry in Silicon Electrochemistry to Study Ultrathin Films. In: Hinrichs, K., Eichhorn, KJ. (eds) Ellipsometry of Functional Organic Surfaces and Films. Springer Series in Surface Sciences, vol 52. Springer, Cham. https://doi.org/10.1007/978-3-319-75895-4_20
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