Abstract
The widespread of organic and inorganic pollutants in wastewater from various industries, are responsible for serious environmental problems meanwhile represent a danger for human being. Therefore, the search of cost-effective methods of wastewater treatment containing in particular heavy metals and dyes, become of great importance. Noteworthy, adsorption has proven to be most effective technology for purification of wastewater from organic and inorganic pollutants. In this review, different types of green and ecofriendly materials (biosorbents, graphene-based composites, metal oxides, etc.) for dyes and heavy metals adsorption will be discussed. The biosorbents such as agricultural waste materials (waste seeds, orange peel, exhausted coffee ground powder, wood apple shell, sweet potato peels, wheat straws, etc.), activated carbon prepared from different types of agricultural waste (coconut husk, forest and wood-processing residues, papaya seeds, magnetic biochar etc.), graphene-based adsorbents and their derivatives, obtained by eco-friendly green synthesis, have been discussed and their adsorption activity has been described in details.
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsReferences
Abia AA, Harsfall M, Didi O (2003) The use of chemically modified and unmodified cassava waste for the removal of Cd, Cu and Zn ions from aqueous solution. Bioresour Technol 90:345–348
Abollino O, Aceto M, Malandrino M et al (2003) Adsorption of heavy metals on Na-montmorillonite. Effect of pH and organic substances. Water Res 37:1619–1627
Adebisi JA, Agunsoye JO, Bello SA et al (2017) Potential of producing solar grade silicon nanoparticles from selected agro-wastes. Sol Energy 142:68–86
Adegoke KA, Bello OS (2015) Dye sequestration using agricultural wastes as adsorbents. Water Res Ind 12:8–24. https://doi.org/10.1016/j.wri.2015.09.002
Adio SO, Omar MH, Asif M et al (2017) Arsenic and selenium removal from water using biosynthesized nanoscale zero-valent iron: a factorial design analysis. Process Saf Environ Prot 107:518–527
Aghababaei A, Ncibi MC, Sillanpää M (2017) Optimized removal of oxytetracycline and cadmium from contaminated waters using chemically-activated and pyrolyzed biochars from forest and wood-processing residues. Bioresour Technol 239:28–36. https://doi.org/10.1016/j.biortech.2017.04.119
Ahluwalia SS, Goyal D (2005) Removal of heavy metals by waste tea leaves from aqueous solution. Eng Life Sci 5:158–162
Ahmed FM (2001) An overview of arsenic removal technologies in Bangladesh and India. In: Feroze Ahmed M et al (eds) Technologies for arsenic removal from drinking water. A compilation of papers presented at the international workshop on technologies for arsenic removal from drinking water. Bangladesh University of Engineering and Technology, Dhaka, Bangladesh and the United Nations University, Tokyo, May 2001
Al Hamouz OCS, Adelabu IO, Saleh TA (2017a) Novel cross-linked melamine based polyamine/CNT composites for lead ions removal. J Environ Manage 192:163–170
Al Hamouz OCS, Estatie M, Tawfik A (2017b) Saleh removal of cadmium ions from wastewater by dithiocarbamate functionalized pyrrole based terpolymers. Sep Purif Technol 177:101–109
Albadarin AB, Charara M, Tarboush BJA et al (2017) Mechanism analysis of tartrazine biosorption onto masau stones; a low cost by-product from semi-arid regions. J Mol Liq 242:478–483. https://doi.org/10.1016/j.molliq.2017.07.045
Alhogbi BG (2017) Potential of coffee husk biomass waste for the adsorption of Pb(II) ion from aqueous solutions. Sustain Chem Pharm 6:21–25. https://doi.org/10.1016/j.scp.2017.06.004
Ali A (2017) Removal of Mn(II) from water using chemically modified banana peels as efficient adsorbent. Environ Nanotech Monit Manage 7:57–63. https://doi.org/10.1016/j.enmm.2016.12.004
Ali HR, Hassaan MA (2017) Applications of bio-waste materials as green synthesis of nanoparticles and water purification. Adv Mater Chem 1(1):6–22. https://doi.org/10.11648/j.amc.20170101.12
Ali A, Saeed K, Mabood F (2016) Removal of chromium (VI) from aqueous medium using chemically modified banana peels as efficient low-cost adsorbent. Alex Eng J 55(3):2933–2942. https://doi.org/10.1016/j.aej.2016.05.011
Aljeboree AM, Alshirifi AN, Alkaim AF (2017) Kinetics and equilibrium study for the adsorption of textile dyes on coconut shell activated carbon. Arab J Chem 10(2):S3381–S3393. https://doi.org/10.1016/j.arabjc.2014.01.020
Almubaddal F, Alrumaihi K, Ajbar A (2009) Performance optimization of coagulation/flocculation in the treatment of wastewater from a polyvinyl chloride plant. J Hazard Mater 161:431–438
Alqadami AA, Naushad M, Abdalla MA et al (2017) Efficient removal of toxic metal ions from wastewater using a recyclable nanocomposite: a study of adsorption parameters and interaction mechanism. J Clean Prod 156:426–436. https://doi.org/10.1016/j.jclepro.2017.04.085
Al-Shehri S, Al-Senany N, Altuwirqi R et al (2017) Green synthesis of CuxO nanoscale MOS capacitors processed at low temperatures. Surf Coat Technol 320:246–251
Alshehri SM, Naushad M, Ahamad T et al (2014) Synthesis, characterization of curcumin based ecofriendly antimicrobial bio-adsorbent for the removal of phenol from aqueous medium. Chem Eng J 254:181–189. https://doi.org/10.1016/j.cej.2014.05.100
Alslaibi TM, Abustan I, Ahmad MA et al (2014) Comparison of activated carbon prepared from olive stones by microwave and conventional heating for iron (II), lead (II), and copper (II) removal from synthetic wastewater. Environ Prog Sustain Energy 33:1074–1085
Al-Zoubi H, Ibrahim KA, Abu-Sbeih KA (2015) Removal of heavy metals from wastewater by economical polymeric collectors using dissolved air flotation process. J Water Process Eng 8:19–27
Amiri M, Salavati-Niasari M, Akbari A et al (2017) Removal of malachite green (a toxic dye) from water by cobalt ferrite silica magnetic nanocomposite: herbal and green sol-gel autocombustion synthesis. Int J Hydrogen Energy 4:24846–24860
Anand K, Tilokea C, Naidoo P et al (2017) Phytonanotherapy for management of diabetes using green synthesis nanoparticles. J Photochem Photobiol, B: Biol 173:626–639
Anastopoulos I, Kyzas GZ (2015) Progress in batch biosorption of heavy metals onto algae. J Mol Liq 209:77–86. https://doi.org/10.1016/j.molliq.2015.05.023
Anastopoulos I, Karamesouti M, Mitropoulos AC et al (2017) A review for coffee adsorbents. J Mol Liq 229:555–565. https://doi.org/10.1016/j.molliq.2016.12.096
Angelis GD, Medeghini L, Conte AM et al (2017) Recycling of eggshell waste into low-cost adsorbent for Ni removal from wastewater. J Clean Prod 164:1497–1506. https://doi.org/10.1016/j.jclepro.2017.07.085
Archana B, Manjunath K, Nagaraju G et al (2017) Enhanced photocatalytic hydrogen generation and photostability of ZnO nanoparticles obtained via green synthesis. Int J Hydrogen Energy 42:5125–5131
Aryal M, Ziagova M, Liakopoulou-Kyriakides M (2010) Study on arsenic biosorption using Fe(III)-treated biomass of Staphylococcus xylosus. Chem Eng J 162:178–185
Asasian N, Kaghazchi T, Soleimani M (2012) Elimination of mercury by adsorption onto activated carbon prepared from the biomass material. J Ind Eng Chem 18:283–289
Asuquo ED, Martin AD (2016) Sorption of cadmium (II) ion from aqueous solution onto sweet potato (Ipomoea batatas L.) peel adsorbent: characterisation, kinetic and isotherm studies. J Environ Chem Eng 4(4):4207–4228. https://doi.org/10.1016/j.jece.2016.09.024
Attari M, Bukhari SS, Kazemian H et al (2017) A low-cost adsorbent from coal fly ash for mercury removal from industrial wastewater. J Environ Chem Eng 5:391–399
Awual MR (2016a) Assessing of lead(III) capturing from contaminated wastewater using ligand doped conjugate adsorbent. Chem Eng J 289:65–73
Awual MR (2016b) Novel nanocomposite materials for efficient and selective mercury ions capturing from wastewater. Chem Eng J 307:456–465
Awual MR, Hasan MM, Shahat A et al (2015) Investigation of ligand immobilized nano-composite adsorbent for efficient cerium(III) detection and recovery. Chem Eng J 265:210–218. https://doi.org/10.1016/j.cej.2014.12.052
Awual MR, Hasan MM, Eldesoky GE et al (2016a) Facile mercury detection and removal from aqueous media involving ligand impregnated conjugate nanomaterials. Chem Eng J 290:243–251
Awual MR, Hasan MM, Khaleque MA et al (2016b) Treatment of copper(II) containing wastewater by a newly developed ligand based facial conjugate materials. Chem Eng J 288:368–376
Ayyappan R, Sophia CA, Swaminathan K et al (2005) Removal of Pb (II) from aqueous solution using carbon derived from agricultural wastes. Process Biochem 4:1293–1299
Babel S, Kurniawan TA (2003) Low-cost adsorbents for heavy metal uptake from contaminated water: a review. J Hazard Mater 97:219–243
Baca R, Cheong KY (2015) Green synthesis of iron oxide thin-films grown from recycled iron foils. Mater Sci Semicond Process 29:294–299
Badawi MA, Negm NA, Abou Kana MTH et al (2017) Adsorption of aluminum and lead from wastewater by chitosan-tannic acid modified biopolymers: isotherms, kinetics, thermodynamics and process mechanism. Int J Biomacromol. https://doi.org/10.1016/j.ijbiomac.2017.03.003
Bahadir T, Bakan G, Altas L et al (2007) The investigation of lead removal by biosorption: an application at storage battery industry wastewaters. Enzyme Microb Technol 41:98–102
Banerjee S, Chattopadhyaya MC (2017) Adsorption characteristics for the removal of a toxic dye, tartrazine from aqueous solutions by a low cost agricultural by-product. Arab J Chem 10:S1629–S1638. https://doi.org/10.1016/j.arabjc.2013.06.005
Bao S, Li K, Ning P et al (2016) Highly effective removal of mercury and lead ions from wastewater by mercaptoamine-functionalised silica-coated magnetic nano-adsorbents: behaviours and mechanisms. Appl Surf Sci 393:457–466
Barakat MA (2011) New trends in removing heavy metals from industrial wastewater. Arab J Chem 4:361–377
Barquilha CER, Cossich ES, Tavares CRG et al (2017) Biosorption of nickel(II) and copper(II) ions in batch and fixed-bed columns by free and immobilized marine algae Sargassum sp. J Clean Prod 150:58–64. https://doi.org/10.1016/j.jclepro.2017.02.199
Bartczak P, Norman M, Klapiszewski Ł et al (2015) Removal of nickel(II) and lead(II) ions from aqueous solution using peat as a low-cost adsorbent: a kinetic and equilibrium study. Arab J Chem. https://doi.org/10.1016/j.arabjc.2015.07.018
Bharath G, Alhseinat E, Ponpandian N et al (2017) Development of adsorption and electrosorption techniques for removal of organic and inorganic pollutants from wastewater using novel magnetite/porous graphene-based nanocomposites. Sep Purif Technol 188:206–218. https://doi.org/10.1016/j.seppur.2017.07.024
Bhargavi SD, Savitha J (2014) Arsenate resistant Penicillium coffeae: a potential fungus for soil bioremediation. Bull Environ Contam Toxicol 92:369–373
Bibi I, Nazar N, Iqbal M, Kamal S, Nawaz H, Nouren S, Safa Y, Jilani K, Sultan M, Ata S, Rehman F, Abbas M (2017) Green and eco-friendly synthesis of cobalt-oxide nanoparticle: characterization and photo-catalytic activity. Adv Powder Technol 28:2035–2043
Bulgariu L, Bulgariu D (2014) Enhancing biosorption characteristics of marine green algae (Ulva lactuca) for heavy metals removal by alkaline treatment. J Bioprocess Biotechniques 4:146
Bulut Y, Tez Z (2003) Removal of heavy metal ions by modified sawdust of walnut. Fresen Environ Bull 12:1499–1504
Bulut Y, Tez Z (2007) Adsorption studies on ground shells of hazelnut and almond. J Hazard Mater 149:35–41
Carolin CF, Kumar PS, Saravanan A et al (2017) Efficient techniques for the removal of toxic heavy metals from aquatic environment: a review. J Environ Chem Eng 5:2782–2799
Cho ES, Kim J, Tejerina B et al (2012) Ultrasensitive detection of toxic cations through changes in the tunnelling current across films of striped nanoparticles. Nat Mater 11(2012):978–985
Choi JM, Jeong D, Cho E et al (2016) Chemically functionalized silica gel with alkynyl terminated monolayers as an efficient new material for removal of mercury ions from water. J Ind Eng Chem 35:376–382
Choudhary R, Patra S, Madhuria R et al (2017) Designing of carbon based fluorescent nanosea-urchin via green-synthesis approach for live cell detection of zinc oxide nanoparticle. Biosens Bioelectron 91:472–481
Chowdhury S, Mazumder MAJ, Al-Attas O et al (2016) Heavy metals in drinking water: occurrences, implications, and future needs in developing countries. Sci Total Environ 569–570:476–488
Chuang CL, Fan M, Xu M et al (2005) Adsorption of arsenic(V) by activated carbon prepared from oat hulls. Chemosphere 61:478–483
Dai B, Cao M, Fang G et al (2012) Schiff base-chitosan grafted multiwalled carbon nanotubes as a novel solid-phase extraction adsorbent for determination of heavy metal by ICP-MS. J Hazard Mater 219–220:103–110
Deb KS, Dwivedi V, Dasgupta K et al (2016) Novel Amidoamine functionalized multi-walled carbon nanotubes for removal of mercury(II) ions from wastewater: combined experimental and density functional theoretical approach. Chem Eng J 313:899
Debbaudt AL, Ferreira ML, Gschaider ME (2004) Theoretical and experimental study of M2 adsorption on biopolymers III: comparative kinetic pattern of Pb, Hg and Cd. Carbohydr Polym 56:321–332
Demirbas A (2008) Heavy metal adsorption onto agro-based waste materials: a review. J Hazard Mater 157:220–229
Devani MA, Munshi B, Oubagaranadin JUK et al (2017) Remediation of Hg(II) from solutions using Cajanus cajan husk as a new sorbent. Environ Technol 38:1878–1886
Dong C, Lu J, Qiu B et al (2017) Developing stretchable and graphene-oxide-based hydrogel for the removal of organic pollutants and heavy metal ions. Appl Catal B: Environ. https://doi.org/10.1016/j.apcatb.2017.10.011
Doyurum S, Celik A (2006) Pb(II) and Cd(II) removal from aqueous solutions by olive cake. J Hazard Mater 138:22–28
Duan Y, Han DS, Batchelor B et al (2016) Synthesis, characterization, and application of pyrite for removal of mercury. Colloid Surf Aspects 490:326–335
Ebtesam EB, Helmy S, Hussien H et al (2013) Bioremediation of heavy metal-contaminated effluent using optimized activated sludge bacteria. Appl Water Sci 3:181–192
El-Shafey EI, Cox M, Pichugin AA et al (2002) Application of a carbon sorbent for the removal of cadmium and other heavy metal ions from aqueous solution. J Chem Tech Biotechnol 77:429–436
Etim UJ, Umoren SA, Eduok UM (2016) Coconut coir dust as a low cost adsorbent for the removal of cationic dye from aqueous solution. J Saud Chem Soc 20:S67–S76. https://doi.org/10.1016/j.jscs.2012.09.014
Farhan AM, Salem NM, Ahmad AL et al (2012) Kinetic, equilibrium and thermodynamic studies on the biosorption of heavy metals by Ceratonia siliqua bark. Am J Chem 2:335–342
Fawzy MA (2016) Phycoremediation and adsorption isotherms of cadmium and copper ions by Merismopedia tenuissima and their effect on growth and metabolism. Environ Toxicol Pharmacol 46:116–121
Feng Y, Liu Y, Xue L et al (2017) Carboxylic acid functionalized sesame straw: a sustainable cost-effective bioadsorbent with superior dye adsorption capacity. Bioresour Technol 238:675–683. https://doi.org/10.1016/j.biortech.2017.04.066
Fiol N, Villaescusa I, Martinez M et al (2006) Sorption of Pb(II), Ni(II), Cu(II) and Cd(II) from aqueous solution by olive stone waste. Sep Purif Technol 50:132–140
Gercel O, Gercel HF (2007) Adsorption of lead(II) ions from aqueous solutions by activated carbon prepared from biomass plant material of Euphorbia rigida. Chem Eng J 132:289–297
Ghidan AY, Al-Antary TM, Awwad AM (2016) Green synthesis of copper oxide nanoparticles using Punica granatum peels extract: effect on green peach. Environ Nanotech, Monit & Manage 6:95–98
Ghodbane I, Nouri K, Hamdaoui O et al (2008) Kinetic and equilibrium study for the sorption of cadmium (II) ions from aqueous phase by eucalyptus bark. J Hazard Mater 152:148–158
Gokila S, Gomathi T, Sudha PN et al (2017) Removal of the heavy metal ion chromium (VI) using chitosan and alginate nanocomposites. Int J Biol Macromol 104(B):1459–1468. https://doi.org/10.1016/j.ijbiomac.2017.05.117
Gueu S, Yao B, Adouby K et al (2007) Kinetics and thermodynamics study of lead adsorption on to activated carbons from coconut and seed hull of the palm tree. Int J Environ Sci Technol 4:11–17
Guo H, Jiao T, Zhang Q et al (2015) Preparation of graphene oxide-based hydrogels as efficient dye adsorbents for wastewater treatment. Nanoscale Res Lett 10:272. https://doi.org/10.1186/s11671-015-0931-2
Hafshejani LD, Tangsir S, Daneshvaret E et al (2017) Optimization of fluoride removal from aqueous solution by Al2O3 nanoparticles. J Mol Liq 238:254–262
Hakami O, Zhang Y, Banks CJ (2015) Thiol-functionalised mesoporous silica-coated magnetite nanoparticles for high efficiency removal and recovery of Hg from water. Water Res 46:3913–3922
Halouane F, Oz Y, Meziane D et al (2017) Magnetic reduced graphene oxide loaded hydrogels: highly versatile and efficient adsorbents for dyes and selective Cr(VI) ions removal. J Colloid Interface Sci 507:360–369. https://doi.org/10.1016/j.jcis.2017.07.075
Hameed KS, Muthirulan P, Sundaram MM (2017) Adsorption of chromotrope dye onto activated carbons obtained from the seeds of various plants: equilibrium and kinetics studies. Arab J Chem 10(2):S2225–S2233. https://doi.org/10.1016/j.arabjc.2013.07.058
Harper TR, Kingham NW (1992) Removal of arsenic from wastewater using chemical precipitation methods. Water Environ Res 64:200–203
Harris HH, Pickering IJ, George GN (2003) The chemical form of mercury in fish. Science 301(5637):1203
Hayashi J, Kazehaya A, Muroyama K et al (2000) Preparation of activated carbon from lignin by chemical activation. Carbon 38(13):1873–1878. https://doi.org/10.1016/S0008-6223(00)00027-0
Hesami F, Bina B, Ebrahimi A, Amin MM (2013) Arsenic removal by coagulation using ferric chloride and chitosan from water. Int J Environ Health Eng 2(17). https://doi.org/10.4103/2277-9183.110170
Ho YS, Chiu WT, Wang CC (2005) Equilibrium isotherms and kinetic studies of removal of methylene blue dye by adsorption onto Miswak leaves as a natural adsorbent. Bioresour Technol 96:1285–1291
Hossain M, Ngo HH, Guo WS (2012) Adsorption and desorption of copper(II) ions onto garden grass. Bioresour Technol 121:386–395
Hubadillah SK, Othman MHD, Harun Z et al (2017) A novel green ceramic hollow fiber membrane (CHFM) derived from rice husk ash as combined adsorbent-separator for efficient heavy metals removal. Ceram Int 43(5):4716–4720. https://doi.org/10.1016/j.ceramint.2016.12.122
Hussain MD, Haque MA, Islam MM et al (2001) Approaches for removal of arsenic from tubewell water for drinking purpose. In: Feroze Ahmed M et al (eds) Technologies for arsenic removal from drinking water. A compilation of papers presented at the international workshop on technologies for arsenic removal from drinking water. Bangladesh University of Engineering and Technology, Dhaka, Bangladesh and the United Nations University, Tokyo, May 2001
Imamoglu M, Tekir O (2008) Removal of copper (II) and lead (II) ions from aqueous solutions by adsorption on activated carbon from a new precursor hazelnut husks. Desalination 228:108–113
Islam M, Patel RK (2008) Polyacrylamide thorium (IV) phosphate as an important lead selective fibrous ion exchanger: synthesis, characterization and removal study. J Hazard Mater 156:509–520
Jafari MH, Mahvi A, Jonidi JA (2014) Removal of lead and zinc from battery industry wastewater using electrocoagulation process: influence of direct and alternating current by using iron and stainless steel rod electrodes. Sep Purif Technol 135:165–175
Jassal V, Shanker U, Gahlota S (2016) Green synthesis of some iron oxide nanoparticles and their interaction with 2-Amino, 3-Amino and 4-aminopyridines. Mater Today: Proc 3:1874–1882
Jawad AH, Sabar S, Ishak MAM et al (2017) Microwave-assisted preparation of mesoporous-activated carbon from coconut (Cocos nucifera) leaf by H3PO4 activation for methylene blue adsorption. Chem Eng Commun 204(10):1143–1156
Jia Y, Wu C, Lee BW et al (2017) Magnetically separable sulfur-doped SnFe2O4/graphene nanohybrids for effective photocatalytic purification of wastewater under visible light. J Hazard Mater 338:447–457. https://doi.org/10.1016/j.jhazmat.2017.05.057
Jiao Y, Wan C, Li J (2016) Synthesis of carbon fiber aerogel from natural bamboo fiber and its application as a green high-efficiency and recyclable adsorbent. Mater Design 107:26–32. https://doi.org/10.1016/j.matdes.2016.06.015
Johari K, Saman N, Song ST (2016) Adsorption enhancement of elemental mercury by various surface modified coconut husk as eco-friendly low-cost adsorbents. Int Biodeterior Biodegradation 109:45–52. https://doi.org/10.1016/j.ibiod.2016.01.004
John AC, Ibironke LO, Adedeji V et al (2011) Equilibrium and kinetic studies of the biosorption of heavy metals (cadmium) on Cassia siamea bark. Am-Eur J Sci Res 6:123–130
Jungcharoen P, O’Carroll D, Anotai J et al (2017) Synthesis of lignin-modified nanoscale zerovalent iron applied to arsenic removal. Full Paper Proc ECBA 3(9):1–6
Kadirvelu K, Namasivayam C (2000) Agricultural byproduct as metal adsorbent: sorption of lead(II) from aqueous solution onto coir pith carbon. Environ Tech 21:1091–1097
Kagramanov GG, Farnosova EN, Kandelaki GI (2009) Heavy metal cationic wastewater treatment with membrane methods. In: Václavíková M, Vitale K, Gallios GP, Ivaničová L (eds) Water treatment technologies for the removal of high-toxicity pollutants. NATO science for peace and security series C: environmental security. Springer, Dordrecht, pp 61–84
Karthik K, Dhanuskodi S, Gobinath C et al (2017a) Andrographis paniculata extract mediated green synthesis of CdO nanoparticles and its electrochemical and antibacterial studies. J Mater Sci: Mater Electron. https://doi.org/10.1007/s10854-017-6503-8
Karthik K, Dhanuskodi S, Kumar SP (2017b) Microwave assisted green synthesis of MgO nanorods and their antibacterial and anti-breast cancer activities. Mater Lett 206:217–220. https://doi.org/10.1016/j.matlet.2017.07.004
Kepner B, Spotts J, Mintz E et al (1998) Removal of arsenic from drinking water with enhanced hybrid aluminas and composite metal oxide particles. In: International conference on arsenic pollution of groundwater: causes, effects, remedies, Dhaka Community Hospital, Dhaka, Bangladesh
Khan MA, Alam MM, Naushad Mu et al (2015) Sol–gel assisted synthesis of porous nano-crystalline CoFe2O4 composite and its application in the removal of brilliant blue-R from aqueous phase: an ecofriendly and economical approach. Chem Eng J 279:416–424
Krishnaiah D, Joseph CG, Anisuzzaman SM et al (2017) Removal of chlorinated phenol from aqueous solution utilizing activated carbon derived from papaya (Carica papaya) seeds. Korean J Chem Eng 34:1377. https://doi.org/10.1007/s11814-016-0337-6
Krishnan KA, Anirudhan TS (2002) Uptake of heavy metals in batch systems by sulfurized steam activated carbon prepared from sugarcane bagasse pith. Ind Eng Chem Res 41:5085–5093
Kuang Y, Wang Q, Chen Z et al (2013) Heterogeneous Fenton-like oxidation of monochlorobenzene using green synthesis of iron nanoparticles. J Colloid Interface Sci 410:67–73
Kumar A, Jena HM (2015) High surface area microporous activated carbons prepared from Fox nut (Euryale ferox) shell by zinc chloride activation. Appl Surf Sci 356:753–761. https://doi.org/10.1016/j.apsusc.2015.08.074
Kumar A, Jena HM (2016) Preparation and characterization of high surface area activated carbon from Fox nut (Euryale ferox) shell by chemical activation with H3PO4. Results Phys 6:651–658. https://doi.org/10.1016/j.rinp.2016.09.012
Kumar A, Jena HM (2017a) Adsorption of Cr(VI) from aqueous phase by high surface area activated carbon prepared by chemical activation with ZnCl2. Process Saf Environ Prot 109:63–71. https://doi.org/10.1016/j.psep.2017.03.032
Kumar A, Jena HM (2017b) Adsorption of Cr(VI) from aqueous solution by prepared high surface area activated carbon from Fox nutshell by chemical activation with H3PO4. J Environ Chem Eng 5(2):2032–2041. https://doi.org/10.1016/j.jece.2017.03.035
Kumar U (2006) Agricultural products and by-products as a low cost adsorbent for heavy metal removal from water and waste-water: a review. Sci Res Essays 1:33–37
Kumar A, Sharma G, Naushad Mu et al (2015) SPION/β-cyclodextrin core–shell nanostructures for oil spill remediation and organic pollutant removal from waste water. Chem Eng J 280:175–187
Kumar A, Kumar A, Sharma G et al (2017) Sustainable nano-hybrids of magnetic biochar supported gC3N4/FeVO4 for solar powered degradation of noxious pollutants-synergism of adsorption, photocatalysis & photo-ozonation. J Clean Prod 165:431–451
Lam SS, Liew RK, Wong YM et al (2017) Microwave-assisted pyrolysis with chemical activation, an innovative method to convert orange peel into activated carbon with improved properties as dye adsorbent. J Clean Prod 162:1376–1387. https://doi.org/10.1016/j.jclepro.2017.06.131
Leyva-Ramos R, Rangel-Mendez JR, Mendoza-Barron J et al (1997) Adsorption of cadmium (II) from aqueous solution onto activated carbon. Water Sci Technol 35:205–211
Li K, Wang X (2008) Adsorptive removal of Pb(II) by activated carbon prepared from Spartina alterniflora: equilibrium, kinetics and thermodynamics. Bioresour Technol 100(2009):2810–2815
Li C, Zhuang Z, Jin X, Chena Z (2017a) A facile and green preparation of reduced graphene oxide using Eucalyptus leaf extract. Appl Surf Sci 422:469–474
Li X, Peng W, Jia Y et al (2017b) Removal of cadmium and zinc from contaminated wastewater using Rhodobacter sphaeroides. Water Sci Techno 75:2489–2498
Ma Y-X, Kou Y-L, Xing D et al (2017) Synthesis of magnetic graphene oxide grafted polymaleicamide dendrimer nanohybrids for adsorption of Pb(II) in aqueous solution. J Hazard Mater 340:407–416. https://doi.org/10.1016/j.jhazmat.2017.07.026
Machida M, Yamazaki R, Aikawa M et al (2005) Role of minerals in carbonaceous adsorbents for removal of Pb(II) ions from aqueous solution. Sep Purif Technol 46:88–94
Martinez-Juarez RVM, Cardenas-Gonzalez JF, Moctezuma-Zarate MG (2013) Biosorption of arsenic(III) from aqueous solutions by modified fungal biomass of Paecilomyces sp. Bioinorg Chem. https://doi.org/10.1155/2013/376780
Mohan D, Kumar H, Sarswat A et al (2014) Cadmium and lead remediation using magnetic oak wood and oak bark fast pyrolysis bio-chars. Chem Eng J 236:513–528. https://doi.org/10.1016/j.cej.2013.09.057
Mondal MK, Garg R (2017) A comprehensive review on removal of arsenic using activated carbon prepared from easily available waste materials. Environ Sci Pollut Res 24:13295–13306
Mureseanu M, Reiss A, Cioatera N et al (2010) Mesoporous silica functionalized with 1-furoyl thiourea urea for Hg(II) adsorption from aqueous media. J Hazard Mater 182:197–203
Naushad M, ALOthman ZA, Khan MR et al (2014) Equilibrium, kinetics and thermodynamic studies for the removal of organophosphorus pesticide using Amberlyst-15 resin: quantitative analysis by liquid chromatography-mass spectrometry. J Ind Eng Chem 20:4393–4400. https://doi.org/10.1016/j.jiec.2014.02.006
Naushad M, Ahamad T, Al-Maswari BM et al (2017) Nickel ferrite bearing nitrogen-doped mesoporous carbon as efficient adsorbent for the removal of highly toxic metal ion from aqueous medium. Chem Eng J 330:1351–1360. https://doi.org/10.1016/j.cej.2017.08.079
Nava OJ, Luque PA, Gomez-Gutierrez CM et al (2017a) Influence of Camellia sinensis extract on Zinc Oxide nanoparticle green synthesis. J Mol Struct 1134:121–125
Nava OJ, Soto-Robles CA, Gomez-Gutierrez CM et al (2017b) Fruit peel extract mediated green synthesis of zinc oxide nanoparticles. J Mol Struct 1147:1–6
Nayak AK, Pal A (2017) Green and efficient biosorptive removal of methylene blue by Abelmoschus esculentus seed: process optimization and multi-variate modeling. J Environ Manage 200:145–159. https://doi.org/10.1016/j.jenvman.2017.05.045
Ocsoy I, Temiz M, Celik C et al (2017) Green approach for formation of silver nanoparticles on magnetic graphene oxide and highly effective antimicrobial activity and reusability. J Mol Liq 227:147–152
Okman I, Karagöz S, Tay T et al (2014) Activated carbons from grape seeds by chemical activation with potassium carbonate and potassium hydroxide. Appl Surf Sci 293:138–142. https://doi.org/10.1016/j.apsusc.2013.12.117
Oliveira WE, Franca AS, Oliveira LS, Rocha SD (2008) Untreated coffee husks as biosorbents for the removal of heavy metals from aqueous solutions. J Hazard Mater 152:1073–1081
Papa S, Šolević T, Jelena K et al (2017) Utilization of fruit processing industry waste as green activated carbon for the treatment of heavy metals and chlorophenols contaminated water. J Clean Prod 162:958–972
Parson S, Jefferson B (2006) Introduction to potable water treatment processes. Blackwell Publishing Ltd, UK
Peng W, Li H, Liu Y, Song S (2017) A review on heavy metal ions adsorption from water by graphene oxide and its composites. J Mol Liq 230:496–504
Postai DL, Demarchi CA, Zanatta F (2016) Adsorption of Rhodamine B and methylene blue dyes using waste of seeds of Aleurites moluccana, a low cost adsorbent. Alex Eng J 55(2):1713–1723. https://doi.org/10.1016/j.aej.2016.03.017
Quintanilla DP, Hierro I, Fajardo M et al (2006) 2-Mercaptothiazoline modified mesoporous silica for mercury removal from aqueous media. J Hazard Mater 134:245–256
Raj KR, Kardam A, Srivastava S (2013) PEI modified Leucaena leucocephala seed powder, a potential biosorbent for the decontamination of arsenic species from water bodies: bioremediation. Appl Water Sci 3:327–333
Reck IM, Paixão RM, Bergamasco R et al (2018) Removal of tartrazine from aqueous solutions using adsorbents based on activated carbon and Moringa oleifera seeds. J Clean Prod 171:85–97. https://doi.org/10.1016/j.jclepro.2017.09.237
Reddy DHK, Yun Y-S (2016) Spinel ferrite magnetic adsorbents: alternative future materials for water purification? Coord Chem Rev 315:90–111. https://doi.org/10.1016/j.ccr.2016.01.012
Ricordel S, Taha S, Cisse I et al (2001) Heavy metals removal by adsorption onto peanut husks carbon: characterization, kinetic study and modeling. Sep Purif Technol 24:389–401
Roy E, Patra S, Madhuri R et al (2016) Europium doped magnetic graphene oxide-MWCNT nanohybrid for estimation and removal of arsenate and arsenite from real water samples. Chem Eng J 299:244–254. https://doi.org/10.1016/j.cej.2016.04.051
Sahu RC, Patel R, Ray BC (2011) Adsorption of Zn(II) on activated red mud: neutralized by CO2. Desalination 266:93–97
Salem NM, Awwad AM, Al-Dujahi AH (2012) Biosorption of Pb(II), Zn(II) and Cd(II) by Eriobotrya japonica Loquat bark. Int J Environ Prot 2:1–7
Santhosh C, Daneshvar E, Kollu P et al (2017) Magnetic SiO2@CoFe2O4 nanoparticles decorated on graphene oxide as efficient adsorbents for the removal of anionic pollutants from water. Chem Eng J 322:472–487. https://doi.org/10.1016/j.cej.2017.03.144
Sartape AS, Mandhare AM, Jadhav VV (2017) Removal of malachite green dye from aqueous solution with adsorption technique using Limonia acidissima (wood apple) shell as low cost adsorbent. Arab J Chem 10:S3229–S3238. https://doi.org/10.1016/j.arabjc.2013.12.019
Seki K, Saito N, Aoyama M (1997) Removal of heavy metal ions from solutions by coniferous barks. Wood Sci Technol 31:441–447
Senapati K, Alam I (2001) Apyron arsenic treatment unit—reliable technology for arsenic safe water. In: Feroze Ahmed M et al (eds) Technologies for arsenic removal from drinking water. A compilation of papers presented at the international workshop on technologies for arsenic removal from drinking water. Bangladesh University of Engineering and Technology, Dhaka, Bangladesh and the United Nations University, Tokyo, May 2001
Shahat A, Awual MR, Khaleque MA et al (2015) Large-pore diameter nano-adsorbent and its application for rapid lead(II) detection and removal from aqueous media. Chem Eng J 273:286–295
Shanker U, Jassal V, Rani M (2017) Green synthesis of iron hexacyanoferrate nanoparticles: potential candidate for the degradation of toxic PAHs. J Environ Chem Eng 5:4108–4120
Sharma VK, Dutta PK, Ray AK (2007) Review of kinetics of chemical and arsenic(III) as influenced by pH. Environ Sci Health 42:997
Sharma JK, Srivastavaa P, Ameen S et al (2017) Phytoconstituents assisted green synthesis of cerium oxide nanoparticles for thermal decomposition and dye remediation. Mat Res Bull 91:98–107
Shehzad K, Xie C, He J et al (2018) Facile synthesis of novel calcined magnetic orange peel composites for efficient removal of arsenite through simultaneous oxidation and adsorption. J Colloid Int Sci 511:155–164. https://doi.org/10.1016/j.jcis.2017.09.110
Shen K, Gondal MA (2017) Removal of hazardous Rhodamine dye from water by adsorption onto exhausted coffee ground. J Saudi Chem Soc 21(1):S120–S127. https://doi.org/10.1016/j.jscs.2013.11.005
Shen B, Tian L, Li F et al (2017) Elemental mercury removal by the modified bio-char from waste tea. Fuel 187:189–196. https://doi.org/10.1016/j.fuel.2016.09.059
Singh KK, Singh AK, Hasan SH (2006) Low cost bio-sorbent ‘wheat bran’ for the removal of cadmium from wastewater: kinetic and equilibrium studies. Bioresour Technol 97:994–1001
Singh C, Sahu J, Mahalik K et al (2008) Studies on the removal of Pb(II) from wastewater by activated carbon developed from Tamarind wood activated with sulphuric acid. J Hazard Mater 153:221–228
Smily JRMB, Sumithra PA (2017) Optimization of chromium biosorption by fungal adsorbent, Trichoderma sp. BSCR02 and its desorption studies. HAYATI J Biosci. https://doi.org/10.1016/j.hjb.2017.08.005
Son E-B, Poo K-M, Chang J-S et al (2018) Heavy metal removal from aqueous solutions using engineered magnetic biochars derived from waste marine macro-algal biomass. Sci Total Environ 615:161–168. https://doi.org/10.1016/j.scitotenv.2017.09.171
Sreekanth TVM, Jung M, Eom I (2016) Green synthesis of silver nanoparticles, decorated on graphene oxide nanosheets and their catalytic activity. Appl Surf Sci 361:102–106
Stevens MGF, Batlokwa BS (2017) Environmentally friendly and cheap removal of lead (II) and zinc (II) from wastewater with fish scales waste remains. Int J Chem 9(4). https://doi.org/10.5539/ijc.v9n4p22
Su C, Puls RW (2001) Arsenate and arsenite removal by zerovalent iron: kinetics, redox transformation, and implications for in situ groundwater remediation. Environ Sci Technol 35:1487–1492
Subramaniam R, Ponnusamy SK (2015) Novel adsorbent from agricultural waste (cashew NUT shell) for methylene blue dye removal: optimization by response surface methodology. Water Res Ind 11:64–70. https://doi.org/10.1016/j.wri.2015.07.002
Sulak MT, Demirbas E, Kobya M (2007) Removal of Astrazon Yellow 7GL from aqueous solutions by adsorption onto wheat bran. Bioresour Technol 98:2590–2598
Tatarchuk T, Bououdina M, Macyk W et al (2017a) Structural, optical, and magnetic properties of Zn-doped CoFe2O4 nanoparticles. Nanoscale Res Lett 12(1):141–151. https://doi.org/10.1186/s11671-017-1899-x
Tatarchuk T, Bououdina M, Paliychuk N et al (2017b) Structural characterization and antistructure modeling of cobalt-substituted zinc ferrites. J Alloys Compd 694:777–791. https://doi.org/10.1016/j.jallcom.2016.10.067
Tatarchuk T, Bououdina M, Vijaya JJ et al (2017c) Spinel ferrite nanoparticles: synthesis, crystal structure, properties, and perspective applications. In: Fesenko O, Yatsenko L (eds) Nanophysics, nanomaterials, interface studies, and applications. NANO 2016. In: Springer proceedings in physics, vol 195. Springer, pp 305–325. https://doi.org/10.1007/978-3-319-56422-7_22
Tatarchuk TR, Paliychuk ND, Bououdina M et al (2017d) Effect of cobalt substitution on structural, elastic, magnetic and optical properties of zinc ferrite nanoparticles. J Alloys Compd. https://doi.org/10.1016/j.jallcom.2017.10.103
Taty-Costodes VC, Fauduet H, Porte C et al (2003) Removal of Cd(II) and Pb(II) ions from aqueous solutions by adsorption onto sawdust of Pinus sylvestris. J Hazard Mater B 105:121–142
Thitame PV, Shukla SR (2017) Removal of lead (II) from synthetic solution and industry wastewater using almond shell activated carbon. Environ Prog Sustain Energy. https://doi.org/10.1002/ep.12616
Tinas H, Caliskan E, Ozbek N et al (2016) Preparation of Fe3O4@montmorillonite composite as an effective sorbent for the removal of lead and cadmium from wastewater samples. Turk J Chem 40:974–978
Tofan L, Paduraru C, Robu B et al (2012) Removal of Cd(II) ions from aqueous solution by retention on pine bark. Environ Eng Manage J 11:199–205
Tofighy MA, Mohammadi T (2012) Chem Eng Res Des 90:1815–1822
Tokunaga S, Wasay SA, Park SW (1997) Removal of arsenic (V) ion from aqueous solutions by Lanthanum compounds. Water Sci Technol 35(7):71–78
Tran HT, Vu ND, Matsukawa M et al (2016) Heavy metal biosorption from aqueous solutions by algae inhabiting rice paddies in Vietnam. J Environ Chem Eng 4(2):2529–2535. https://doi.org/10.1016/j.jece.2016.04.038
Upadhyay RK, Soin N, Bhattacharya G, Saha S, Barman A, Roy SS (2015) Grape extract assisted green synthesis of reduced graphene oxide for water treatment application. Mater Lett 160:355–358
Vaibhav V, Vijayalakshmi U, Mohana S, Amiri M, Salavati-Niasari M, Akbari A, Gholami T (2015) Agricultural waste as a source for the production of silica nanoparticles. Spectrochim Acta Part A Mol Biomol Spectrosc 139:515–520
Vasudevan S, Lakshmi J, Sozhan G (2012) Optimization of electrocoagulation process for the simultaneous removal of mercury, lead, and nickel from contaminated water. Environ Sci Pollut Res 19(7):2734–2744
Vendamanib VS, Tripathia A, Singh MK, Pathak AP, Tiwaria A, Chettri P (2017) Green synthesis of silver nanoparticle-reduced graphene oxide using Psidium guajava and its application in SERS for the detection of methylene blue. Appl Surf Sci 406:312–318
Verma SP, Sarkar B (2017) Rhamnolipid based micellar-enhanced ultrafiltration for simultaneous removal of Cd(II) and phenolic compound from wastewater. Chem Eng J 319:131–142
Verma A, Kumar S, Kumar S (2016) Biosorption of lead ions from the aqueous solution by Sargassum filipendula: equilibrium and kinetic studies. J Environ Chem Eng 4(4):4587–4599. https://doi.org/10.1016/j.jece.2016.10.026
Vidya C, Chandra Prabhab MN, Antony Raj MAL (2016) Green mediated synthesis of zinc oxide nanoparticles for the photocatalytic degradation of Rose Bengal dye. Environ Nanotechnol, Monit Manage 6:134–138
Vinh NV, Zafar M, Behera SK et al (2015) Arsenic(III) removal from aqueous solution by raw and zinc loaded pine cone biochar: equilibrium, kinetics, and thermodynamics studies. Int J Environ Sci Technol 12:1283–1294
Wahi R, Ngaini Z (2009) Removal of mercury, lead and copper from aqueous solution by activated carbon of palm oil empty fruit bunch. World Appl Sci J 5:84–91
Wang L, Zhang F-S (2017) Characterization of a novel sound absorption material derived from waste agricultural film. Constr Build Mater 157:237–243. https://doi.org/10.1016/j.conbuildmat.2017.07.192
Wang H, Lin SH, Juang RS (2003) Removal of heavy metals from aqueous solutions using various low-cost adsorbents. J Hazard Mater 102:291–302
Wang L, Zhu L, Bing N, Wang L (2017a) Facile green synthesis of Pd/N-doped carbon nanotubes catalysts and their application in Heck reaction and oxidation of benzyl alcohol. J Phys Chem Solids 107:125–130
Wang W, Cai K, Wu X et al (2017b) A novel poly(m-phenylenediamine)/reduced graphene oxide/nickel ferrite magnetic adsorbent with excellent removal ability of dyes and Cr(VI). J Alloys Compd 722:532–543. https://doi.org/10.1016/j.jallcom.2017.06.069
Wen H-F, Yang C, Yu D-G et al (2016) Electrospun zein nanoribbons for treatment of lead-contained wastewater. Chem Eng J 290:263–272
WHO/UNICEF (2000) Global water supply and sanitation assessment report 2000, WHO, Geneva, Switzerland
Xia Z, Baird L, Zimmerman N, Yeager M (2017) Heavy metal ion removal by thiol functionalized aluminum oxide hydroxide nanowhiskers. Appl Surf Sci 416:565–573
Xu D, Tan X, Chen C et al (2008) Removal of Pb(II) from aqueous solution by oxidized multiwalled carbon nanotube. J Hazard Mater 154:407–416
Yadav AK, Kaushik CP, Haritash AK et al (2006) Defluoridation of groundwater using brick powder as an adsorben. J Hazard Mater 128:289–293
Yang F, Sun L, Xie W et al (2017) Nitrogen-functionalization biochars derived from wheat straws via molten salt synthesis: an efficient adsorbent for atrazine removal. Sci Total Environ 607–608:1391–1399. https://doi.org/10.1016/j.scitotenv.2017.07.020
Yang Q, Ren SS, Zhao Q et al (2018) Selective separation of methyl orange from water using magnetic ZIF-67 composites. Chem Eng J 333:49–57. https://doi.org/10.1016/j.cej.2017.09.099
Yap MW, Mubarak NM, Sahu JN et al (2017) Microwave induced synthesis of magnetic biochar from agricultural biomass for removal of lead and cadmium from wastewater. J Ind Eng Chem 45:287–295
Zare-Dorabei R, Ferdowsi SM, Barzin A et al (2016) Highly efficient simultaneous ultrasonic-assisted adsorption of Pb(II), Cd(II), Ni(II) and Cu (II) ions from aqueous solutions by graphene oxide modified with 2,20-dipyridylamine: central composite design optimization. Ultrason Sonochem 32:265–276
Zhang J, Ding T, Zhang Z et al (2015) Enhanced adsorption of trivalent arsenic from water by functionalized diatom silica shells. PLoS ONE 10(4):e0123395. https://doi.org/10.1371/journal.pone.0123395A
Zhang Y, Cao B, Zhao L et al (2018) Biochar-supported reduced graphene oxide composite for adsorption and coadsorption of atrazine and lead ions. Appl Surf Sci 427(A):147–155. https://doi.org/10.1016/j.apsusc.2017.07.237
Zhou Q, Liao B, Lin L et al (2018) Adsorption of Cu(II) and Cd(II) from aqueous solutions by ferromanganese binary oxide–biochar composites. Sci Total Environ 615:115–122. https://doi.org/10.1016/j.scitotenv.2017.09.220
Zhu Y, Hu J, Wang J (2012) Competitive adsorption of Pb(II), Cu(II) and Zn(II) onto xanthate modified magnetic chitosan. J Hazard Mater 221:155–161
Zolgharnein J, Shahmoradi A, Bagtash M et al (2017) Chemometrics optimization for simultaneous adsorptive removal of ternary mixture of Cu(II), Cd(II), and Pb(II) by Fraxinus tree leaves. J Chemom. https://doi.org/10.1002/cem.2935
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2019 Springer International Publishing AG, part of Springer Nature
About this chapter
Cite this chapter
Tatarchuk, T., Bououdina, M., Al-Najar, B., Bitra, R.B. (2019). Green and Ecofriendly Materials for the Remediation of Inorganic and Organic Pollutants in Water. In: Naushad, M. (eds) A New Generation Material Graphene: Applications in Water Technology. Springer, Cham. https://doi.org/10.1007/978-3-319-75484-0_4
Download citation
DOI: https://doi.org/10.1007/978-3-319-75484-0_4
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-75483-3
Online ISBN: 978-3-319-75484-0
eBook Packages: Earth and Environmental ScienceEarth and Environmental Science (R0)