Abstract
In 1911 H. Kamerlingh Onnes measured the electrical resistivity of mercury and found that it dropped to zero below 4.15 K. He could do this experiment because he was the first to liquefy helium and thus he could work with the low temperatures required for superconductivity. It took 46 years before Bardeen, Cooper, and Schrieffer (BCS) presented a theory that correctly accounted for a large number of experiments on superconductors. Even today, the theory of superconductivity is rather intricate and so perhaps it is best to start with a qualitative discussion of the experimental properties of superconductors.
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Notes
- 1.
See Kuper [8.20 p. 221].
- 2.
See Saint-James et al. [8.27 p. 141].
- 3.
Note this is actually an oversimplified semiconductor-like picture of a complicated many-body effect [8.14 p. 247], but the picture works well for certain aspects and certainly is the simplest way to get a feel for the experiment.
- 4.
For the superconducting density of states see Problem 8.2.
- 5.
See, e.g., Feynman et al. [8.13], and Josephson [8.18], this was Josephson’s Nobel Prize address. See also Dalven [8.11] and Kittel [23 Chap. 12].
- 6.
See [8.24].
- 7.
See Cooper [8.10].
- 8.
Fermion Pairing: Shafroth [8.29] seems to be the first to connect superconductivity with a Bose–Einstein condensation of fermion pairs. It is now understood that the ideas of Shafroth were incomplete and not really the way to view things. As we have mentioned, superconductivity in metals was discovered early on (1911). Superfluidity in 4He was discovered somewhat later (1938) by Kapitsa and also Allen and Misener. It was speculated fairly soon that the explanations for each must have some connection, but the relation was certainly not clear. In particular, F. London argued that superfluidity must have a connection with Bose–Einstein condensation (BEC). Because of these and related ideas, one sometimes calls superconductivity charged superfluidity. See C. A. R. Sa de Melo, “When fermions become bosons: pairing in ultra-cold gas,” Physics Today, Oct. 2008, pp. 45–51 for details and references. See also the Chap. 12 section entitled “Bose–Einstein Condensation.”
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Problems
Problems
-
8.1
Show that the flux in a superconducting ring is quantized in units of h/q, where q = |2e|.
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8.2
Derive an expression for the single-particle tunneling current between two superconductors separated by an insulator at absolute zero. If ET is measured from the Fermi energy, you can calculate a density of states as below.
Note:
where D(0) is the number of states per unit energy without pairing.
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Bailey, B.C., Bailey, B.C. (2018). Superconductivity. In: Solid-State Physics. Springer, Cham. https://doi.org/10.1007/978-3-319-75322-5_8
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