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ZnO Thin Films of Flowered-Fibrous Micro/Nanowebs on Glass Substrates Using the Spray Pyrolysis Method

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Characterization of Minerals, Metals, and Materials 2018 (TMS 2018)

Part of the book series: The Minerals, Metals & Materials Series ((MMMS))

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Abstract

Zinc oxide (ZnO ) flowered-fibrous micro/nanowebs were produced as thin films on glass substrates at 350 ℃ using the low cost spray pyrolysis (SP) method. The films were characterized using the XRD diffraction, scanning electron microscopy (SEM ), and X-ray energy dispersive spectroscopy (EDS). Hexagonal structure was confirmed from X-ray diffractogram, which showed preferential orientation along the (002) line. SEM images showed two dimensional flowered-fibrous micro/nanowebs, and EDS elemental analysis revealed the presence of chlorine in the films in addition to zinc and oxygen. The obtained morphology is important for optoelectronic device industry and solar cells , where it provides large surface area that helps light harvesting.

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References

  1. Cho S et al (2010) Formation of amorphous zinc citrate spheres and their conversion to crystalline ZnO nanostructures. Langmuir 27:371–378

    Article  Google Scholar 

  2. Wu J, Xue D (2011) Progress of science and technology of ZnO as advanced material. Sci Adv Mater 3:127–149

    Article  Google Scholar 

  3. Kim J, Yong K (2011) Mechanism study of ZnO nanorod-bundle sensors for H2S gas sensing. J Phys Chem C 115:7218–7224

    Article  Google Scholar 

  4. Li H et al (2011) Fabrication of ordered flower-like ZnO nanostructures by a microwave and ultrasonic combined technique and their enhanced photocatalytic activity. Mater Lett 65:3440–3443

    Article  Google Scholar 

  5. Lai Y, Meng M, Yu Y (2010) One-step synthesis, characterizations and mechanistic study of nanosheets-constructed fluffy ZnO and Ag/ZnO spheres used for rhodamine B photodegradation. Appl Catal B: Environ 100(3–4):491–501

    Article  Google Scholar 

  6. Milao TM, de Mendonca VR, Araujo VD, Avansi W, Ribeiro C, Longo E, Bernardi MI (2012) Microwave hydrothermal synthesis and photocatalytic performance of ZnO and M:ZnO nanostructures (M = V, Fe, Co). Sci Adv Mater 4:54–60

    Article  Google Scholar 

  7. Roselin LS, Selvin R (2011) Photocatalytic degradation of reactive orange 16 dye in a ZnO coated thin film flow photoreactor. Sci Adv Mater 3:251–258

    Article  Google Scholar 

  8. Liao Y, Xie C, Liu Y, Huang Q (2013) Enhancement of photocatalytic property of ZnO for gaseous formaldehyde degradation by modifying morphology and crystal defect. J Alloys Comp 550:190–197

    Article  Google Scholar 

  9. Ko SH, Lee D, Kang HW, Nam KH, Yeo JY, Hong SJ, Grigoropoulos CP, Sung HJ (2011) Nanoforest of hydrothermally grown hierarchical ZnO nanowires for a high efficiency dye-sensitized solar cell. Nano Lett 11(2):666–671

    Article  Google Scholar 

  10. Ling T, Song JG, Chen XY, Yang J, Qiao SZ, Du XW (2013) Comparison of ZnO and TiO2 nanowires for photoanode of dye-sensitized solar cells. J Alloys Comp 546:307–313

    Article  Google Scholar 

  11. Kao M-C, Chen H-Z, Young S-L, Lin C-C, Kung C-Y (2012) Structure and photovoltaic properties of ZnO nanowire for dye-sensitized solar cells. Nanoscale Res Lett 7:260

    Google Scholar 

  12. Huang MH, Mao S, Feick H, Yan HQ, Wu YY, Kind H, Weber E, Russo R, Yang PD (2001) Room-temperature ultraviolet nanowire nanolasers. Science 292(8):1897–1899

    Article  Google Scholar 

  13. Xiang B, Wang PW, Zhang XZ, Dayeh SA, Aplin DPR, Soci C, Yu DP, Wang DL (2007) Rational synthesis of p-type zinc oxide nanowire arrays using simple chemical vapor deposition. Nano Lett 7(2):323–328

    Article  Google Scholar 

  14. Sun Y, Fuge GM, Ashfold MNR (2004) Growth of aligned ZnO nanorod arrays by catalyst-free pulsed laser deposition methods. Chem Phys Lett 396(1–3):21–26

    Article  Google Scholar 

  15. Kluth O, Schöpe G, Hüpkes J, Agashe C, Müller J, Rech B (2003) Modified Thornton model for magnetron sputtered zinc oxide: film structure and etching behavior. Thin Solid Films 442:80–85

    Article  Google Scholar 

  16. Ohyama M, Kozuka H, Yoko T (1998) Sol-gel preparation of transparent and conductive aluminum-doped zinc oxide films with highly preferential crystal orientation. J Am Ceram Soc 81:1622–1632

    Article  Google Scholar 

  17. Ekthammathat N, Phuruangrat A, Thongtem S, Thongtem T (2015) Hydrothermal-assisted synthesis and photoluminescence of ZnO microrods. Dig J Nanomater Biostruct 10(1):149–153

    Google Scholar 

  18. Ikhmayies Shadia (2016) Synthesis of ZnO microrods by the spray pyrolysis technique. J Electron Mater 45(8):3964–3969

    Article  Google Scholar 

  19. Ikhmayies SJ, Abu El-Haija NM, Ahmad-Bitar RN (2014) A comparison between different ohmic contacts for ZnO thin films. J Semicond 36(3):033005-1-6

    Google Scholar 

  20. Ikhmayies SJ, Abu El-Haija NM, Ahmad-Bitar RN (2010) Electrical and optical properties of ZnO:Al thin film prepared by the spray pyrolysis technique. Phys Scr 81(1):015703

    Google Scholar 

  21. Ikhmayies SJ, Abu El-Haija NM, Ahmad-Bitar RN (2010) Characterization of undoped spray-deposited ZnO thin films of photovoltaic applications. FDMP: Fluid Dyn Mater Proces 6(2):165–178

    Google Scholar 

  22. Ikhmayies SJ, Abu El-Haija NM, Ahmad-Bitar RN (2010) The Influence of annealing in nitrogen atmosphere on the electrical, optical and structural properties of spray- deposited ZnO thin films. FDMP: Fluid Dyn Mater Proces 6(2):219–232

    Google Scholar 

  23. Ikhmayies SJ, Zbib MB (2017) Spray pyrolysis synthesis of ZnO micro/nanorods on glass substrate. J Electron Mater 46(10):5629–5634

    Article  Google Scholar 

  24. Ikhmayies SJ (2017) Formation of three dimensional ZnO micro flowers from self assembled ZnO micro discs. Metall Mater Trans 48(8):3625–3629

    Article  Google Scholar 

  25. Ikhmayies SJ, Zbib MB (2017) Synthesis of ZnO hexagonal micro discs on glass substrates using the spray pyrolysis technique. J Electron Mater 46(7):3982–3986

    Article  Google Scholar 

  26. Juwhari HK, Ikhmayies SJ, Lahlouh B (2017) Room temperature photoluminescence of spray-deposited ZnO thin films on glass substrates. Int J Hydrog Energy 42:17741–17747

    Article  Google Scholar 

  27. Ikhmayies SJ (2017) Synthesis of ZnO micro prisms on glass substrates by the spray pyrolysis method. In: Characterization of minerals, metals, and materials 2017, part of the the minerals, metals & materials series book series (MMMS), pp 131–138

    Google Scholar 

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Correspondence to Shadia J. Ikhmayies .

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Ikhmayies, S.J. (2018). ZnO Thin Films of Flowered-Fibrous Micro/Nanowebs on Glass Substrates Using the Spray Pyrolysis Method. In: Li, B., et al. Characterization of Minerals, Metals, and Materials 2018 . TMS 2018. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-319-72484-3_23

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