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Recovery of Nickel and Cobalt from a Waste Zone of Nickel Laterite Ore Using a Mixture of Extractants in Solvent Extraction Technique

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Energy Technology 2018 (TMS 2018)

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Abstract

The surface zone of nickel laterite ore is generally considered as residue. However, because of the depletion of ore sources and the increase in demand, this previously discarded zone may now be processed economically for nickel and cobalt. After leaching and removal of the impurities, the solution contains cobalt, magnesium, manganese and nickel. Solvent extraction is a hydrometallurgical technique used in the separation of metals from aqueous solutions. Cyanex 272 and D2EHPA are extractants used to separate nickel from cobalt. The mixture of extractants can change the performance during the metals extraction. This work aims to evaluate the solvent extraction of nickel and cobalt when Cyanex 272 and D2EHPA are mixed. The results showed that the increased concentration of D2EHPA in the organic phase increased the extraction of nickel and magnesium. However, cobalt extraction was reduced and the manganese extraction was not altered.

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References

  1. U.S.Geological Survey (2016) Nickel. In: U.S.Geological Survey. Mineral Commodity Summaries 2017, Virginia, pp 114–115. doi:10.3133/70180197

    Google Scholar 

  2. Crundwell FK, Moats MS, Ramachandran V, Robinson TG, Davenport WG (2011) Extractive metallurgy of nickel, cobalt and platinum group metals. Elsevier, Oxford

    Google Scholar 

  3. Elias M (2002) Nickel laterite deposits—geological overview, resources and exploitation. In: Cooke DR, Pongratz J (ed) Giant ore deposits: characteristics, genesis and exploration; University of Tasmania, Tasmania, pp 205–220

    Google Scholar 

  4. Kyle J (2010) Nickel laterite processing technologies—where to next? Paper presented at ALTA 2010 Nickel/Cobalt/Copper Conference, Perth, Western Australia, 24–27 May 2010

    Google Scholar 

  5. Liu H, Reynolds GA (2012) Process for atmospheric leaching of laterite ores using hypersaline leach solution. US. Patent 8,268,039 B2. 18 September 2012

    Google Scholar 

  6. Neudorf D (2006) Method for nickel and cobalt recovery from laterite ores by reaction with concentrated acid and water leaching. US. Patent 11/166,125. 5 January 2006

    Google Scholar 

  7. Georgiou D, Papangelakis VG (1998) Sulphuric acid pressure leaching of a limonitic laterite: chemistry and kinetics. Hydrometallurgy 49(1–2):23–46

    Article  CAS  Google Scholar 

  8. Gupta CK (2003) Chemical metallurgy principles and practice. Wiley-VCH, Weinheim

    Google Scholar 

  9. Kesler SE, Simon AC (2015) Mineral resources, economics and the environment. Cambridge University Press, Cambridge

    Google Scholar 

  10. Moskalyk RR, Alfantazi AM (2002) Nickel laterite processing and electrowinning practice. Miner Eng 15:593–605

    Article  CAS  Google Scholar 

  11. Tang JA, Valix M (2006) Leaching of low grade limonite and nontronite ores by fungi metabolic acids. Miner Eng 19(12):1274–1279

    Article  CAS  Google Scholar 

  12. Roche EG (2011) Iron Precipitation. US. Patent 12/991,985. 26 May 2011

    Google Scholar 

  13. McDonald RG, Whittington BI (2008) Atmospheric acid leaching of nickel laterites review Part I. Surphuric acid technologies. Hydrometallurgy 91(1–4):35–55

    Article  CAS  Google Scholar 

  14. Büyükakinci E, Topkaya YA (2009) Extraction of nickel from lateritic ores at atmospheric pressure with agitation leaching. Hydrometallurgy 97(1–2):33–38

    Article  Google Scholar 

  15. Dalvi AD, Bacon WG, Osborne RC (2004) The Past and the Future of Nickel Laterites. Paper presented at PDAC 2004 International Convention, Toronto, Canada, 7–10 March 2004

    Google Scholar 

  16. Flett DS (2004) Cobalt-Nickel separation in hydrometallurgy: a review. Chem Sustain Dev 12:81–91

    Google Scholar 

  17. de Morais CA, de Albuquerque RO, Ladeira ACQ (2014) Processos Físicos e Químicos Utilizados na Indústria Mineral. Cad Temáticos Química Nov na Esc 8:9–17

    Google Scholar 

  18. Vogel AI (1981) Análise química quantitativa. Editora Mestre Jou, São Paulo

    Google Scholar 

  19. Cheng CY, Urbani MD, Davies MG, Pranolo Y, Zhu Z (2015) Recovery of nickel and cobalt from leach solutions of nickel laterites using a synergistic system consisting of Versatic 10 and Acorga CLX 50. Miner Eng 77:17–24

    Article  CAS  Google Scholar 

  20. Free M (2013) Hydrometallurgy: fundamentals and applications. Wiley, New Jersey

    Book  Google Scholar 

  21. Habashi F (1970) Principles of extractive metallurgy –, vol 2. Gordon and Brach Science Publishers, New York

    Google Scholar 

  22. Kislik VS (2012) Solvent extraction: classical and novel approaches. Elsevier, Oxford

    Google Scholar 

  23. Ritcey GM, Ashbrook AW (1984) Solvent Extraction: principles and applications to process metallurgy –, vol 1. Elsevier, Oxford

    Google Scholar 

  24. Cytec (2008) CYANEX 272 Extractant. Cytec Industries Inc. http://www.cytec.com/sites/default/files/datasheets/CYANEX 272 Brochure.pdf. Accessed 21 February 2016

  25. Flett DS (2005) Solvent extraction in hydrometallurgy: the role of organophosphorus extractants. J Organomet Chem 690(10):2426–2438

    Article  CAS  Google Scholar 

  26. Zhang Y, Zhang T, Lv G, Zhang G, Liu Y, Zhang W (2016) Synergistic extraction of vanadium(IV) in sulfuric acid media using a mixture of D2EHPA and EHEHPA. Hydrometallurgy 166:87–93

    Article  CAS  Google Scholar 

  27. Bart H-J, Stevens GW (2002) Reactive Solvent Extraction. In: Marcus Y, SenGupta AK, Marinsky JA (eds) Ion exchange and solvent extraction: a series of advances. Marcel Dekker, New York, pp 37–83

    Google Scholar 

  28. Ahmadipour M, Rashchi F, Ghafarizadeh B, Mostoufi N (2011) Synergistic effect of D2EHPA and Cyanex 272 on separation of Zinc and Manganese by solvent extraction. Sep Sci Technol 46:2305–2312

    Article  CAS  Google Scholar 

  29. Darvishi D, Haghshenas DF, Keshavarz Alamdari E, Sadrnezhaad SK, Halali M (2005) Synergistic effect of Cyanex 272 and Cyanex 302 on separation of cobalt and nickel by D2EHPA. Hydrometallurgy 77:227–238

    Article  CAS  Google Scholar 

  30. Aliprandini P (2017) O uso da extração por solventes para tratamento de licor de lixiviação de minério limonítico de níquel. Master’s thesis, University of São Paulo

    Google Scholar 

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Acknowledgements

To the Counsel of Technological and Scientific Development (CNPq), for financial support in the form of a doctorate grant.

To the Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) for financial support in the form of a doctorate grant.

To the Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) for financial support through research project 2012/51871-9.

To Ana Carolina Fadel Dalsin, for her technical assistance in the execution of testwork for this project.

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Correspondence to Paula Aliprandini .

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Aliprandini, P., Jiménez Correa, M.M., Soares Tenório, J.A., Espinosa, D.C.R. (2018). Recovery of Nickel and Cobalt from a Waste Zone of Nickel Laterite Ore Using a Mixture of Extractants in Solvent Extraction Technique. In: Sun, Z., et al. Energy Technology 2018 . TMS 2018. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-319-72362-4_39

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