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Effect of the pH on the Recovery of Al3+, Co2+, Cr3+, Cu2+, Fe3+, Mg2+, Mn2+, Ni2+ and Zn2+ by Purolite S950

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Energy Technology 2018 (TMS 2018)

Part of the book series: The Minerals, Metals & Materials Series ((MMMS))

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Abstract

The generation of mining waste has been the subject of environmental, economic and social concern. Alternative and sustainable methods of recycling metals technologies are desired. The present work focuses on the application of the ion exchange technique for the extraction of metals contained in a lateritic nickel mining effluent. The Purolite S950 chelating resin was used in the present work because it has the ability to adsorb transition metals present in an acidic solution. The experiments were carried out in a batch varying the pH in the range of 0.5–2.0. 1 g of resin was placed in contact with 50 mL of solution and stirred for 120 min at a speed of 200 rpm and temperature at 25 °C. The results demonstrated that the affinity of the resin varied with pH. The adsorbed metals were only copper, manganese, magnesium and zinc. The most extracted metal was copper, corresponding to 37%, when the solution was conditioned at pH 2.0.

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References

  1. Bide T, Hetherington L, Gunn G, Minks A (2008) Nickel. British geological survey, pp 1–24

    Google Scholar 

  2. Diniz CV, Doyle FM, Ciminelli VST (2002) Effect of pH on the adsorption of selected heavy metal ions from concentrated chloride solutions by the chelating resin Dowex M-4195. Sep Sci Technol 37(14):3169–3185

    Article  CAS  Google Scholar 

  3. Jackson E (1986) Hydrometallurgical extraction and reclamation. Ellis Horwood, Chichester

    Google Scholar 

  4. Fu F, Wang Q (2011) Removal of heavy metal ions from wastewaters: a review. J Environ Manage 92(3):407–418

    Article  CAS  Google Scholar 

  5. Bessbousse H, Rhlalou T, Verchère JF, Lebrun L (2008) Removal of heavy metal ions from aqueous solutions by filtration with a novel complexing membrane containing poly(ethyleneimine) in a poly(vinyl alcohol) matrix. J Membr Sci 307(2):249–259

    Article  CAS  Google Scholar 

  6. Cheng C, Boddy G, Zhang W, Godfrey M, Barnard K, Robinson D, Pranolo Y, Zhu Z, Zeng L, Wang W, Turner N, Shiers D, Hill T (2010) Separation of nickel and cobalt from manganese, magnesium and calcium by synergistic solvent extraction–from batch tests to pilot plant operation. In: XXV international mineral processing congress, pp 285–297

    Google Scholar 

  7. Chaudhari LB, Murthy ZVP (2010) Separation of Cd and Ni from multicomponent aqueous solutions by nanofiltration and characterization of membrane using IT model. J Hazard Mater 180(1–3):309–315

    Article  CAS  Google Scholar 

  8. Guimarães AS, Da Silva PS, Mansur MB (2014) Purification of nickel from multicomponent aqueous sulfuric solutions by synergistic solvent extraction using Cyanex 272 and Versatic 10. Hydrometallurgy 150:173–177

    Article  Google Scholar 

  9. Zainol Z, Nicol MJ (2009) Comparative study of chelating ion exchange resins for the recovery of nickel and cobalt from laterite leach tailings. Hydrometallurgy 96(4):283–287

    Article  CAS  Google Scholar 

  10. Shaaban AF, Fadel DA, Mahmoud AA, Elkomy MA, Elbahy SM (2014) Synthesis of a new chelating resin bearing amidoxime group for adsorption of Cu(II), Ni(II) and Pb(II) by batch and fixed-bed column methods. J Environ Chem Eng 2(1):632–641

    Article  CAS  Google Scholar 

  11. Kumar R, Kumar M, Ahmad R, Barakat MA (2013) L-Methionine modified Dowex-50 ion-exchanger of reduced size for the separation and removal of Cu(II) and Ni(II) from aqueous solution. Chem Eng J 218:32–38

    Article  CAS  Google Scholar 

  12. Deepatana A, Tang JA, Valix M (2006) Comparative study of chelating ion exchange resins for metal recovery from bioleaching of nickel laterite ores. Miner Eng 19(12):1280–1289

    Article  CAS  Google Scholar 

  13. Deepatana A, Valix M (2006) Recovery of nickel and cobalt from organic acid complexes: adsorption mechanisms of metal-organic complexes onto aminophosphonate chelating resin. J Hazard Mater 137(2):925–933

    Article  CAS  Google Scholar 

  14. Kiefer R, Kalinitchev AI, Höll WH (2007) Column performance of ion exchange resins with aminophosphonate functional groups for elimination of heavy metals. React Funct Polym 67:1421–1432

    Article  CAS  Google Scholar 

  15. Gupta CK (2003) Chemical metallurgy principles and practice. Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

    Google Scholar 

  16. Wang XS, Huang J, Hu HQ, Wang J, Qin Y (2007) Determination of kinetic and equilibrium parameters of the batch adsorption of Ni(II) from aqueous solutions by Na-mordenite. J Hazard Mater 142(1–2):468–476

    Article  CAS  Google Scholar 

  17. Bhatt RR, Shah BA (2015) Sorption studies of heavy metal ions by salicylic acid-formaldehyde-catechol terpolymeric resin: Isotherm, kinetic and thermodynamics. Arab J Chem 8(3):414–426

    Article  CAS  Google Scholar 

  18. Liebenberg CJ, Dorfling C, Bradshaw SM, Akdogan GA, Eksteen JJ (2013) The recovery of copper from a pregnant sulphuric acid bioleach solution with developmental resin Dow XUS43605. J South Afr Inst Min Metall 113(5):389–397

    CAS  Google Scholar 

  19. Shaaban AF, Fadel DA, Mahmoud AA, Elkomy MA, Elbahy SM (2013) Removal of Pb(II), Cd(II), Mn(II), and Zn(II) using iminodiacetate chelating resin by batch and fixed-bed column methods. Desalin Water Treat 51(28–30):5526–5536

    Article  CAS  Google Scholar 

  20. Hamabe Y, Hirashima Y, Izumi J, Yamabe K, Jyo A (2009) Properties of a bifunctional chelating resin containing aminomethylphosphonate and sulfonate derived from poly(ώ-bromobutylstyrene-co-divinylbenzene) beads. React Funct Polym 69(11):828–835

    Article  CAS  Google Scholar 

  21. Dabrowski A, Hubicki Z, Podkoscielny P, Robens E (2004) Selective removal of the heavy metal ions from waters and industrial wastewaters by ion-exchange method. Chemosphere 56(2):91–106

    Article  CAS  Google Scholar 

  22. Wołowicz A, Hubicki Z (2012) The use of the chelating resin of a new generation Lewatit MonoPlus TP-220 with the bis-picolylamine functional groups in the removal of selected metal ions from acidic solutions. Chem Eng J 197:493–508

    Article  Google Scholar 

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Aknowledgements

To the Counsel of Technological and Scientific Development (CNPq) for the financial support through doctorate grant.

To the Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) for the financial support through master grant.

To the Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) for financial support through the research Project 2012/51871-9.

To the Instituto Tecnológico Vale.

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Correspondence to Isadora Dias Perez .

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Perez, I.D., Correa, M.M.J., Tenório, J.A.S., Espinosa, D.C.R. (2018). Effect of the pH on the Recovery of Al3+, Co2+, Cr3+, Cu2+, Fe3+, Mg2+, Mn2+, Ni2+ and Zn2+ by Purolite S950. In: Sun, Z., et al. Energy Technology 2018 . TMS 2018. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-319-72362-4_34

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