Abstract
This chapter provides a brief overview and summary of the steps that comprise the industrial process for anodizing aluminum, the various types of, and applications for, the anodic aluminum oxide (AAO). Images of various types of AAO, grown from various electrolytes under various industrial anodizing process conditions, are presented, highlighting the structural characteristics of the AAO. The unique, highly ordered cellular structure can be tuned by adjusting the process parameters, enabling engineering adjustment of the diameter of the central pore and the cell walls. The ionic nature of the central pore offers reaction sites for bonding with other molecules, providing a surface for dyeing, coloring, and bonding. AAO structural integrity provides a barrier to the external environment and corrosion protection over a fixed pH range; the size and residual stress within the AAO structure provide abrasion and wear resistance.
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References
Runge, J., & Pomis, A. (2000, June). Anodic oxide film formation: Relating mechanism to composition and structure. In Proceedings of the AESF SUR/FIN 2000 Technical Conference, AESF.
Workbook from “Anodizing Essentials”, one-day intensive course offered by the Aluminum Anodizers Council (AAC), (2016).
Brace, A. W. (2000). The technology of anodizing aluminium (3rd ed.). Modena, Italy: Interall Srl.
Runge, J. M. (2014). Anodizing for design and function. Journal of Materials Science and Nanotechnology, 1(1), S108.
Jones, D. A. (1996). Principles and prevention of corrosion (2nd ed.). Upper Saddle River, NJ: Prentice Hall.
Zhu, H., Dahle, A. K., Zhang, X., & Couper, M. J. (2008). Effect of extrusion microstructure on formation of streaking defects on the surface of anodized aluminum extrusions. In Proceedings of the 18th Annual Anodizing Conference and Expo of the Aluminum Anodizers Council, San Francisco.
Wernick, S., Pinner, R., & Sheasby, P. G. (1987). The surface treatment and finishing of aluminum and its alloys, volume 1 (5th ed.). ASM International, Finishing Publications: Middlesex, England.
Masuda, H., & Fukuda, K. (1995). Ordered metal nanohole arrays made by two-step replications of honeycomb structures of anodic alumina. Science, 268, 9.
Apple.com website.
Han, C., & Runge, J. (2002). The future of anodizing. In Proceedings of the Annual Technical Conference and Exposition of the Aluminum Anodizers Council, Oakbrook, Illinois.
Military Specification (MIL)—A—8625F: Anodic Coatings for Aluminum and aluminum Alloys, (1993, Sept 10).
Arurault, L. (2008). Pilling-Bedworth ratio of thick anodic aluminium porous films prepared at high voltages in H 2 SO 4 based electrolyte. Leeds, UK: Maney Publishing, Institute of Metal Finishing.
Jessensky, O., Müller, F., & Gösele, U. (1998). Self-organized formation of hexagonal pore arrays in anodic alumina. Applied Physics Letters, 72(10), 1173–1175.
Thompason, G. E. (1997). Porous anodic alumina: Fabrication, characterization and applications. Thin Solid Films, 297(1–2), 192–201.
Nielsch, K., Choi, J., Schwirn, D., Wehrspohn, R., & Gösele, U. (2002). Self-ordering regimes of porous alumina: The 10% porosity rule. Nano Letters, 2(7), 677–680.
Pilling, N. B., & Bedworth, R. E. (1923). The oxidation of metals at high temperatures. Journal of the Institute of Metals, 29, 529–591.
Gabe, D. R. (2000). Density values for anodic films on aluminium and some observations of pore morphology. Transactions of the Institute of Metal Finishing, 78(6), 207–209.
Xu, C., & Gao, W. (2000). Pilling-Bedworth ratio for oxidation of alloys. Materials Research Innovations, 3, 231–235.
Runge, J. (2007). Formation of porous anodic oxide finishes: A new approach and theory. In Conference Proceedings of Aluminium 2000, Florence.
Levendusky, et al. (2010, June 8). Corrosion resistant aluminum alloy substrates and methods of producing the same (US Patent No. 7,732,068).
Runge, J., Gilbert, A., Kriesch, G., & Pernick, J. (2006). Hybrid nanostructure of the anodic oxide for polymer bonding: A case study. In Proceedings of the AAC Annual Technical Conference and Exposition, Toronto, Canada.
Poinern, G., Ali, N., & Fawcett, D. (2011). Progress in nano-engineered anodic aluminum oxide membrane development. Materials, 4, 487–526.
Le Coz, F., Aururault, L., & Datas, L. (2010). Chemical analysis of a single basic cell of porous anodic aluminum oxide templates. Materials Characterization, 61, 283–288.
Runge, J. M. (2015). Enhancing anodic aluminum oxide for bonding applications. In Proceedings of the 24th Annual AAC Conference, San Diego, California.
Ducretet, M. E. (1875). Note sur un Rhéotome Liquide a Direction Constate, Fondé sur une Propriété nouvelle de L’Aluminium. Journal de Physique Théorique, 4(1), 84–85.
Pollak, C. (1897). German Patent: “Elektrischer Flüssigkeitskondensator mit Aluminiumelektroden”, No. 92564, Granted 19 May, 1897.
Guntherschulze, A. (1906). Über das Verhalten von Aluminiumanoden. Annalen der Physik, 21, 929–954.
Sulka, G. D. (2008). Highly ordered anodic porous alumina formation by self-organized anodziing, section 1.2.1 types of anodic oxide film. In A. Eftekhari (Ed.), Nanostructured materials in electrochemistry (pp. 7–8). Weinheim: Wiley-VCH Verlag GmbH & Co. KGaA. (Ch. 1).
Burgers, W. G. Claasen, A., & Zernike, J. (1932). Über die chemische Natur der Oxydschichten, welche sich bei anodischer Polarisation auf den Metallen Aluminium, Zirkon, Titan and Tantal bilden (pp. 593–603). Eindhoven, Holland: Naturkundig Laboratorium der N.V. Philips’ Gloeilampenfabriken.
VanGeel, W. C., & Schelen, B. J. J. (1957). Some properties of oxide layers produced on aluminium by electrolytic oxidation. Philips Research Reports, 12, 240–248.
Mott, W. R. (1904). Colloidal precipitation upon aluminium anodes. Electrochemical Industry, II(11), 444–447.
Murphy, J. F., & Michelson, C. E. (1961). Proceedings of a Conference on Anodising Aluminium at the University of Nottingham, Convened by the Aluminium Development Association of London, September 12–14, 1961 (pp. 83–95).
Paschanka, M., & Schneider, J. (2011). Origin of self-organization in porous anodic alumina films derived from analogy with Rayleigh-Bénard convection cells. Journal of Materials Chemistry, 21, 18761–18767.
Thompson, G. E., & Wood, G. C. (1983). Anodic films on aluminium, section V. Barrier type anodic films. In J. C. Scully (Ed.), Corrosion: Aqueous processes and passive films, Treatise on materials science and technology (Vol. 23, pp. 230–254). London: Academic Press.
Evangelisti, F., Stiefel, M., Guseva, O., Patoveh-Nia, R., Hauert, R., Hack, E., et al. (2017). Electronic and structural characterization of barrier-type amorphous aluminium oxide. Electrochimica Acta, 224, 503–516.
Brown, S. D., Kuna, K. J., & Van, T. B. (1971). Anodic spark deposition from aqueous solution of NaAlO2 and Na2SiO3. Journal of the American Ceramic Society, 54(8), 384–390.
Runge-Marchese, J. M., & Nussbaum, T. (1998). New insights regarding the mechanism of spark anodization processes. In AESF SURFIN Proceedings (Vol. 6, pp. 531–540).
Dehnavi, V., Liu, X.-Y., Luan, B.-L., Shoesmith, D., & Rohani, S. (2014). Phase transformation in plasma electrolytic oxidation coatings on 6061 aluminum alloy. Surface & Coatings Technology, 251, 106–114.
Bengough, G., & Stuart, J. (1923, August 2). Improved process of protecting surfaces of aluminium or aluminium alloys (British Patent 223,994).
Runge, J., & Pomis, A. (2002). Continued development in chrome-free anodic oxide finishes for aluminum: Evaluation of selected mechanical properties. In Proceedings of the American Electroplaters and Surface Finishers Society Aerospace/Aircraft Forum August 27–29, 2002.
Chesterfield, L., & Runge, J. (2013). Anodizing for design and function. In Proceedings of the 22nd Annual AAC Conference, Seattle, Washington.
Stumm, W., & Furrer, G. (1989). The dissolution of oxides and aluminum silicates; examples of surface-coordination-controlled kinetics. In W. Stumm (Ed.), Aquatic surface chemistry; chemical processes at the particle-water interface. Zurich: Wiley.
Chesterfield, L., & Runge, J. (2013). Connecting theory to practice: The science of successfully anodizing aluminum die castings. In Proceedings of the 19th Annual AAC Conference, Seattle, Washington.
Runge, J. (2012). Trace elements and their impact on surface finishing characteristics of aluminum extrusions. In Proceedings of ET 2012, Miami, FL.
Vieira Coelho, A.C. (2007). Specific surface area and structures of aluminas from fibrillar pseudo-boehmite. Revista Materia, 13(2), 329–341.
Hossain T. (2013). Unpublished work.
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Runge, J.M. (2018). Anodizing as an Industrial Process. In: The Metallurgy of Anodizing Aluminum. Springer, Cham. https://doi.org/10.1007/978-3-319-72177-4_3
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DOI: https://doi.org/10.1007/978-3-319-72177-4_3
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