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Electrocatalysts for the Oxidation of Small Organic Molecules in Alkaline Media

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Anion Exchange Membrane Fuel Cells

Part of the book series: Lecture Notes in Energy ((LNEN,volume 63))

Abstract

The development of the first practical alkaline anion exchange membrane approximately 10 years ago opened up direct liquid fuel cell research to alkaline media, allowing the use of a wider variety of less noble metal catalysts due to the decreased (or eliminated) corrosion compared to acid media. While Pt-based catalysts are used in many acid fuel cells, Pd has been found to efficiently oxidize various small organic molecules in alkaline media. Much recent progress has been made in the addition of various non-noble admetals and supports in order to improve the oxidation rates of important molecules such as: formate, ethanol, propanol, ethylene glycol, propylene glycol, and glycerol. Evidence of significant contributions from the electronic effect and bifunctional effect on catalyst efficiency will be explored, and practical comparisons of each molecule will be made.

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  1. California State University, Fullerton, CA, USA

    John L. Haan, Omar Muneeb & Jose Estrada

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  1. Department of Mechanical Engineering, The Hong Kong Polytechnic University, Hong Kong SAR, China

    Liang An

  2. Department of Mechanical and Aerospace Engineering, The Hong Kong University of Science and Technology, Hong Kong SAR, China

    T.S. Zhao

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Haan, J.L., Muneeb, O., Estrada, J. (2018). Electrocatalysts for the Oxidation of Small Organic Molecules in Alkaline Media. In: An, L., Zhao, T. (eds) Anion Exchange Membrane Fuel Cells. Lecture Notes in Energy, vol 63. Springer, Cham. https://doi.org/10.1007/978-3-319-71371-7_2

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