Abstract
In this chapter, electrodes containing the cathode material Li[Ni0.33Co0.33Mn0.33]O2 (NCM) were recycled in order to test a newly developed recycling concept which is aiming towards commercial application. The possibility of graphite recovery from spent LIBs by means of three different treatment methods is demonstrated.
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References
Cançado LG, Takai K, Enoki T, Endo M, Kim YA, Mizusaki H, Jorio A, Coelho LN, Magalhães-Paniago R, Pimenta MA (2006) General equation for the determination of the crystallite size La of Nanographite by Raman Spectroscopy. Applied Physics Letters 88(16):163106. doi:http://dx.doi.org/10.1063/1.2196057
Castillo S, Ansart F, Laberty-Robert C, Portal J (2002) Advances in the recovering of spent lithium battery compounds. J Power Sources 112(1):247–254
Collins J, Gourdin G, Foster M, Qu D (2015) Carbon surface functionalities and SEI formation during Li Intercalation. Carbon 92(1):193–244. doi:http://dx.doi.org/10.1016/j.carbon.2015.04.007
Dippel C, Krueger S, Kraft V, Nowak S, Winter M, Li J (2013) Aging stability of Li2FeSiO4 polymorphs in LiPF6 containing organic electrolyte for lithium-ion batteries. Electrochimica Acta 105:542–546. doi:http://dx.doi.org/10.1016/j.electacta.2013.05.013
Dorella G, Mansur MB (2007) A study of the separation of cobalt from spent Li-ion battery residues. J Power Sources 170(1):210–215
Ferreira DA, Prados LMZ, Majuste D, Mansur MB (2009) Hydrometallurgical separation of aluminium, cobalt, copper and lithium from spent Li-ion batteries. J Power Sources 187(1):238–246. doi:http://dx.doi.org/10.1016/j.jpowsour.2008.10.077
Figueiredo JL, Pereira MFR, Freitas MMA, Órfão JJM (1999) Modification of the surface chemistry of activated carbons. Carbon 37(9):1379–1389. doi:http://dx.doi.org/10.1016/S0008-6223(98)00333-9
Fuente E, Menéndez JA, Suárez D, Montes-Morán MA (2003) Basic surface oxides on carbon materials: a global view. Langmuir 19(8):3505–3511. https://doi.org/10.1021/la026778a
Georgi-Maschler T, Friedrich B, Weyhe R, Heegn H, Rutz M (2012) Development of a recycling process for Li-ion batteries. J Power Sources 207:173–182. doi:http://dx.doi.org/10.1016/j.jpowsour.2012.01.152
Grützke M, Kraft V, Weber W, Wendt C, Friesen A, Klamor S, Winter M, Nowak S (2014) Supercritical carbon dioxide extraction of Lithium-Ion battery electrolytes. J Supercrit Fluids 94(1):216–222. doi:http://dx.doi.org/10.1016/j.supflu.2014.07.014
Grutzke M, Monnighoff X, Horsthemke F, Kraft V, Winter M, Nowak S (2015) Extraction of Lithium-Ion battery electrolytes with liquid and supercritical carbon dioxide and additional solvents. RSC Adv 5(54):43209–43217. https://doi.org/10.1039/c5ra04451k
Hanisch C, Haselrieder W, Kwade A (2011) Recovery of active materials from spent Lithium-Ion electrodes and electrode production rejects. In: Hesselbach J, Herrmann C (eds) Globalized solutions for sustainability in manufacturing. Springer Berlin Heidelberg, pp 85–89. doi:10.1007/978-3-642-19692-8_15
Jorio A, Saito R, Dresselhaus G, Dresselhaus MS (2011) Raman Spectroscopy: From Graphite to sp2 Nanocarbons. In: Jorio A, Saito R, Dresselhaus G, Dresselhaus MS (eds) Raman Spectroscopy in Graphene Related Systems. Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, Germany, pp 73–101. doi:10.1002/9783527632695.ch4
Kasnatscheew J, Evertz M, Streipert B, Wagner R, Klopsch R, Vortmann B, Hahn H, Nowak S, Amereller M, Gentschev AC, Lamp P, Winter M (2016) The truth about the 1st cycle coulombic efficiency of LiNi1/3Co1/3Mn1/3O2 (NCM) Cathodes. Phys Chem Chem Phys 18(5):3956–3965. https://doi.org/10.1039/c5cp07718d
Kohs W, Hofer F, Schrötner H, Doninger J, Barsukov I, Albering JH, Besenhard JO, Winter M (2003) Graphite’s crystallinity influences on anodes electrochemical properties in Lithium-Ion Cells. In: Julien CM, Prakash J (eds) New trends in intercalation compounds for energy storage and conversion: proceedings of the international symposium, vol 2003–20. Electrochemical Society, Pennington
Kraft V, Grützke M, Weber W, Menzel J, Wiemers-Meyer S, Winter M, Nowak S (2015) Two-dimensional ion chromatography for the separation of ionic organophosphates generated in thermally decomposed Lithium Hexafluorophosphate-based Lithium-Ion battery electrolytes. J Chromatogr A 1409(1):201–209. doi:http://dx.doi.org/10.1016/j.chroma.2015.07.054
Krüger S, Hanisch C, Kwade A, Winter M, Nowak S (2014) Effect of impurities caused by a recycling process on the electrochemical performance of Li[Ni0.33Co0.33Mn0.33]O2. J Electroanal Chem 726(1):91–96. doi:http://dx.doi.org/10.1016/j.jelechem.2014.05.017
Li L, Ge J, Wu F, Chen R, Chen S, Wu B (2010) Recovery of cobalt and lithium from spent Lithium ion batteries using organic citric acid as leachant. J Hazard Mater 176(1–3):288–293. doi:http://dx.doi.org/10.1016/j.jhazmat.2009.11.026
Li L, Lu J, Ren Y, Zhang XX, Chen RJ, Wu F, Amine K (2012) Ascorbic-acid-assisted recovery of cobalt and lithium from spent Li-ion batteries. J Power Sources 218:21–27
Lu W, Chung DDL (2001) Anodic performance of vapor-derived carbon filaments in Lithium-Ion secondary battery. Carbon 39(4):493–496. doi:http://dx.doi.org/10.1016/S0008-6223(00)00157-3
Lux SF, Lucas IT, Pollak E, Passerini S, Winter M, Kostecki R (2012) The mechanism of HF formation in LiPF6 based organic carbonate electrolytes. Electrochem Commun 14(1):47–50. https://doi.org/10.1016/j.elecom.2011.10.026
Contestabile M, Panero S, Scrosati B (1999) A laboratory-scale lithium batterie recycling process. J Power Sources 83:4
Pu N-W, Wang C-A, Sung Y, Liu Y-M, Ger M-D (2009) Production of few-layer graphene by supercritical CO2 exfoliation of Graphite. Mater Lett 63(23):1987–1989. doi:http://dx.doi.org/10.1016/j.matlet.2009.06.031
Rothermel S, Evertz M, Kasnatscheew J, Qi X, Grützke M, Winter M, Nowak S (2016) Graphite recycling from spent Lithium ion batteries. ChemSusChem [accepted]. doi:10.1002/cssc.201601062
Saeki S, Lee J, Zhang Q, Saito F (2004) Co-grinding LiCoO2 with PVC and water leaching of metal chlorides formed in ground product. Int J Mineral Process 74, Supplement (0):S373–S378. doi:http://dx.doi.org/10.1016/j.minpro.2004.08.002
Shin SM, Kim NH, Sohn JS, Yang DH, Kim YH (2005) Development of a metal recovery process from Li-ion battery wastes. Hydrometallurgy 79(3–4):172–181. doi:http://dx.doi.org/10.1016/j.hydromet.2005.06.004
Shu J, Shui M, Xu D, Wang D, Ren Y, Gao S (2011) A comparative study of overdischarge behaviors of cathode materials for Lithium-ion batteries. J Solid State Electrochem 16(2):819–824. https://doi.org/10.1007/s10008-011-1484-7
Stuart BH (2007) Degradation. In: Stuart BH (ed) Analytical techniques in the sciences. Wiley, Ltd., Chichester, pp 191–208. doi:10.1002/9780470511343.ch7
Sun L, Qiu K (2012) Organic oxalate as leachant and precipitant for the recovery of valuable metals from spent lithium-ion batteries. Waste Manag 32(8):1575–1582
Xing W, Dahn JR (1997) Study of irreversible capacities for Li insertion in hard and graphitic carbons. J Electrochem Soc 144(4):1195–1201. https://doi.org/10.1149/1.1837572
Young K, Wang C, Wang LY, Strunz K (2013) Electric vehicle battery technologies. In: Garcia-Valle R, Peças Lopes AJ (eds) Electric vehicle integration into modern power networks. Springer New York, New York, NY, pp 15–56. doi:10.1007/978-1-4614-0134-6_2
Zeng G, Deng X, Luo S, Luo X, Zou J (2012) A copper-catalyzed bioleaching process for enhancement of cobalt dissolution from spent lithium-ion batteries. J Hazard Mater 199–200:164–169
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Rothermel, S., Krüger, S., Winter, M., Nowak, S. (2018). Hydrometallurgical Processing and Thermal Treatment of Active Materials. In: Kwade, A., Diekmann, J. (eds) Recycling of Lithium-Ion Batteries. Sustainable Production, Life Cycle Engineering and Management. Springer, Cham. https://doi.org/10.1007/978-3-319-70572-9_13
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