Abstract
Treated wastewater is a reliable water resource for agriculture in arid and semiarid areas. Nanomaterials are promising to clean wastewater. Here we review nanomaterials characteristics, reactivity and potentiality to reduce or remove pollutants from wastewater. Characteristics include high reactivity of surface areas, quantum confinement effects, surface charge density and stability of nanophases. We discuss applications to remove from inorganic and organic contaminants, with focus on reaction kinetics, sorption and degradation. Remediation efficiency is also controlled by wastewater properties such as pH, ionic strength and water temperature.
The use of nanomaterials often allow a removal of more than 80% of most pollutants. Nonetheless, this review explains that the cost, the aggregate formation and the difficulty of recovering most applied nanomaterials are challenging. Alternatively, natural nanomaterials such as nano clay represent an inexpensive and environmental friendly substance for wastewater remediation.
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Abbreviations
- CNT:
-
Carbon nanotubes
- DOS:
-
density of states
- FAO:
-
Food and Agriculture Organization
- ISO:
-
International Organization for Standardization
- nZVI:
-
nanoscale zero valent iron
- POPs:
-
persistent organic pollutants
- PZC:
-
point of zero charge
- U.S EPA:
-
U.S. Environmental Protection Agency
- WHO:
-
World Health Organization
References
Abbasizadeh S, Keshtkar AR, Mousavian MA (2014) Sorption of heavy metal ions from aqueous solution by a novel cast PVA/TiO2 nanohybrid adsorbent functionalized with amine groups. J Ind Eng Chem 20(4):1656–1664. https://doi.org/10.1016/j.jiec.2013.08.013
Adeleye AS, Conway JR, Garner K, Huang Y, Su Y, Keller AA (2016) Engineered nanomaterials for water treatment and remediation: costs, benefits, and applicability. Chem Eng J 286:640–662. https://doi.org/10.1016/j.cej.2015.10.105
Afkhami A, Saber-Tehrani M, Bagheri H (2010) Simultaneous removal of heavy-metal ions in wastewater samples using nano-alumina modified with 2,4-dinitrophenylhydrazine. J Hazard Mater 181(1–3):836–844. https://doi.org/10.1016/j.jhazmat.2010.05.089
Agrawal DC (2013) Introduction to nanoscience and nanomaterials. World Scientific Publishing Co. Pte. Ltd, Singapore
Ahmadi K, Ghaedi M, Ansari A (2015) Comparison of nickel doped zinc sulfide and/or palladium nanoparticle loaded on activated carbon as efficient adsorbents for kinetic and equilibrium study of removal of Congo red dye. Spectrochim Acta A 136:1441–1449. https://doi.org/10.1016/j.saa.2014.10.034
Andrievski RA (2014) Review of thermal stability of nanomaterials. J Mater Sci 49:1449–1460. https://doi.org/10.1007/s10853-013-7836-1
Araújo R, Castro ACM, Baptista JS, Fiúza A (2016) Nanosized iron based permeable reactive barriers for nitrate removal-systematic review. Phys Chem Earth Pt A/B/C 94:29–34. https://doi.org/10.1016/j.pce.2015.11.007
Artiola JF (2006) Industrial and municipal solid waste treatment and disposal. In: Pepper IL, Gerba CP, Brusseau ML (eds) Environmental & pollution science, 2nd edn. Elsevier Inc, California, pp 415–428
Bao S, Li K, Ning P, Peng J, Jin X, Tang L (2017) Highly effective removal of mercury and lead ions from wastewater by mercaptoamine-functionalised silica-coated magnetic nano-adsorbents: behaviours and mechanisms. Appl Surf Sci 393:457–466. https://doi.org/10.1016/j.apsusc.2016.09.098
Barisik M, Atalay S, Beskok A, Qian S (2014) Size dependent surface charge properties of silica nanoparticles. J Phys Chem C 118:1836–1842. https://doi.org/10.1021/jp410536n
Bhatnagar A, Kumar E, Sillanpää M (2010) Nitrate removal from water by nano-alumina: characterization and sorption studies. Chem Eng J 163:317–323. https://doi.org/10.1016/j.cej.2010.08.008
Boverhof DR, Bramante CM, Butala JH, Clancy SF, Lafranconi M, West J, Gordon SC (2015) Comparative assessment of nanomaterial definitions and safety evaluation considerations. Regul Toxicol Pharm 73:137–150. https://doi.org/10.1016/j.yrtph.2015.06.001
Brant J, Lecaotnet H, Wiessner MR (2005) Aggregation and deposition characteristics of fullerene nanoparticles in aqueous systems. J Nanopart Res 7:545–553. https://doi.org/10.1007/s11051-005-4884-8
Bunani S, Yörükoğlu E, Sert G, Yüksel Ü, Yüksel M, Kabay N (2013) Application of nanofiltration for reuse of municipal wastewater and quality analysis of product water. Desalination 315:33–36. https://doi.org/10.1016/j.desal.2012.11.015
Bunani S, Yörükoğlu E, Yüksel Ü, Kabay N, Yüksel M (2014) Application of nanofiltration for reuse of wastewater. Int J Global Warming 6(2/3):325–338. https://doi.org/10.1504/IJGW.2014.061028
Buzea C, Blandino IIP, Robbie K (2007) Nanomaterials and nanoparticles: sources and toxicity. Biointerphases 2(4):MR17–MR172. https://doi.org/10.1116/1.2815690
Cai N, Larese-Casanova P (2016) Application of positively-charged ethylenediamine-functionalized graphene for the sorption of anionic organic contaminants from water. J Environ Chem Eng 4:2941–2951. https://doi.org/10.1016/j.jece.2016.06.004
Cao G, Wang Y (2011) Nanostructures and nanomaterials: synthesis, properties, and applications, World scientific series in nanoscience and nanotechnology: volume 2, 2nd edn. World Scientific Publishing Co. Pte. Ltd, Hackensack, p 581
Chamtouri I, Abida H, Khanfir H, Bouri S (2008) Impacts of at-site wastewater disposal systems on the groundwater aquifer in arid regions: case of Sfax City, southern Tunisia. Environ Geol 55:1123–1133. https://doi.org/10.1007/s00254-007-1060-8
Chen L, Feng S, Zhao D, Chen S, Li F, Chen C (2017) Efficient sorption and reduction of U(VI) on zero-valent iron-polyaniline-graphene aerogel ternary composite. J Colloid Interf Sci 490:197–206. https://doi.org/10.1016/j.jcis.2016.11.050
Clavier A, Seijo M, Carnal F, Stoll S (2015) Surface charging behavior of nanoparticles by considering site distribution and density, dielectric constant and pH changes – a Monte Carlo approach. Phys Chem Chem Phys 17:4346–4353. https://doi.org/10.1039/c4cp04733h
Dasgupta N, Ramalingam C (2016) Silver nanoparticle antimicrobial activity explained by membrane rupture and reactive oxygen generation. Environ Chem Lett 14(4):477–485
Dasgupta N, Ranjan S, Mundekkad D, Ramalingam C, Shanker R, Kumar A (2015) Nanotechnology in agro-food: from field to plate. Food Res Int 69:381–400
Dasgupta N, Ranjan S, Rajendran B, Manickam V, Ramalingam C, Avadhani GS, Kumar A (2016a) Thermal co-reduction approach to vary size of silver nanoparticle: its microbial and cellular toxicology. Environ Sci Pollut Res 23(5):4149–4163
Dasgupta N, Ranjan S, Chakraborty AR, Ramalingam C, Shanker R, Kumar A (2016b) Nanoagriculture and water quality management. Pp 1-42. In: Ranjan S, Dasgupta N, Lichtfouse E (eds) Nanoscience in food and agriculture 1, sustainable agriculture reviews (20). Springer, Cham
Dasgupta N, Ranjan S, Ramalingam C (2017) Applications of nanotechnology in agriculture and water quality management. Environ Chem Lett 15(4):591–605
Elbana TA, Ramadan MA, Gaber HM, Bahnassy MH, Kishk FM, Selim HM (2013) Heavy metals accumulation and spatial distribution in long term wastewater irrigated soils. J Environ Chem Eng 1:925–933. https://doi.org/10.1016/j.jece.2013.08.005
Fang Z, Chen J, Qiu X, Qiu X, Cheng W, Zhu L (2011) Effective removal of antibiotic metronidazole from water by nanoscale zero-valent iron particles. Desalination 268:60–67. https://doi.org/10.1016/j.desal.2010.09.051
FAO (Food and Agriculture Organization of the United Nations) (2017) AQUASTAT. Available at: http://www.fao.org/nr/water/aquastat/water_use/index.stm. Accessed 28 Jan 2017
Flörke M, Kynast E, Bärlund I, Eisner S, Wimmer F, Alcamo J (2013) Domestic and industrial water uses of the past 60 years as a mirror of socio-economic development: a global simulation study. Glob Environ Chang 23(1):144–156. https://doi.org/10.1016/j.gloenvcha.2012.10.018
Fu F, Wang Q (2011) Removal of heavy metal ions from wastewaters: a review. J Environ Manag 92:407–418. https://doi.org/10.1016/j.jenvman.2010.11.011
Fu Q, Xue Y, Cui Z, Wang M (2014) Study on the size-dependent oxidation reaction kinetics of nanosized zinc sulfide. J Nanomat. Article ID 856489,8 pages. doi:https://doi.org/10.1155/2014/856489
Gautam RK, Chattopadhyaya MC (2016) Nanotechnology for water cleanup. In: Gautam RK, Chattopadhyaya MC (eds) Nanomaterials for wastewater remediation. Butterworth-Heinemann, Boston, pp 1–18
Gehrke I, Geiser A, Somborn-Schulz A (2015) Innovations in nanotechnology for water treatment. Nanotechnol Sci Appl 8:1–17. https://doi.org/10.2147/NSA.S43773
Ghasemi Z, Younesi H, Zinatizadeh AA (2016) Kinetics and thermodynamics of photocatalytic degradation of organic pollutants in petroleum refinery wastewater over nano-TiO2 supported on Fe-ZSM-5. J Taiwan Inst Chem E 65:357–366. https://doi.org/10.1016/j.jtice.2016.05.039
Hasemzadeh G, Momenpour M, Omidi F (2014) Applications of nanomaterials in water treatment and environmental remediation. Front Environ Sci En 8(4):471–482. https://doi.org/10.1007/s11783-014-0654-0
Hayati B, Maleki A, Najafi F, Daraei H, Gharibi F, McKay G (2016) Synthesis and characterization of PAMAM/CNT nanocomposite as a super-capacity adsorbent for heavy metal (Ni2+, Zn2+, As3+, Co2+) removal from wastewater. J Mol Liq 224:1032–1040. https://doi.org/10.1016/j.molliq.2016.10.053
He Z, Alexandridis P (2015) Nanoparticles in ionic liquids: interactions and organization. Phys Chem Chem Phys 17:18238–18261. https://doi.org/10.1039/C5CP01620G
Henze M (2002) Wastewater, volumes and composition. In: Henze M, Harremoës P, JlC J, Arvin E (eds) Wastewater treatment, Biological and chemical processes, 3rd edn. Springer, Berlin/Heidelberg, pp 11–42
Holmes AB, Gu FX (2016) Emerging nanomaterials for the application of selenium removal for wastewater treatment. Environ Sci Nano 3:982–996. https://doi.org/10.1039/C6EN00144K
Huong P-T, Lee B-K, Kim J (2016) Improved removal of 2-chlorophenol by a synthesized Cu-nano zeolite. Process Saf Environ Prot 100:272–280. https://doi.org/10.1016/j.psep.2016.02.002
ISO (2015) ISO/TS 80004-1:2015. Nanotechnologies – vocabulary – part 1: core terms. International Organization for Standardization
Jain A, Ranjan S, Dasgupta N, Ramalingam C (2016) Nanomaterials in food and agriculture: an overview on their safety concerns and regulatory issues. Crit Rev Food Sci Nutr 15:1–21
Janardan S, Suman P, Ragul G, Anjaneyulu U, Shivendu R, Dasgupta N, Ramalingam C, Swamiappan S, Vijayakrishna K, Sivaramakrishna A (2016) Assessment on the antibacterial activity of nanosized silica derived from hypercoordinated silicon(iv) precursors. RSC Adv 6(71):66394–66406
Kanel SR, Manning B, Charlet L, Choi H (2005) Removal of arsenic(III) from groundwater by nanoscale zero-valent iron. Environ Sci Technol 39:1291–1298. https://doi.org/10.1021/es048991u
Kanjwal MA, Alm M, Thomsen P, Barakat NAM (2016) Hybrid matrices of TiO2 and TiO2–Ag nanofibers with silicone for high water flux photocatalytic degradation of dairy effluent. J Ind Eng Chem 33:142–149. https://doi.org/10.1016/j.jiec.2015.09.026
Karaouzas I (2016) Agro-industrial wastewater pollution in Greek river ecosystems. In: The handbook of environmental chemistry. Springer, Berlin/Heidelberg. https://doi.org/10.1007/698_2016_453.
Karthikeyan KG, Meyer MT (2006) Occurrence of antibiotics in wastewater treatment facilities in Wisconsin, USA. Sci Total Environ 361:196–207. https://doi.org/10.1016/j.scitotenv.2005.06.030
Kootenaei FG, Rad HA (2013) Treatment of hospital wastewater by novel nano-filtration membrane bioreactor (NF-MBR). Iran J Energ Env 4(1):60–67. https://doi.org/10.5829/idosi.ijee.2013.04.01.10
Kržišnik N, Mladenovič A, Škapin AS, Škrlep L, Ščančar J, Milačič R (2014) Nanoscale zero-valent iron for the removal of Zn2+, Zn(II)–EDTA and Zn(II)–citrate from aqueous solutions. Sci Total Environ 476-477:20–28. https://doi.org/10.1016/j.scitotenv.2013.12.113
Kumar R, Chawla J (2014) Removal of cadmium ion from water/ wastewater by nano-metal oxides: a review. Water Qual Expo Health 5:215–226. https://doi.org/10.1007/s12403-013-0100-8
Lefevre E, Bossa N, Wiesner MR, Gunsch CK (2016) A review of the environmental implications of in situ remediation by nanoscale zero valent iron (nZVI): behavior, transport and impacts on microbial communities. Sci Total Environ 565:889–901. https://doi.org/10.1016/j.scitotenv.2016.02.003
Levenspiel O (1999) Chemical reaction engineering, 3rd edn. Wiley, New York, p 668
Li K, Wang J, Liu J, Wei Y, Chen M (2016) Advanced treatment of municipal wastewater by nanofiltration: operational optimization and membrane fouling analysis. J Environ Sci 43:106–117. https://doi.org/10.1016/j.jes.2015.09.007
Liu X, Wang M, Zhang S, Pan B (2013) Application potential of carbon nanotubes in water treatment: a review. J Environ Sci 25(7):1263–1280. https://doi.org/10.1016/S1001-0742(12)60161-2
Maddinedi SB, Mandal BK, Ranjan S, Dasgupta N (2015) Diastase assisted green synthesis of size-controllable gold nanoparticles. RSC Adv 5(34):26727–26733
Maddinedi SB, Mandal BK, Patil SH, Andhalkar VV, Ranjan S, Dasgupta N (2017) Diastase induced green synthesis of bilayered reduced graphene oxide and its decoration with gold nanoparticles. J Photochem Photobiol B Biol 166:252–258
McDonald J, Gaston L, Elbana T, Kevin A, Eileen C (2013) Dimoxystrobin sorption and degradation in sandy loam soil: impact of different landscape positions. Soil Sci 178:662–670. https://doi.org/10.1097/SS.0000000000000030
Méndez V, Fedotov S, Horsthemke W (2010) Reaction-transport systems, mesoscopic foundations, fronts, and spatial instabilities. Springer-Verlag, Berlin/Heidelberg, p 454
Meng X, Liu Z, Deng C, Zhu M, Wang D, Li K, Deng Y, Jiang M (2016) Microporous nano-MgO/diatomite ceramic membrane with high positive surface charge for tetracycline removal. J Hazard Mater 320:495–503. https://doi.org/10.1016/j.jhazmat.2016.08.068
Mondloch JE, Bayram E, Finke RG (2012) A review of the kinetics and mechanisms of formation of supported-nanoparticle heterogeneous catalysts. J Mol Catal A-Chem 355:1–38. https://doi.org/10.1016/j.molcata.2011.11.011
Murty BS, Shankar P, Raj B, Rath BB, Murday J (2013) Applications of nanomaterials. In: Textbook of nanoscience and nanotechnology. Springer, Berlin/Heidelberg, pp 107–148
Nadaroglu H, Cicek S, Gungor AA (2017) Removing Trypan blue dye using nano-Zn modified Luffa sponge. Spectrochim Acta A 172:2–8. https://doi.org/10.1016/j.saa.2016.08.052
O’Carroll D, Sleep B, Krol M, Boparai H, Kocur C (2013) Nanoscale zero valent iron and bimetallic particles for contaminated site remediation. Adv Water Resour 51:104–122. https://doi.org/10.1016/j.advwatres.2012.02.005
Pham T, Lee B, Kim J (2016) Improved adsorption properties of a nano zeolite adsorbent toward toxic nitrophenols. Process Saf Environ 104(322):314. https://doi.org/10.1016/j.psep.2016.08.018
Qu X, Alvarez PJJ, Li Q (2013) Applications of nanotechnology in water and wastewater treatment. Water Res 47:3931–3946. https://doi.org/10.1016/j.watres.2012.09.058
Raghunath S, Anand K, Gengan RM, Nayunigari MK, Maity A (2016) Sorption isotherms, kinetic and optimization process of amino acid proline based polymer nanocomposite for the removal of selected textile dyes from industrial wastewater. J Photoch Photobio B 165:189–201. https://doi.org/10.1016/j.jphotobiol.2016.10.012
Ramya T, Anbazhagi M, Muthukumar M (2016) Electrochemical oxidation of fipronil contaminated wastewater by RuO2/IrO2/TaO2 coated titanium anodes and sorbent nano hydroxyapatite. Mater Today Proc 3(6):2509–2517. https://doi.org/10.1016/j.matpr.2016.04.169
Ranjan S, Ramalingam C (2016) Titanium dioxide nanoparticles induce bacterial membrane rupture by reactive oxygen species generation. Environ Chem Lett 14(4):487–494
Ranjan S, Dasgupta N, Chakraborty AR, Melvin Samuel S, Ramalingam C, Shanker R, Kumar A (2014) Nanoscience and nanotechnologies in food industries: opportunities and research trends. J Nanopart Res 16(6):1–23
Ranjan S, Dasgupta N, Rajendran B, Avadhani GS, Ramalingam C, Kumar A (2016) Microwave-irradiation-assisted hybrid chemical approach for titanium dioxide nanoparticle synthesis: microbial and cytotoxicological evaluation. Environ Sci Pollut Res 23(12):12287–12302
Ray PZ, Shipley HJ (2015) Inorganic nano-adsorbents for the removal of heavy metals and arsenic: a review. RSC Adv 5:29885–29907. https://doi.org/10.1039/C5RA02714D
Ren X, Chen C, Nagatsu M, Wang X (2011) Carbon nanotubes as adsorbents in environmental pollution management: a review. Chem Eng J 170:395–410. https://doi.org/10.1016/j.cej.2010.08.045
Roduner E (2006) Size matters: why nanomaterials are different. Chem Soc Rev 35:583–592. https://doi.org/10.1039/B502142C
Rosales E, Pazos M, Sanromán MÁ (2017) Advanced oxidation processes using nanomaterials. In: Gautam RK, Chattopadhyaya MC (eds) Advanced nanomaterials for wastewater remediation. Taylor & Francis Group, LLC, Boca Raton, pp 109–132
Safavi A, Momeni S (2012) Highly efficient degradation of azo dyes by palladium/hydroxyapatite/Fe3O4 nanocatalyst. J Hazard Mater 201–202:125–131. https://doi.org/10.1016/j.jhazmat.2011.11.048
Savage N, Diallo MS (2005) Nanomaterials and water purification: opportunities and challenges. J Nanopart Res 7:331–342. https://doi.org/10.1007/s11051-005-7523-5
Shahmansouri A, Bellona C (2015) Nanofiltration technology in water treatment and reuse: applications and costs. Water Sci Technol 71(3):309–319. https://doi.org/10.2166/wst.2015.015
Shukla A, Dasgupta N, Ranjan S, Singh S, Chidambram R (2017) Nanotechnology towards prevention of anaemia and osteoporosis: from concept to market. Biotechnol Biotechnol Equip 31(5):863–879
Siripireddy B, Mandal BK, Ranjan S, Dasgupta N, Ramalingam C (2017) Nano-zirconia – evaluation of its antioxidant and anticancer activity. J Photochem Photobiol B Biol 170:125–133
Solveyra ES, Szleifer I (2016) What is the role of curvature on the properties of nanomaterials for biomedical applications? WIREs Nanomed Nanobi 8:334–354. https://doi.org/10.1002/wnan.1365
Stahl T, Mattern D, Brunn H (2011) Toxicology of perfluorinated compounds. Environ Sci Eur 23:38–52. https://doi.org/10.1186/2190-4715-23-38
Tammina SK, Mandal BK, Ranjan S, Dasgupta N (2017) Cytotoxicity study of Piper nigrum seed mediated synthesized SnO2 nanoparticles towards colorectal (HCT116) and lung cancer (A549) cell lines. J Photochem Photobiol B Biol 166:158–168
Tanji KK, Kielen NC (2002) Agricultural drainage water management in arid and semi-arid areas, FAO irrigation and drainage paper 61. Food and Agriculture Organization of the United Nations, Rome
U.S. Environmental Protection Agency (2012) Guidelines for water reuse, 600/R-12/618. U.S. EPA, Washington, DC
UN-Water (2015) Wastewater management - a UN-water analytical brief. United Nations, New York. Note. http://www.unwater.org/publications/publications-detail/en/c/275896/.Accessed 18 Nov 2016
Walia N, Dasgupta N, Ranjan S, Chen L, Ramalingam C (2017) Fish oil based vitamin D nanoencapsulation by ultrasonication and bioaccessibility analysis in simulated gastro-intestinal tract. Ultrason Sonochem 39:623–635
Wang Y, Gao H, Xu H (2011) Nanogeochemistry: nanostructures and their reactivity in natural systems. In: Parker A, Russell H (eds) Frontiers in geochemistry. Wiley-Blackwell, Chichester, pp 200–220
WHO, World Health Organization (2006a) Guidelines for the safe use of wastewater, excreta and greywater, volume 1: policy and regulatory aspects. World Health Organization, Geneva, pp 1–114
WHO, World Health Organization (2006b) Guidelines for the safe use of wastewater, excreta and greywater, volume 2: wastewater use in agriculture. World Health Organization, Geneva, pp 1–196
WHO, World Health Organization (2006c) Guidelines for the safe use of wastewater, excreta and greywater, volume 3: wastewater and excreta use in aquaculture. World Health Organization, Geneva, pp 1–140
WHO, World Health Organization (2006d) Guidelines for the safe use of wastewater, excreta and greywater, volume 4: excreta and greywater use in agriculture. World Health Organization, Geneva, pp 1–182
Yurekli Y (2016) Removal of heavy metals in wastewater by using zeolite nano-particles impregnated polysulfone membranes. J Hazard Mater 309:53–64. https://doi.org/10.1016/j.jhazmat.2016.01.064
Zhang M, Gao B, Jin J, Chen H, Yao Y, Fang J, Creamer AE (2015a) Use of nanotechnology against heavy metals present in water. In: Sharma SK (ed) Heavy metals in water: presence, removal and safety. The Royal Society of Chemistry, Cambridge, pp 177–192
Zhang C, Wang L, Li J, Su P, Peng C (2015b) Removal of perfluorinated compounds in wastewater treatment plant effluents by electrochemical oxidation. Water Sci Technol 71(12):1783–1789. https://doi.org/10.2166/wst.2015.160
Zhang Y, Wu B, Xu H, Liu H, Wang M, He Y, Pan B (2016) Nanomaterials-enabled water and wastewater treatment. NanoImpact 3-4:22–39. https://doi.org/10.1016/j.impact.2016.09.004
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Elbana, T., Yousry, M. (2018). Nanomaterials Reactivity and Applications for Wastewater Cleanup. In: Gothandam, K., Ranjan, S., Dasgupta, N., Ramalingam, C., Lichtfouse, E. (eds) Nanotechnology, Food Security and Water Treatment. Environmental Chemistry for a Sustainable World. Springer, Cham. https://doi.org/10.1007/978-3-319-70166-0_8
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