Skip to main content

Groundwater Age Dating in Motril-Salobreña Coastal Aquifer with Environmental Tracers (δ18O/δ2H, 3H/3He, 4He, 85Kr, and 39Ar)

  • Conference paper
  • First Online:
Groundwater and Global Change in the Western Mediterranean Area

Abstract

The Motril-Salobreña coastal aquifer (SE Spain) is under high anthropogenic pressure due to the changes in river infiltration, irrigation and pumping. There are several uncertainties regarding how groundwater flows from the recharge areas to the discharge areas, and how long groundwater circulates in the aquifer due to the presence of layers with different hydraulic conductivity. This study constrains the age distribution in the aquifer by dating water samples taken at three different locations (recharge sector, intermediate sector and discharge sector) and at variable depths. The environmental tracers used were δ18O/δ2H, 4He, 3H/3He, 85Kr, and 39Ar. The groundwater dating allows to define the flow distribution and preferential flowpaths, to determine the mean groundwater residence times in the system and to establish the connection between age distribution and saltwater intrusion processes. Mean groundwater residence times range from recent to ~170 years, with the presence of young water in almost all the areas of the aquifer at a shallow depth and an age gradient at deeper locations in the discharge zone. The presence of the salt wedge increases the age mixing processes. The groundwater flow in the shallow part of the aquifer (0–50 m depth) turns out to be fast, with a residence time lower than 5 years, while the flow in the deeper parts (50–150 m depth) is slower and groundwater has at least 170 years.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  • Åkesson M, Suckow A, Visser A, Sültenfuβ J, Laier T, Purtschert R, Sparrenbom CJ (2015) Constraining age distributions of groundwater from public supply wells in diverse hydrogeological settings in Scania, Sweden. J Hydrol 528:217–229

    Article  Google Scholar 

  • Benettin P, Rinaldo A, Botter G (2013) Kinematics of age mixing in advection-dispersion models. Water Resour Res 49:8539–8551

    Article  Google Scholar 

  • Broers HP (2004) The spatial distribution of groundwater age for different geohydrological situations in the Netherlands: implications for groundwater quality monitoring at the regional scale. J Hydrol 299(1):84–106

    Article  Google Scholar 

  • Cook PG, Böhlke JK (2000) Determining timescales for groundwater flow and solute transport. In: Environmental tracers in subsurface hydrology, pp 1–30

    Google Scholar 

  • Corcho-Alvarado JA, Purtschert R, Barbecot F, Chabault C, Rueedi J, Schneider V, Aeschbach‐Hertig W, Kipfer R, Loosli H (2007) Constraining the age distribution of highly mixed groundwater using 39Ar: A multiple environmental tracer (3H/3He, 85Kr, 39Ar, and 14C) study in the semiconfined Fontainebleau sands aquifer (France). Water Resour Res 43(3):16 p

    Google Scholar 

  • Duque C, Calvache ML, Pedrera A, Martín-Rosales W, López-Chicano M (2008) Combined time domain electromagnetic soundings and gravimetry to determine marine intrusion in a detrital coastal aquifer (southern Spain). J Hydrol 349:536–547

    Article  Google Scholar 

  • Duque C, López-Chicano M, Calvache M, Martín-Rosales W, Gómez-Fontalva J, Crespo F (2011) Recharge sources and hydrogeological effects of irrigation and an influent river identified by stable isotopes in the Motril-Salobreña aquifer (southern Spain). Hydrol Process 25:2261–2274

    Article  Google Scholar 

  • Duque C (2009) Influencia antrópica sobre la hidrogeología del acuífero Motril-Salobreña. Doctoral thesis, University of Granada, Granada, Spain, 196 pp

    Google Scholar 

  • Loosli HH, Purtschert R (2005) Rare gases. In: Aggarwal P, Gat JR, Froehlich K (eds) Isotopes in the water cycle: past, present and future of a developing science. IAEA, Vienna, pp 91–95

    Chapter  Google Scholar 

  • Reilly TE, Plummer LN, Phillips PJ, Busenberg E (1994) The use of simulation and multiple environmental tracers to quantify groundwater flow in a shallow aquifer. Water Resour Res 30:421–433

    Article  Google Scholar 

  • Riedmann RA, Purtschert R (2016) Separation of argon from environmental samples for Ar-37 and Ar-39 analyses. Sep Purif Technol 170:217–223

    Article  Google Scholar 

  • Sanford W (2011) Calibration of models using groundwater age. Hydrogeol J 19:13–16

    Article  Google Scholar 

  • Solomon DK (2000) 4He in groundwater. In: Environmental tracers in subsurface hydrology, pp 425–439

    Google Scholar 

  • Suckow A (2014) The age of groundwater—definitions, models and why we do not need this term. Appl Geochem 50:222–230

    Article  Google Scholar 

  • Sültenfuβ J, Purtschert R, Führböter JF (2011) Age structure and recharge conditions of a coastal aquifer (Northern Germany) investigated with 39Ar, 14C, 3H, He isotopes and Ne. Hydrogeol J 19:221–236

    Article  Google Scholar 

  • Winger K, Feichter J, Kalinowski MB, Sartorius H, Schlosser C (2005) A new compilation of the atmospheric 85krypton inventories from 1945 to 2000 and its evaluation in a global transport model. J Environ Radioact 80:183–215

    Article  Google Scholar 

  • Woolfenden LR, Ginn TR (2009) Modeled groundwater age distributions. Ground Water 47:547–557

    Article  Google Scholar 

Download references

Acknowledgements

This study was supported by project CGL2016-77503-R, which was funded by the Ministerio de Economía y Competitividad (Government of Spain), by the research group RNM-369 of the Junta de Andalucía and by the Marie Curie International Outgoing Fellowship (624496).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to J. P. Sánchez-Úbeda .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2018 Springer International Publishing AG

About this paper

Cite this paper

Sánchez-Úbeda, J.P. et al. (2018). Groundwater Age Dating in Motril-Salobreña Coastal Aquifer with Environmental Tracers (δ18O/δ2H, 3H/3He, 4He, 85Kr, and 39Ar). In: Calvache, M., Duque, C., Pulido-Velazquez, D. (eds) Groundwater and Global Change in the Western Mediterranean Area. Environmental Earth Sciences. Springer, Cham. https://doi.org/10.1007/978-3-319-69356-9_33

Download citation

Publish with us

Policies and ethics