Abstract
This chapter introduces the reader to the analysis of the structural and electronic system properties of various carbon allotropes (CNT, graphene) and several molecular derivatives. The genesis of the electronic system formation is investigated in detail. Non-regular defected nanocarbon systems are considered for possible applications in different fields, including energy storage; chemical, biochemical and electrochemical sensing; water purification; and catalysis.
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References
Hirsch A 2010 The era of carbon allotropes Nature materials 4 868–70
Greenville Whittaker A 1978 The controversial carbon solid-liquid-vapour triple point Nature 276(5689) 695–6
Shenderova O A, Zhirno V V, Brenner D W 2002 Carbon Nanostructures Critical Reviews in Solid State and Materials Sciences 27(3/4) 227–356
Cambridge Structural Database 2016 https://www.ccdc.cam.ac.uk/structures-beta/, retrieved 2016–10-14
Crystallography Open Database 2016 http://www.crystallography.net, accessed 2016 10 02
Straumanis M E, Aka E Z 1951 Precision determination of lattice parameter, coefficient of thermal expansion and atomic weight of carbon in diamond J. Am. Chem. Soc. 73 5643–6
Simpson C D, Brand J D, Berresheim A J, Przybilla L, Räder H J, Müllen K 2002 Synthesis of a Giant 222 Carbon Graphite Sheet Chemistry 6(6) 1424–9
Cooper D R, D’Anjou B, Ghattamaneni N, Harack B, Hilke M, Horth A, Majlis N, Massicotte M, Vandsburger L, Whiteway E, Yu V 2012 Experimental Review of Graphene ISRN Condensed Matter Physics International Scholarly Research Network 2012 1–56
Singh S B, Singh A 2002 The Third Allotrope of Carbon: Fullerene an Update International Journal of ChemTech Research 5(1) 167–71
Qiao R, Roberts A P, Mount A S, Klaine S, J, Ke P C 2007 Translocation of C60 and Its Derivatives Across a Lipid Bilayer Nano Letters 7(3) 614–9
Eatemadi A, Daraee H, Karimkhanloo H, Kouhi M, Zarghami N, Akbarzadeh A, Abasi M, Ha-nifehpour Y, Joo S W 2014 Carbon nanotubes: properties, synthesis, purification, and medical applications Nanoscale Research Letters 9 393
Tersoff J, Ruoff R S 1994 Structural Properties of a Carbon-Nanotube Crystal Physical Review Letters 73(5) 676–9
Veiga R G A, Tomanek D, Frederick N 2008 Carbon nanotube generation applet, http://www.nanotube.msu.edu/tubeASP/, accessed 2016 08 16
Terrones M 2003 Science and technology of the twenty-first century: synthesis, proper types, and applications of carbon nanotubes Annu. Rev. Mater. Res. 33 419–501
Gaussian 09, Revision D.01 2013 Frisch M J, Trucks G W, Schlegel H B, Scuseria G E, Robb M A, Cheeseman J R, Scalmani G, Barone V, Mennucci B, Petersson G A, Nakatsuji H, Caricato M, Li X, Hratchian H P, Izmaylov A F, Bloino J, Zheng G, Sonnenberg J L, Hada M, Ehara M, Toyota K, Fukuda R, Hasegawa J, Ishida M, Nakajima T, Honda Y, Kitao O, Nakai H, Vreven T, Montgomery J A Jr, Peralta J E, Ogliaro F, Bearpark M, Heyd J J, Brothers E, Kudin K N, Staroverov V N, Keith T, Kobayashi R, Normand J, Raghavachari K, Rendell A, Burant J C, Iyengar S S, Tomasi J, Cossi M, Rega N, Millam J M, Klene M, Knox J E, Cross J B, Bakken V, Adamo C, Jaramillo J, Gomperts R, Stratmann R E, Yazyev O, Austin A J, Cammi R, Pomelli C, Ochterski J W, Martin R L, Morokuma K, Zakrzewski V G, Voth G A, Salvador P, Dannenberg J J, Dapprich S, Daniels A D, Farkas O, Foresman J B, Ortiz J V, Cioslowski J, Fox D J, Gaussian, Inc., Wallingford CT.
Wang C M, Zhang Y Y, Xiang Y, Reddy J N 2010 Recent Studies on Buckling of Carbon Nanotubes Appl. Mech. Rev. 63(3) 030804
Bolotin K I, Sikes K J, Jiang Z, Klima M, Fudenberg G, Hone J, Kim P, Stormer H L 2008 Ultrahigh electron mobility in suspended graphene Solid State Communications 146 351–5
Novoselov K S, McCann E, Morozov S V, Falko V I, Katsnelson M I, Zeitler U, Jiang D, Schedin F, Geim A K 2006 Unconventional quantum Hall effect and Berry’s phase of 2pi in bilayer graphene Nature Physics 2 177–80
Saito R, Fujita M, Dresselhaus G, Dresselhaus M S 1992 Electronic structure of chiral graphene tubules Appl. Phys. Lett. 60 2204–6
Saito R, Fujita M, Dresselhaus G, Dresselhaus M S 1992 Electronic structure of graphene tubules based on C60 Phys. Rev. B 46 1804–11
Minot E D, Yaish Y, Sazonova V, McEuen P L 2004 Determination of electron orbital magnetic moments in carbon nanotubes Nature 428 536–9
Ramirez A P, Haddon R C, Zhou O, Fleming R M, Zhang J, McClure S M, Smalley R E 1994 Magnetic susceptibility of molecular carbon: nanotubes and fullerite Science 265 84–6
Wang J, Jiang W, Wang B, Gao Y, Wang Z, Zhang R Q 2016 Chirality dependent spin polarization of carbon nanotubes New J. Phys. 18 023029
Jespersen T S, Grove-Rasmussen K, Paaske J, Muraki K, Fujisawa T, Nygard J, Flensberg K 2011 Gate-dependent spin–orbit coupling in multielectron carbon nanotubes Nature Physics 7 348–53
Wang B, Wang J 2010 First-principles investigation of transport properties through longitudinal unzipped carbon nanotubes Physical Review B 81 045425
Miyauchi Y, Oba M, Maruyama S 2006 Cross-polarized optical absorption of single-walled nanotubes by polarized photoluminescence excitation spectroscopy Physical Review B 74 205440
Iakoubovskii N, Minami N, Kim Y, Miyashita K, Kazaoui S, Nalini B 2006 Midgap luminescen-ce centers in single-wall carbon nanotubes created by ultraviolet illumination Applied physics letters 89 173108
Wildoer J W G, Venema L C, Rinzler A G, Smalley R E, Dekker C 1998 Electronic structure of atomically resolved carbon nanotubes Nature 391 59–62
Odom T W, Huang J L, Kim P, Lieber C M 1998 Atomic structure and electronic properties of single-walled carbon nanotubes Nature 391 62–4
Luo C, Xie H, Wang Q, Luo G, Liu C 2015 A Review of the Application and Performance of Carbon Nanotubes in Fuel Cells Journal of Nanomaterials 2015 560392
Girishkumar G, Rettker M, Underhile R, Binz D, Vinodgopal K, McGinn P, Kamat P 2005 Single-wall carbon nanotube-based proton exchange membrane assembly for hydrogen fuel cells Langmuir 21(18) 8487–94
Berkovic G, Krongauz V, Weiss V 2000 Spiropyrans and Spirooxazines for Memories and Swi-tches Chem. Rev. 100 1741–53
Madani S Y, Mandel A, Seifalian A A 2013 A concise review of carbon nanotube’s toxicology Nano Rev. 4(10) 21521(1–14)
Rajasekaran G, Narayanan P, Parashar A 2016 Effect of Point and Line Defects on Mechanical and Thermal Properties of Graphene: A Review Critical Reviews in Solid State and Materials Sciences 41(1) 47–71
Krasheninnikov A V, Lehtinen P O, Foster A S, Pyykkö P, Nieminen R M 2009 Embedding Transition-Metal Atoms in Graphene: Structure, Bonding, and Magnetism Phys. Rev. Lett. 102 12680
Wang M C, Yan C, Ma L, Hu N, Chen M W 2012 Effect of defects on fracture strength of graphene sheets Comput.Mater.Sci. 54 236–9
Zandiatashbar A, Lee G H, An S J, Lee S, Mathew N, Terroness M, Hayashi T, Picu C R, Hone J, Koratkar N 2014 Effect of defects on the intrinsic strength and stiffness of graphene Nat. Commun. 5 3186
Wang M C, Yan C, Galpaya D, Zheng B L, Ma L, Hu N, Yuan Q, Bai R, Zhou L 2013 Molecular dynamics simulation of fracture strength and morphology of defective graphene J.Nano Res. 23 43–9
Balandin A A, Ghosh S, Bao W, Calizo I, Teweldebrhan D,Feng M, Lau C N 2008 Superior thermal conductivity of single-layer graphene Nano Lett. 8, 902–7
Baimova J A, Bo L, Dmitriev S V, Zhou K, Nazarov A A 2013 Effect of Stone-Thrower-Wales defect on structural stability of graphene at zero and finite temperature EPL 103 46001
Xiao L, Thomas H M, Robinson J T, Houston B H, Scarpa F 2012 Shear modulus of monolayer graphene prepared by chemical vapor deposition Nano Lett. 12 1013–7
Gillen R, Mohr M, Maultzsch J 2010 Raman-active modes in graphene nanoribbons Phys. Status Solidi B 247 2941–4
Bosak A, Krisch M, Mohr M, Maultzsch J, Thomsen C 2007 Elasticity of single-crystalline graphite: Inelastic x-ray scattering study Phys. Rev. B Condens. Matter 75 153408
Dmitrriev S V, Baimoya J A, Savin A V, Kivshar Y S 2012 Ultimate strength, ripples, sound velocities, and density of phonon states of strained graphene Comput. Mater. Sci. 53 194–203
Zakharchenko K V, Los J H, Katsnelson M I, Fasolino A 2010 Atomistic simulations of structural and thermodynamic properties of bilayer graphene Phys. Rev. B Condens. Matter 81 235439(1–6)
Zhu Y, Murali S, Cai W, Li X, Suk J W, Potts J R, Ruoff R S 2010 Graphene and graphene oxide: synthesis, properties and applications Adv. Mater. 22 3906–24
Edwards R S, Coleman K S 2013 Graphene synthesis: relationship to applications Nanoscale 5 38–51
Bolotin K I, Sikes K J, Jiang Z, Klima M, Fudenberg G, Hone J, Kim P, Stormer H L 2008 Ultrahigh electron mobility in suspended graphene Solid State Commun. 146 351–5
Taghioskoui M 2009 Trends in graphene research Mater. Today 12 34–7
Geim K 2009 Graphene: status and prospects Science 324 1530–4
Garg R, Dutta N K, Choudhuri N R 2014 Work function engineering of graphene Nanomaterials 4 267–300
Araujo P T, Terrones M, Dresselhaus M S 2012 Defects and impurities in graphene-like materials Mater. Today 15(3) 98–109
Liu L, Qing M, Wang Y, Chen S 2015 Defects in graphene: generation, healing, and their effects on the properties of graphene: a review J. Mater. Sci. Technol. 31 599–606
Zhang T, Li X, Gao H 2014 Designing graphene structure with controlled distributions of topological defects: A case study of toughness enhancement in graphene ruga Extreme Mech. Lett. 1 3–8
Robertson W, Warner J H 2013 Atomic resolution imaging of graphene by transmission electron microscopy Nanoscale Res. Lett. 5 4079–93
Xu L, Wei N, Zheng Y 2013 Mechanical properties of highly defective graphene: from brittle rupture to ductile fracture Nanotechnology 24 505703
Sun S, Wang C, Chen M, Zheng J 2013 A novel method to control atomic defects in graphene sheets, by selective surface reactions Appl. Surf. Sci. 283 566–70
Liu J, Liu Z, Barrow C J, Yang W 2015 Molecularly engineered graphene surfaces for sensing applications: A review Anal. Chim. Acta 859 1–19
Yadav S, Zhu Z, Singh C V 2014 Defect engineering of graphene for effective hydrogen storage Int. J. Hydrog. Ener. 39 4981–95
Terrones M, Botello-Mendez A R, Campos-Delgado J, Lopez-Urias F, Vega-Cantu Y I, Rodriguez-Macias F J, Elias A. L, Munoz-Sandoval E, Cano-Marquez A G, Charlier J C, Terrones H 2010 Graphene and graphite nanoribbons: Morphology, properties, synthesis, defects and applications, Nano Today 5 351–72
Liu X Y, Zhang J M, Xu K W, Ji V 2014 Improving SO2 gas sensing properties of graphene by introducing dopant and defect: A first-principles study Appl. Surf. Sci. 313 405–10
Li T, Tang X, Liu Z, Zhang P 2011 Effect of intrinsic defects on electronic structure of bilayer graphene: First-principles calculations Physica E 43 1597–601
Bitzek E, Gumbsch P 2013 Mechanisms of dislocation multiplication at crack tips Acta Mater. 61 1394–403
Bonilla L L, Carpio A 2012 Driving dislocations in graphene Science 337 161–2
Yazyev O V, Louie S G 2010 Topological defects in graphene: Dislocations and grain boundaries Phys. Rev. B Condens. Matter 81 195420
Mohammadi N, Adeh N B, Najafi M 2016 Synthesis and characterization of highly defective mesoporous carbon and its potential use in electrochemical sensors RSC Adv. 6(40) 33419–25
Huang H, Ying Y, Peng X 2014 Graphene oxide nanosheet: an emerging star material for novel separation membranes J. Mater. Chem. A 2 13772–82
Nishihara H, Kyotani T Templated nanocarbons for energy storage 2012 Adv. Mater. 24, 4473–98
Zhou M, Guo S 2015 Electrocatalytic Interface Based on Novel Carbon Nanomaterials for Advanced Electrochemical Sensors ChemCatChem 7(18) 2744–64
Zhai Y, Zhu Z, Dong S 2015 Carbon-Based Nanostructures for Advanced Catalysis ChemCatChem 7 2806–15
Vicarelli L, Heerema S J, Dekker C, Zandbergen H W 2015 Controlling Defects in Graphene for Optimizing the Electrical Properties of Graphene Nanodevices AcsNano 9 3428–35
Lim D H, Wilcox J 2012 Mechanisms of the Oxygen Reduction Reaction on Defective Graphene-Supported Pt Nanoparticles from First-Principles J. Phys. Chem. C 116 3653–60
Zhong J H, Zhang J, Jin X, Liu J Y, Li Q, Li M H, Cai W, Wu D Y, Zhan D, Ren B 2014 Quantitative Correlation between Defect Density and Heterogeneous Electron Transfer Rate of Single Layer Graphene J.Am Chem. Soc 136 16609–17
Kamiya K, Hashimoto K, Nakanishi S 2014 Graphene Defects as Active Catalytic Sites that are Superior to Platinum Catalysts in Electrochemical Nitrate Reduction ChemElectroChem 1 858–62
Ren T Z, Liu L, Zhang Y, Yuan Z Y 2013 Direct electrocatalytic and simultaneous determination of purine and pyrimidine DNA bases using novel mesoporous carbon fibers as electrocatalyst J Solid State Electrochem 17 927–35
Hosseinia H, Behbahania M, Mahyaria M, Kazeroonib H, Bagheria A, Shaabania A 2014 Ordered carbohydrate-derived porous carbons immobilized gold nanoparticles as a new electrode material for electrocatalytical oxidation and determination of nicotinamide adenine dinucleotide Biosensors and Bioelectronics 59 412–7
Liu Y, Lia Y, He X 2014 In situ synthesis of ceria nanoparticles in the ordered mesoporous carbon as a novel electrochemical sensor for the determination of hydrazine Anal. Chim. Acta 819 26–33
Gadipelli S, Guo Z X 2015 Graphene-based materials: Synthesis and gas sorption, storage and separation Progress in Materials Science 69 1–60
Zuttel A, Sudan P, Mauron P, Wenger P 2004 Model for the hydrogen adsorption on carbon nanostructures Appl Phys A 78 941–6
Burress J W, Gadipelli S, Ford J, Simmons J M, Zhou W, Yildirim T 2010 Graphene oxide framework materials: theoretical predictions and experimental results Angew Chem Int Ed 49 8902–4
Kubas J 2001 Metal-dihydrogen and r-bond coordination: the consummate extension of the Dewar-Chatt-Duncanson model for metal-olefin p bonding J Organomet Chem 635 37–68
Hussain T, Pathak B, Ramzan M, Maark TA, Ahuja R 2012 Calcium doped graphane as a hydrogen storage material Appl Phys Lett 100 183902
Miura Y, Kasai H, Dino W, Nakanishi H, Sugimoto T 2003 First principles studies for the dissociative adsorption of H2 on graphene J Appl Phys 93 3395–400
Chen J J, Li W W, Li X L, Yu H Q 2012 Improving biogas separation and methane storage with multilayer graphene nanostructure via layer spacing optimization and lithium doping: a molecular simulation investigation Environ Sci Technol 46 10341–8
Katsnelson M I, Fasolino A 2013 Graphene as a prototype crystalline membrane. Acc Chem Res 46 97–105
Leenaerts O, Partoens B, Peeters F M Graphene: a perfect nanoballoon 2008 Appl Phys Lett 93 193107
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Shunin, Y., Bellucci, S., Gruodis, A., Lobanova-Shunina, T. (2018). Graphene, Fullerenes, Carbon Nanotubes: Electronic Subsystem. In: Nonregular Nanosystems. Lecture Notes in Nanoscale Science and Technology, vol 26. Springer, Cham. https://doi.org/10.1007/978-3-319-69167-1_8
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DOI: https://doi.org/10.1007/978-3-319-69167-1_8
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