Abstract
The operation of thermochemical heat storage devices in open mode by permeating a reactive porous body or particle bed by a compressible heat-transfer fluid which in turn transports a reactive fluid component constitutes a strongly coupled problem of multiple physical processes. High reaction rates associated with a rapid release of significant amounts of heat and a complicated dependence of processes and material properties on the physical and chemical state of the system add to the level of complexity. It is the purpose of this chapter to (i) define a suitable benchmark for a suitable process model and (ii) perform such a comparison by using the simulation platforms OpenGeoSys, DuMux and ANSYS Fluent.
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Notes
- 1.
The source term formulations have been modified in an updated model formulation which will be presented in a follow-up publication of this chapter within this series.
- 2.
A current implementation using different source-term formulations and a modification of the reaction enthalpy by the volume work suited for the formulation of the energy balance as implemented in DuMux provides results that match the results of the other codes more closely. The specifics require further testing, the results of which will be published as a separate chapter within this book series.
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Nagel, T., Ostermeier, P., Seitz, G., Class, H., Helmig, R. (2018). THC-Processes. In: Kolditz, O., Nagel, T., Shao, H., Wang, W., Bauer, S. (eds) Thermo-Hydro-Mechanical-Chemical Processes in Fractured Porous Media: Modelling and Benchmarking. Terrestrial Environmental Sciences. Springer, Cham. https://doi.org/10.1007/978-3-319-68225-9_12
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DOI: https://doi.org/10.1007/978-3-319-68225-9_12
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