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Studies on the Physical, Mechanical, Thermal and Morphological Properties of Impregnated Furfuryl Alcohol-co-Glycidyl Methacrylate/Nanoclay Wood Polymer Nanocomposites

  • M. R. RahmanEmail author
  • J. C. H. Lai
  • S. Hamdan
Chapter
Part of the Engineering Materials book series (ENG.MAT.)

Abstract

In this study, physical, morphological, mechanical, and thermal properties of furfuryl alcohol/glycidyl methacrylate/halloysite nanoclay wood polymer nanocomposites (FA-co-GMA-HNC WPNCs) were investigated. FA-co-GMA-HNC WPNCs were prepared via impregnation method, and the effect of different ratio between the polymers was subsequently investigated. The properties of nanocomposites were characterized using Fourier Transform Infrared Spectroscopy (FT-IR), Scanning Electron Microscopy (SEM), three-point flexural test, dynamic mechanical thermal analysis (DMTA), Thermogravimetric Analysis (TGA), differential Scanning calorimetry (DSC) analysis, and moisture absorption test. The weight percent gain for 50:50 FA-co-GMA-HNC WPNCs was the highest compared to raw wood (RW) and other WPNCs. FT-IR results confirmed the polymerization took place in the nanocomposites especially 50:50 FA-co-GMA-HNC WPNCs with reducing hydroxyl groups. SEM result revealed that the 50:50 FA-co-GMA-HNC WPNCs showed the best surface morphology among all the compositions. Besides, 50:50 FA-co-GMA-HNC WPNCs showed the highest flexural strength and modulus of elasticity. The DMA results revealed that the storage modulus and loss modulus of FA-co-GMA-HNC WPNCs were higher while the tan δ of FA-co-GMA-HNC WPNCs was lower compared to RW. FA-co-GMA-HNC WPNCs exhibited the higher thermal stability through TGA and DSC analysis. 50:50 FA-co-GMA-HNC WPNCs exhibited significantly lower moisture absorption compared to RW. From the analysis, 50:50 FA-co-GMA showed the best compatibility with RW among all the compositions.

Keywords

Morphology Strength Thermal Clay 

Notes

Acknowledgements

The authors would like to acknowledge the financial support from Research and Innovation Management Centre, Universiti Malaysia Sarawak under fund with Grant No. (F02/SpGS/1443/2016/25).

References

  1. Ahmad EEM, Luyt AS, Djokovic V (2013) Thermal and dynamic mechanical properties of bio-based poly(furfuryl alcohol)/sisal whiskers nanocomposites. Polym Bull 70(4):1265–1276CrossRefGoogle Scholar
  2. Aydemir D, Gunduz G, Altuntas E, Ertas M, Sahin HT, Alma AH (2011) Investigating changes in the chemical constituents and dimensional stability of heat-treated hornbeam and uludag fir wood. BioRes 6(2):1308–1321Google Scholar
  3. Baysal E, Yalinkilic M, Altinok M, Sonmezc A, Pekerd H, Colaka M (2007) Some physical, biological, mechanical, and fire properties of wood polymer composite (WPC) pretreated with boric acid and borax mixture. Constr Build Mater 21(9):1879–1885CrossRefGoogle Scholar
  4. Bouhelal S, Cagiao ME, Benachour D, Calleja FJC (2007) Structure modification of isotactic polypropylene through chemical crosslinking: toughening mechanism. J Appl Polym Sci 103(5):2968–2976CrossRefGoogle Scholar
  5. Dong Y, Qin Y, Wang K, Yan Y, Zhang S, Li J, Zhang S (2012) Assessment of the performance of furfurylated wood and acetylated wood: comparison among four fast-growing wood species. BioRes 11(2):3679–3690Google Scholar
  6. Dong Y, Yan Y, Zhang S, Li J (2014) Wood/polymer nanocomposites prepared by impregnation with furfuryl alcohol and nano-SiO2. BioRes 9(4):6028–6040CrossRefGoogle Scholar
  7. Fuller B, Ellis W, Rowell R, US 5605767, 25 Feb 1997Google Scholar
  8. Guigo N, Mija A, Zavaglia R, Vincent L, Sbirrazzuoli N (2009) New insights on the thermal degradation pathways of neat poly(furfuryl alcohol) and poly(furfuryl alcohol)/SiO2 hybrid materials. Polym Degrad Stab 94(6):908–913CrossRefGoogle Scholar
  9. Hamdan S, Talib ZA, Rahman MR, Ahmed AS, Islam MS (2010) Dynamic Young’s modulus measurement of treated and post-treated tropical wood polymer composites (WPC). BioRes 5(1):324–342Google Scholar
  10. Hazarika A, Maji TK (2013) Effect of different crosslinkers on properties of melamine formaldehyde-furfuryl alcohol copolymer/montmorillonite impregnated softwood (Ficus hispida). Polym Eng Sci 53(7):1394–1407CrossRefGoogle Scholar
  11. Kabir MA, Huque MM, Islam MR, Bledzki AK (2010) Mechanical properties of jute fiber reinforced polypropylene composites: Effect of chemical treatment by benzenediazonium salt in alkaline medium. BioRes 5(3):1618–1625Google Scholar
  12. Kakiuchi H (1964) Manufacture and application of epoxy resins. Macromolecule Chemistry Publication Society, KyotoGoogle Scholar
  13. Kherroub DE, Belbachir M, Lamouri S (2015) Synthesis of poly(furfuryl alcohol)/montmorillonite nanocomposites by direct in-situ polymerization. Arabian J Sci Eng 40(1):143–150CrossRefGoogle Scholar
  14. Kunita MH, Girotto EM, Muniz EC, Rubira AF (2006) Polypropylene grafted with glycidyl methacrylate using supercritical CO2 medium. Braz J Chem Eng 23(2):267–271CrossRefGoogle Scholar
  15. Lee SY, Doh GH, Kang IA (2006) Thermal behaviour of hwangto and wood flour reinforced high density polyethylene (HDPE) composites. Mokchae Konghak 34:59–66Google Scholar
  16. Li Y (2011) Wood-polymer composites. Trans Tech Publications Inc., SwitzerlandCrossRefGoogle Scholar
  17. Li Y, Liu Y, Wang X, Wu Q, Yu H, Li J (2011) Wood-polymer composites prepared by in-situ polymerization of monomers within wood. J Appl Polym Sci 119(6):3207–3216CrossRefGoogle Scholar
  18. Liew FK, Hamdan S, Rahman MR, Mahmood MR, Rahman MM, Lai JCH, Sultan MT (2016) 4-methylcatechol-treated jute-bamboo hybrid composites: effects of pH on thermo-mechanical and morphological properties. BioRes 11(3):6880–6895CrossRefGoogle Scholar
  19. Mulinari DR, Voorwald HJC, Cioffi MOH, Rocha GJ, Silva MLCPD (2010) Surface modification of sugarcane bagasse cellulose and its effect on mechanical and water absorption properties of sugarcane bagasse cellulose/HDPE composites. BioRes 5(2):661–671Google Scholar
  20. Pandey K (1999) A study of chemical structure of soft and hardwood and wood polymers by FTIR spectroscopy. J Appl Polym Sci 71(12):1969–1975CrossRefGoogle Scholar
  21. Parshaei S, Hosseinzadeh S (2016) Preparation of organo nanoclay incorporated polyamide/melamine cyanurate/nanoclay composites and study on thermal and mechanical behaviours. Iranian Chem Comm 4:102–114Google Scholar
  22. Pothan LA, George CN, John MJ, Thomas S (2010) Dynamic mechanical and dielectric behaviour of banana-glass hybrid fiber reinforced polyester composites. J Reinf Plastics Compos 29(8):1131–1145CrossRefGoogle Scholar
  23. Pranger LA, Nunnery GA, Tannenbaum R (2012) Mechanism of the nanoparticle-catalyzed polymerization of furfuryl alcohol and the thermal and mechanical properties of the resulting nanocomposites. Compos Part B 43:1139–1146CrossRefGoogle Scholar
  24. Qin Z, Gao Q, Zhang S, Li J (2013) Glycidyl methacrylate grafted onto enzyme-treated soybean meal adhesive with improved wet shear strength. BioRes 8(4):5369–5379CrossRefGoogle Scholar
  25. Rials TG, Glasser WG (1984) Engineering plastics from lignin and enthalpy relaxation of prepolymers. J Wood Chem Technol 4(3):331–345CrossRefGoogle Scholar
  26. Saw SS, Datta C (2009) Thermomechanical properties of jute/bagasse hybrid fibre reinforced epoxy thermoset composites. BioRes 4(4):1455–1476Google Scholar
  27. Singha AS, Thakur VK (2008) Fabrication and study of lignocellulosic hibiscus sabdariffa fiber reinforced polymer composites. BioRes 3(4):1173–1186Google Scholar
  28. Smitinand T, Larsen K (eds) (1984) Flora of Thailand. Royal Forest Department, BangkokGoogle Scholar
  29. Toriz G, Arvidsson R, Westin M, Gatenholm P (2003) Novel cellulose ester-poly(furfuryl alcohol)-flax fiber biocomposites. J Appl Polym Sci 88(2):337–345CrossRefGoogle Scholar
  30. Viet Cao X, Ismail H, Rashid AA, Takeichi T, Vo-Huu T (2011) Mechanical properties and water absorption of kenaf powder filled recycled high density polyethylene/natural rubber biocomposites using mape as a compatibilizer. BioRes 6(3):3260–3271Google Scholar
  31. Wechsler A, Hiziroglu S, Ballerini AA (2008) Some of the properties of wood plastic composites. Paper presented at the proceedings of the 51st International Convention of Society of Wood Science and Technology, Concepcion, Chile, 10–12 Nov 2008Google Scholar
  32. Xue F, Zhao G (2008) Optimum preparation technology for Chinese fir wood/Ca-montmorillonite (Ca-MMT) composite board. Forest Stud Chin 10(3):2581–2590CrossRefGoogle Scholar

Copyright information

© Springer International Publishing AG 2018

Authors and Affiliations

  1. 1.Faculty of EngineeringUniversiti Malaysia SarawakKota SamarahanMalaysia

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