Abstract
Chirality is one of the basic characteristics of biological structures; chirality is a symmetry property. Multi-tori are complex structures consisting of more than one torus, embedded in negatively curved surfaces. Design of multi-tori may be achieved by operations on maps. The “monomers” used to design the chiral multi-tori discussed in this chapter are snubs of Platonic solids. A snub polyhedron s(P) is achieved by dualizing the p 5(P) transform: s(P) = d(p 5(P)); since p 5-operation is prochiral, all the consecutive structures will be chiral; high genus structures of rank k = 3 were thus obtained. The genus and rank (or space dimension) of a structure are parameters of complexity.
Topological symmetry of the structures herein discussed was evaluated by ring signature and centrality index and confirmed by symmetry calculation using the adjacency matrix permutations. C60-related chiral tori were also designed and their symmetry evaluated. An atlas section illustrates the discussed chiral multi-tori.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Babić D, Klein DJ, Schmalz TG (2001) Curvature matching and strain relief in bucky-tori: usage of sp3-hybridization and nonhexagonal rings. J Mol Graph Model 19:223–231
Barborini E, Piseri P, Milani P, Benedek G, Ducati C, Robertson J (2002) Negatively curved spongy carbon. Appl Phys Lett 81:3359–3361
Benedek G, Vahedi-Tafreshi H, Barborini E, Piseri P, Milani P, Ducati C, Robertson J (2003) The structure of negatively curved spongy carbon. Diam Relat Mater 12:768–773
Blatov VA, O’Keeffe M, Proserpio DM (2010) Vertex-, face-, point-, Schläfli-, and Delaney-symbols in nets, polyhedra and tilings: recommended terminology. Cryst Eng Comm 12:44–48
Buckley F (1979) Self-centered graph with given radius. Congr Numer 23:211–215
Buckley F (1989) Self-centered graphs. Ann NY Acad Sci 576:71–78
Diudea MV (1994) Layer matrices in molecular graphs. J Chem Inf Comput Sci 34:1064–1071
Diudea MV, Nagy CL (2007) Periodic nanostructures. Springer, Dordrecht
Diudea MV, Petitjean M (2008) Symmetry in multi-tori. Symmetry Cult Sci 19(4):285–305
Diudea MV, Petitjean M (2016) Chiral multitori as snub derivatives. Rev Roum Chim 61(4–5):329–337
Diudea MV, Rosenfeld VR (2017) The truncation of a cage graph. J Math Chem 55(4):1014–1020. doi:10.1007/s10910-016-0716-6
Diudea MV, Ursu O (2003) Layer matrices and distance property descriptors. Indian J Chem A 42(6):1283–1294
Euler L (1752–1753) Elementa doctrinae solidorum-Demonstratio nonnullarum insignium proprietatum, quibus solida hedris planis inclusa sunt praedita. Novi Comment Acad Sc Imp Petropol 4:109–160
Harary F (1969) Graph theory. Addison-Wesley, Reading
Hargittai M, Hargittai I (2010) Symmetry through the eyes of a chemist. Springer, Dordrecht
Higuchi Y (2001) Combinatorial curvature for planar graphs. J Graph Theory 38:220–229
Janakiraman TN, Ramanujan J (1992) On self-centered graphs. Math Soc 7:83–92
Kelvin L (1904) Baltimore lectures on molecular dynamics and the wave theory of light, Appendix H, Sect. 22, footnote p. 619. C.J. Clay and Sons, Cambridge University Press Warehouse, London
Klein DJ (2002) Topo-combinatoric categorization of quasi-local graphitic defects. Phys Chem Chem Phys 4:2099–2110
Klein DJ, Liu X (1994) Elemental carbon isomerism. Int J Quantum Chem S28:501–523
Lenosky T, Gonze X, Teter M, Elser V (1992) Energetics of negatively curved graphitic carbon. Nature 355:333–335
Lijnen E, Ceulemans A (2005) The symmetry of Dyck graph: group structure and molecular realization. J Chem Inf Model 45(6):1719–1726
Mackay AL, Terrones H (1991) Diamond from graphite. Nature 352:762–762
Meier WM, Olson DH (1992) Atlas of zeolite structure types, 3rd edn. Butterworth-Heineman, London
Nagy CL, Diudea MV (2009) Nano studio software. Babes-Bolyai University, Cluj
Nagy CL, Diudea MV (2017) Ring signature index. MATCH Commun Math Comput Chem 77(2):479–492
Nazeer W, Kang SM, Nazeer S, Munir M, Kousar J, Sehar A, Kwun YC (2016) On center, periphery and average eccentricity for the convex polytopes. Symmetry 8:145–168
Negami S, Xu GH (1986) Locally geodesic cycles in 2-self-centered graphs. Discret Math 58:263–268
Petitjean M (2016) http://petitjeanmichel.free.fr/itoweb.petitjean.freeware.html
Schulte E (1985) Regular incidence-polytopes with Euclidean or toroidal faces and vertex-figures. J Combin Theory A 40(2):305–330
Schulte E (2014) Polyhedra, complexes, nets and symmetry. Acta Crystallographica A 70:203–216
Terrones H, Mackay AL (1997) From C60 to negatively curved graphite. Prog Crystal Growth Charact 34:25–36
Author information
Authors and Affiliations
Chapter 10 Atlas: Chiral Multi-tori
Chapter 10 Atlas: Chiral Multi-tori
10.1.1 Dodecahedron Related Structures
|
|
|
s(D).60 | s(D)@s(D)7S.120 | op(ca(D)).200 |
|
|
|
s(D).60 | Op(Ca(D)).200 | C280,S |
|
|
|
op(ca(D)).200 | C280,S | t(C280).840_cyclic cover |
|
|
|
C280,R | P5.1(C280,R).1240 | s(C280R).840 |
|
|
|
Op(Ca(D)).200 | d(m(C280)).400 | C280,S |
|
|
|
s(D).60_5 | m(C280).420 | C280,S |
|
|
|
s(D).60_5 | op(ca(D)).200 | C280,S |
|
|
|
s(D).60_5 | Op(Ca(D)).200 | d(p 4(C280)820).840 |
|
|
|
op(ca(D)).200 | C280,S | p 4(C280).820 |
10.2 C 60 related structures
|
|
|
s(C60).180 | s(C60)@s(C60)7R.360 A5; Classes 6: |6{60}| | op(ca(C60)).600 |
|
|
|
s(C60).180 | op(ca(C60)).600 | C840,7R |
|
|
|
op(ca(C60)).600 | d(m(C840)).1200_3 | C840,7R_3 |
|
|
|
op(ca(C60)).600_5 | m(C840).1260_3 | C840,7R_3 |
|
|
|
s(C60).180 | op(ca(C60)).600 | C840,R_5 |
|
|
|
op(ca(C60)).600 | C840,R_5 | t(C840).2520_cyclic cover |
Rights and permissions
Copyright information
© 2018 Springer International Publishing AG
About this chapter
Cite this chapter
Diudea, M.V. (2018). Chiral Multi-tori. In: Multi-shell Polyhedral Clusters. Carbon Materials: Chemistry and Physics, vol 10. Springer, Cham. https://doi.org/10.1007/978-3-319-64123-2_10
Download citation
DOI: https://doi.org/10.1007/978-3-319-64123-2_10
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-64121-8
Online ISBN: 978-3-319-64123-2
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)