Abstract
This work discusses the phase behavior of conventional liquids and their binary mixtures in the presence of graphene genealogic tree nanoparticles. An algorithm for evaluation of critical parameters shift after adding the nanoparticles to the pure liquid is applied to estimate critical point of nanofluid. It is argued that dimensionless thermodynamic surfaces of reference liquid and nanofluid with volume nanoparticle concentration less than 5% are coincided. A global phase diagram approach is proposed to evaluate a possible azeotropic states in binary mixtures after nanoparticles doping. The influence of graphene genealogic tree nanoparticles (carbon nanotubes—CNT, fullerenes—C60, and graphene flakes) on the liquid–liquid equilibria is discussed. The change in location of upper critical end point (UCEP) for liquid–liquid coexistence curve of the mixture of nitrobenzene and heptane and system of nitrobenzene, heptane and graphene genealogic tree nanoparticles is predicted.
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References
R.L. Smith Jr., Z. Fang, Properties and phase equilibria of fluid mixtures as the basis for developing green chemical processes. Fluid Phase Equilib. 302, 65–73 (2011)
C. King, D. Pendlebury, WEB of knowledge— “research fronts 2013” (2013), http://sciencewatch.com/sites/sw/files/sw-article/media/research-fronts-2013.pdf
S.A. Angayarkanni, J. Philip, Review on thermal properties of nanofluids: recent developments. Adv. Coll. Interface. Sci. 225, 146–176 (2015)
Y. Prylutskyy, S. Durov, L. Bulavin, et al., Structure and thermophysical properties of fullerene C60 aqueous solutions. Int. J. Thermophys. 22(3) (2001)
D. Nikitin, V. Mazur, Thermodynamic and phase behaviour of fluids embedded with nanostructured materials. Int. J. Therm. Sci. 62, 44–49 (2012)
S. Artemenko, V. Mazur, O. Vasilieva, Thermodynamic and phase behavior of nanofluids, in Proceedings in Physics, (Springer, 2015), pp. 313–333
E. Lemmon, R. Span, Short fundamental equations of state for 20 industrial fluids. J. Chem. Eng. Data 51, 785 (2006)
R. Span, W. Wagner, A new equation of state for carbon dioxide covering the fluid region from the triple‐point temperature to 1100 K at pressures up to 800 Mpa. J. Phys. Chem. Ref. Data 25(6), 1509 (1996)
J. Avsec, M. Oblak, The calculation of thermal conductivity, viscosity and thermodynamic properties for nanofluids on the basis of statistical nanomechanics. Int. J. Heat Mass Trans. 50(21–22), 4331 (2007)
G. Soave, Equilibrium constants from a modified Redlich-Kwong equation of state. Chem. Eng. Sci. 27, 1197–2003 (1972)
S. Artemenko, V. Mazur, Azeotropy in the natural and synthetic refrigerant mixtures. Int. J. Refrig 30, 831–839 (2007)
U.K. Deiters, J.L. Pegg, Systematic investigation of the phase behavior of binary fluid mixtures. I. Calculations based on the Redlich-Kwong equation of state. J. Chem. Phys. 90, 6632–6641 (1989)
E. Lemmon, M. Huber, M. McLinden, NIST reference fluid thermodynamic and transport properties—REFPROP. version 9.1. (NIST, Boulder, 2013)
P.V. Borzenkov, V.P. Zhelezny, The nanoparticles effect on the liquid–liquid phase equilibrium parameters. Part1. Refrig. Eng. Technol. 6, 4–9 (2014)
J. Shelton, D. Balzarini, Coexistence curve of the binary fluid nitrobenzene–heptane. Can. J. Phys. 59, 334 (1981)
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Artemenko, S., Karnaukh, V., Mazur, V. (2018). Phase Behavior of Liquids Embedded with Graphene Genealogic Tree Nanoparticles. In: Bulavin, L., Chalyi, A. (eds) Modern Problems of Molecular Physics. Springer Proceedings in Physics, vol 197. Springer, Cham. https://doi.org/10.1007/978-3-319-61109-9_3
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DOI: https://doi.org/10.1007/978-3-319-61109-9_3
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