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Detection and Control of Charge State in Single Molecules Toward Informatics in Molecule Networks

  • Seiya KasaiEmail author
  • Shinya Inoue
  • Syoma Okamoto
  • Kentaro Sasaki
  • Xiang Yin
  • Ryota Kuroda
  • Masaki Sato
  • Ryo Wakamiya
  • Kenta Saito
Conference paper
Part of the Advances in Atom and Single Molecule Machines book series (AASMM)

Abstract

One of the key components in the single-molecule-based informatics is the interface between the single-molecule and the conventional electronics. This component reads out the very small charge state of the molecule in real time and also controls the charge state. A big challenge here is the precise operation under various fluctuations. In this chapter, we describe our recent results on detection of molecule charge state using a III-V compound semiconductor nanowire field-effect transistor (FET) having a metal gate electrode. It is found that the metal gate enhances the sensitivity to the molecule charge in an electrostatic manner. The dynamics of the molecule charge state is detected in terms of the drain current noise. Our unique technique is applied to single-molecule identification and detection of spatial distribution of charges in a molecular network. Representation of information by controlling the molecule charge state under thermal fluctuation through the nonlinearity under the detailed balance condition is also discussed.

Notes

Acknowledgements

The authors sincerely thank Prof. S. W. Hwang of Korea University, Prof. T. Ogawa of Osaka University, Dr. M. Akai of Osaka University, and Dr. Z. Yatabe of Kumamoto University for valuable discussion. This work was partly supported by a Grant-in-Aid for Scientific Research on Innovative Areas “Molecular Architectonics: Orchestration of Single Molecules for Novel Functions” (No. 25110001, No. 25110013).

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Copyright information

© Springer International Publishing AG 2017

Authors and Affiliations

  • Seiya Kasai
    • 1
    Email author
  • Shinya Inoue
    • 1
  • Syoma Okamoto
    • 1
  • Kentaro Sasaki
    • 1
  • Xiang Yin
    • 1
  • Ryota Kuroda
    • 1
  • Masaki Sato
    • 1
  • Ryo Wakamiya
    • 1
  • Kenta Saito
    • 1
  1. 1.Research Center for Integrated Quantum Electronics and Graduate School of Information Science & TechnologyHokkaido UniversitySapporoJapan

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