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Synthesis of Conjugated Polyrotaxanes and Its Application to Molecular Wires

  • Jun TeraoEmail author
Conference paper
Part of the Advances in Atom and Single Molecule Machines book series (AASMM)

Abstract

A new method for the synthesis of an insulated π-conjugated molecule as a powerful building block for the construction of a insulated molecular wire (IMW) was developed via the sequential self-inclusion of π-conjugated guest-branched permethylated α-cyclodextrin followed by the elongation of the π-conjugated unit. Covering a single π-conjugated wire by an α-cyclodextrin derivatives can suppress conductance fluctuation. The insulated π-conjugated molecules were utilized in the synthesis of highly conductive zigzag- and functionalized insulated molecular wires.

Keywords

Insulated molecular wires Polyrotaxane Permethylated cyclodextrin Charge mobility 

Notes

Acknowledgements

I greatly acknowledge the experimental and intellectual contribution of my coworkers listed in the references that have made possible the research described herein.

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Authors and Affiliations

  1. 1.Department of Basic Science, Graduate School of Art and SciencesThe University of TokyoBunkyoJapan

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