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Synthesis of Conjugated Polyrotaxanes and Its Application to Molecular Wires

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Book cover Molecular Architectonics

Part of the book series: Advances in Atom and Single Molecule Machines ((AASMM))

Abstract

A new method for the synthesis of an insulated π-conjugated molecule as a powerful building block for the construction of a insulated molecular wire (IMW) was developed via the sequential self-inclusion of π-conjugated guest-branched permethylated α-cyclodextrin followed by the elongation of the π-conjugated unit. Covering a single π-conjugated wire by an α-cyclodextrin derivatives can suppress conductance fluctuation. The insulated π-conjugated molecules were utilized in the synthesis of highly conductive zigzag- and functionalized insulated molecular wires.

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Acknowledgements

I greatly acknowledge the experimental and intellectual contribution of my coworkers listed in the references that have made possible the research described herein.

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  1. Department of Basic Science, Graduate School of Art and Sciences, The University of Tokyo, Bunkyo, Tokyo, 153–8902, Japan

    Jun Terao

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  1. Jun Terao
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Correspondence to Jun Terao .

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  1. Department of Chemistry, Graduate School of Science, Osaka University, Osaka, Japan

    Takuji Ogawa

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Terao, J. (2017). Synthesis of Conjugated Polyrotaxanes and Its Application to Molecular Wires. In: Ogawa, T. (eds) Molecular Architectonics. Advances in Atom and Single Molecule Machines. Springer, Cham. https://doi.org/10.1007/978-3-319-57096-9_20

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