Abstract
In many technical fields a contact between two surfaces is very important and often the subject of research. The numerous physical phenomena that occur at the contact between two materials indicate the complexity of the processes that take place at the macro, micro or nanoscale. Therefore, friction, lubrication and wear are the subjects that have been attracting attention for many years, especially as part of tribological investigations. The research has shown that these three components are of fundamental importance for surfaces in contact. The aim of this chapter is to primarily describe friction as a tribological component and lubrication as a process to control friction, at scales of various lengths, especially at the atomic level. At the atomic and molecular scale there are materials with the property to spontaneously assemble themselves into ordered structures and many surface properties are influenced by the formation of such a film. One of the procedures to make these ultrathin organic films of controlled thickness is to prepare self-assembled monolayers. These monolayers are described as a model system to study boundary lubrication.
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References
Abe K, Takiguchi H, Tamada K (2000) Dynamic contact angle measurement of Au (111)-thiol self-assembled monolayers by the Wilhelmy plate method. Langmuir 16(5):2394–2397
Adams BJ, Hector LG Jr, Siegel DJ et al (2001) Adhesion, lubrication and wear on the atomic scale. Surf Interface Anal 31:619–626
Allen M (2004) Introduction to molecular dynamics simulation. NIC Ser 23:1–28
Beaumont N, Hancox I, Sullivan P et al (2011) Increased efficiency in small molecule organic photovoltaic cells through electrode modification with self-assembled monolayers. Energy Environ Sci 4:1708–1711
Beer S, Kenmoe GD, Muser MH (2015) On the friction and adhesion hysteresis between polymer brushes attached to curved surfaces: rate and solvation effects. Friction 3(2):148–160
Berman D, Krim J (2013) Surface science, MEMS and NEMS: progress and opportunities for surface science research performed on, or by, microdevices. Prog Surf Sci 88:171–211
Bhushan B, Israelachvili JN, Landman U (1994) Nanotribology: friction, wear and lubrication at the atomic scale. Nature 374:607–616
Bhushan B, Kulkarni AV (1996) Effect of normal load on microscale friction measurements. Thin Solid Films 278:49–56
Bhushan B (2001) Modern tribology handbook. CRC Press, New York
Biswas S, Ray P, Chakrabarti BK (2015) Statistical physics of fracture, breakdown, and earthquake: effects of disorder and heterogeneity. Wiley-VCH Verlag GmbH & Co, KGaA
Blau PJ (2008) Friction science and technology: from concepts to applications. CRC Press
Bowden FP, Tabor D (1938) The area of contact between stationary and between moving surfaces. In: Proceedings of the royal society of London. Ser A, Math Phys Sci: 391–413
Braun OM, Kivshar YS (2004) The frenkel-kontorova model. Springer, Berlin
Braun O (2005) Nanotribology: mechanisms of friction on the atomic scale, printing material. Kiev, Ukraine
Braun OM, Naumovets AG (2006) Nanotribology: microscopic mechanisms of friction. Surf Sci Rep 60:79–158
Broitman E (2014) The nature of the frictional force at the macro-, micro-, and nano-scales. Friction 2(1):40–46
Brovelli D, Hahner G, Ruiz L et al (1999) Highly oriented, self-assembled alkane phosphate monolayers on tantalum (V) oxide surfaces. Langmuir 15(13):4324–4327
Carpick RW, Salmeron M (1997) Scratching the surface: fundamental investigations of tribology with atomic force microscopy. Chem Rev 97(4):1163–1194
Chaki NK, Vijayamohanan K (2002) Self-assembled monolayers as a tunable platform for biosensor applications. Biosens Bioelectron 17(1–2):1–12
Charitidis CA, Koumoulos EP, Dragatogiannis DA (2013) Nanotribological behavior of carbon based thin films: friction and lubricity mechanisms at the nanoscale (review). Lubricants 1:22–47
Chen YL, Israelachvili JN (1992) Effects of ambient conditions on adsorbed surfactant and polymer monolayers. J Phys Chem 96(19):7752–7760
Clear SC, Nealey PF (2001) Lateral force microscopy study of the frictional behavior of self-assembled monolayers of octadecyltrichlorosilane on silicon/silicon dioxide immersed in n-alcohols. Langmuir 17(3):720–732
Crone W (2008) A brief introduction to MEMS and NEMS. Springer handbook of experimental solid mechanics. Springer Science + Business Media, New York, pp. 203–228
Dedkov GV (2000) Nanotribology: experimental facts and theoretical models. Physics Uspekhi 43(6):541–572
Doudevski I, Schwartz DK (2000) Mechanisms of self-assembled monolayer desorption determined using in situ atomic force microscopy. Langmuir 16(24):9381–9384
Doudevski I, Schwartz DK (2001a) Self-assembled monolayers in the context of epitaxial film growth. Appl Surf Sci 175:17–26
Doudevski I, Schwartz DK (2001b) Concentration dependence of self-assembled monolayer island nucleation and growth. J Am Chem Soc 123(28):6867–6872
Egberts P, Carpick RW (2013) Friction at the Atomic Scale. Physics 6:102
Filipponi L, Sutherland D (2010) NANOYOU. International Nanoscience Center (iNANO), Aarhus University
Gawali AL, Kumawat SC (2011) Nanotribology. Int J Adv Eng Technol 2:300–310
Gebeshuber IC, Drack M, Scherge M (2008) Tribology in biology. Tribology 2(4):200–212
Gnecco E, Meyer E (2007) Fundamentals of friction and wear. Springer, Berlin
Grosse I, Estel K (2000) Thin surfactant layers at the solid interface. Colloid Polym Sci 278(10):1000–1006
Hahner G, Spencer N (1998) Rubbing and scrubbing. Phys Today 22–27
Hironaka S (1984) Boundary lubrication and lubricants. Three Bond Technical News 1(9):1–8
Holscher H, Schirmeisen A, Schwarz U (2008) Principles of atomic friction: from sticking atoms to superlubric sliding. Phil Trans R Soc A 366:1383–1404
Hsu S (2004a) Molecular basis of lubrication. Tribol Int 37(7):553–559
Hsu S (2004b) Nano-lubrication: concept and design. Tribol Int 37:537–545
Hsu S, Ying C, Zhao F (2014) The nature of friction: a critical assessment. Friction 2(1):1–26
Hu YZ, Granick S (1998) Microscopic study on thin film lubrication and its contributions to macroscopic tribology. Tribol Lett 5:81–88
Hyun-Joon K, Dae-Eun K (2009) Nano-scale friction: a review. Int J Precisi Eng Manuf 10(2):141–151
Israelachvili J, Tabor D (1973) Van der Waals forces: theory and experiment. Prog Surf Membr Sci 7:1–55
Jun Z, Yonggang M (2015) Boundary lubrication by adsorption film. Friction 3(2):115–147
Kim H, Kim E (2009) Nano-scale friction a review. Int J Precis Eng Manuf 10(2):141–151
Kopta S (2001) Nanometer scale friction and wear on self-assembled monolayers investigated by atomic force microscopy. Dissertation, University Basel
Krilov SY, Frenken WM (2014) The physics of atomic-scale friction: basic considerations and open questions (review article). Phys Status Solid B 251(4):711–736
Krim J (1996) Atomic-scale origins of friction. Langmuir 12:4564–4566
Krim J (2002a) Resource letter: FMMLS-1: friction at macroscopic and microscopic length scales. Am J Phys 70(9):890–897
Krim J (2002b) Surface science and the atomic-scale origins of friction: what once was old is new again. Surf Sci 500:741–758
Krim J (2012) Friction and energy dissipation mechanisms in adsorbed molecules and molecularly thin films (review). Adv Phys 61(3):155–323
Krim J, Solina DH, Chiarello R (1991) Nanotribology of a Kr monolayer: a quartz-crystal microbalance study of atomic-scale friction. Phys Rev Lett 66:181–184
Kumar B, Kumar KB, Negi YS (2014) Organic thin film transistors: structures, models, materials, fabrication, and applications: a review. Polym Rev 54:33–111
Liu M, Lu Y, Zhang J et al (2009) MEMS/microelectronics self-assembly based on analogy of Langmuir-Blodgett approach. Microelectron Eng 86(11):2279–2282
Lue JT (2007) Physical properties of nanomaterials. Encycl Nanosci Nanotechnol X:1–46
Manojlovic J (2006) Structure, morphology and history effects in surfactant self-assembly. Dissertation, ETH Zuerich
Manojlovic J (2010) Friction and lubrication at the atomic level. In: Paper presented at the international conference, mechanical engineering in XXI century, MASING 2010, University of Niš, Serbia, 25–26 Nov 2010
Manojlovic J (2012) The Krafft temperature of surfactant solutions. Thermal Sci 16(2):S633–S642
Manojlovic J (2013) Self-assembled monolayers in lubrication on atomic level. In: The 2nd international conference, mechanical engineering in XXI century, faculty of mechanical engineering, Nis, Serbia, 20–21 June 2013
Manojlovic J (2013) Preparation and characterization of quaternary ammonium surfactants on muscovite mica. SERBIATRIB 2013. In: 13th international conference on tribology faculty of engineering, Kragujevac, 15–17 May 2013
Manojlovic J, Milojevic A, Tomic M et al (2015) Tribology in micromechatronical devices. In: SERBIATRIB, 2015, 14th international conference on tribology, Belgrade, 13–15 May 2015
Mate MC, McClelland MG, Erlandsson et al (1987) Atomic-scale friction of a tungsten tip on a graphite surface. Phys Rev Lett 59(17):1942–1946
Mathew CM (2008) Tribology on the small scale. Oxford University Press Inc., New York
Mattias L (2008) Self lubrication on the atomic scale design. Dissertation, Uppsala University
Matsumoto K (2003) Surface chemical and tribological investigations of phosphorus-containing lubricant additives. Dissertation, ETH Zuerich
Mellott M, Hayes W, Schwartz DK (2004) Kinetics of octadecyltrimethylammonium bromide self-assembled monolayer growth at mica from an aqueous solution. Langmuir 20(6):2341–2348
Miyake K, Kume T, Nakano M et al (2012) Effects of surface chemical properties on the frictional properties of self-assembled monolayers lubricated with oleic acid. Tribol Online 7(4):218–224
Mo Y, Turner KT, Szlufaraska I (2009) Friction laws at the nanoscale. Nature 457:1116–1119
Mowat I, Moskito J, Ward I et al (2007) Analytical methods for nanotechnology. NSTI-Nanotech 4:20–23
Popova E, Popov LV (2015) The research works of Coulomb and Amontons and generalized laws of friction. Friction 3(2):183–190
Quing Z, Qi Y, Hector LG et al (2007) Origin of static friction and its relationship to adhesion at the atomic scale. Phys Rev B 75(144114):1–7
Rajkumar G, Sethuraman MG (2014) Corrosion protection ability of self-assembled monolayer of 3-amino-5-mercapto-1, 2, 4-triazole on copper electrode. Thin Sold Films 562:32–36
Ramanpreet S, Sreedhar M (2014) Bio-tribology and its applications in medical sciences-a review. Int J Mech Eng Rob Res 3(3):141–144
Ratner M, Ratner D (2006) Nanotechnology. Pearson Education, Inc
Riedoa E, Brune H (2003) Young modulus dependence of nanoscopic friction coefficient in hard coatings. Appl Phys Lett 83(10):1986–1988
Rymuza Z (2010) Advanced techniques for nanotribological studies. Sci Probl Mach Oper Maint 1(161):33–43
Scherge M, Schaefer JA (1998) Microtribological investigations of stick/slip phenomena using a novel oscillatory friction and adhesion tester. Tribol Lett 4:37–42
Schmid G, Corain B (2003) Nanoparticulated gold: syntheses, structures, electronics, and reactivities. Eur J Inorg Chem 17:3081–3098
Shivaprakash NR (2013) Adhesion and tribology on well-defined, nano-scale rough surfaces: a gradient approach. Dissertation, ETH Zuerich
Singer IL (1994) Friction and energy dissipation at the atomic scale: a review. J Vac Sci Technol A 12(5):2605–2616
Singh A, Suh K (2013) Biomimetic patterned surfaces for controllable friction in micro- and nanoscale devices. Micro Nano Syst Lett 1:6
Sokoloff J (2003) A mechanism for lubrication between surfaces with atomic level roughness. Physics Faculty Publications. Paper 4, Northeastern University, Boston
Somers EA, Howlett PC, MacFarlane DR et al (2013) A review of ionic liquid lubricants. Lubricants 1:3–21
Spikes H (1996) Direct observation of boundary layers. Langmuir 12:4567–4573
Spikes H (2001) Tribology research in the twenty-first century. Tribol Int 34:789–799
Sung IH, Lee HS, Kim DE (2003) Effect of surface topography on the frictional behavior at the micro/nano-scale. Wear 254:1019–1031
Szlufarska I, Chandross M, Carpick RW (2008) Recent advances in single-asperity nanotribology (topical review). J Phys D Appl Phys 41(123001):1–39
Taylor RI (2012) Tribology and energy efficiency: from molecules to lubricated contacts to complete machines. Royal Soc Chem Faraday Discuss 156:361–382
Theodore L (2006) Nanotechnology: basic calculations for engineers and scientists. Wiley, New York
Ulman A (2013) An introduction to ultrathin organic films: from Langmuir-Blodgett to self- assembly. Academic Press
Urbakh M, Krafter J, Gourdon D et al (2004) The nonlinear nature of friction. Nature 430:525–528
Vakarelski IU, Brown SC, Rabinovich YI et al (2004) Lateral force microscopy investigation of surfactant-mediated lubrication from aqueous solution. Langmuir 20(5):1724–1731
Vanossi A, Manini N, Urbakh M et al (2013) Modeling friction: from nano to meso scales. Rev Mod Phys 85(2):529–552
Wang Z-J, Ma T-B, Hu Y-Z et al (2015) Energy dissipation of atomic-scale friction based on onedimensional Prandtl-Tomlinson model. Friction 3(2):170–182
Weymouth AJ, Meuer D, Wutscher MT et al (2013) Atomic structure affects the directional dependence of friction. Phys Rev Lett 111(126103):1–4
Widmer M (2002) Modified molecular friction in artificial hip joints. Dissertation, ETH Zurich
Williams L (2007) Nanotechnology demystified. McGraw-Hill Companies
Xuan Z (2014) Molecular dynamics simulation of boundary lubricated contacts. Dissertation, University of Wollongong
Xue Y, Li X, Li H et al (2014) Quantifying thiol–gold interactions towards the efficient strength control. Nat Commun 5:4348. doi:10.1038/ncomms5348
Yang C (2008) Role of surface roughness in tribology: from atomic to macroscopic scale. Dissertation, Berlin
Yang Y, Singh J, Ruths M (2014) Friction of aromatic thiol monolayers on silver: SFA and AFM studies of adhesive and non-adhesive contacts. Royal Soc Chem 4:18801–18810
Zana R (2005) Dynamics of surfactant self-assemblies. CRC Press, Taylor & Francis
Zhang J (2012) Nanotribological and nanomechanical investigation of nanomaterials. Dissertation, Rice University
Zhang J, Meng Y (2015) Boundary lubrication by adsorption film. Friction 3(2):115–147
Zhang Q, Qi Y, Hector LG et al (2007) Origin of static friction and its relationship to adhesion at the atomic scale. Phys Rev B 75(144114):1–7
Zimmerli L, Nuller F, Hidber H-R et al (2005) Exploring the nano-world: friction and light at the nanometer scalenano3d visualization. http://nano-world2.cs.unibas.ch/Events/nmt-master/doc.pdf
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Manojlović, J. (2018). Friction at Nanoscale—Self-assembled Monolayers. In: Brabazon, D., et al. Commercialization of Nanotechnologies–A Case Study Approach. Springer, Cham. https://doi.org/10.1007/978-3-319-56979-6_7
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