Abstract
Samples of the ternary system (Bi1−x−y Pbx+y)(Fe1−x/2−y Ti y Nb x/2)O3 (sections y = 0.10 with 0.175 ≤ x ≤ 0.325 and x = 0.05 with 0.175 ≤ y ≤ 0.325) were obtained by the solid-phase reactions method with following conventional ceramic technology sintering. Optimal regulations of synthesis and sintering of these materials were determined. It is shown that the obtained objects have a complex phase structure affecting both on microstructure and on macroresponses of studied samples. For one of the studied section were measured dielectric properties in a wide temperature and frequency ranges. Explanation of the observed effects from the viewpoint of crystal-chemical disorder and morphotropic areas evolution in the ceramic structures was proposed.
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Acknowledgements
The work was supported by the Ministry of Education of the Russian Federation: the themes Nos. 1927, 213.01-2014/012-IG and 3.1246.2014/K. It was used equipment of CCU “Electromagnetic, Electromechanical and Thermal Properties of Solids” of the Physics Research Institute, Southern Federal University.
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Glazunova, E.V., Boldyrev, N.A., Shilkina, L.A., Reznichenko, L.A., Nagaenko, A.V., Andryushina, I.N. (2017). Structure, Grains Structure and Dielectric Responses of the Ternary System Solid Solutions (Bi1−X−Y Pb x+Y )(Fe1−X/2−Y Ti y Nb x/2)O3 . In: Parinov, I., Chang, SH., Jani, M. (eds) Advanced Materials. Springer Proceedings in Physics, vol 193. Springer, Cham. https://doi.org/10.1007/978-3-319-56062-5_16
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