Abstract
Mössbauer studies of PbFe0.5Nb0.5O3 samples prepared by mechanical activation of PbO, Fe2O3 and Nb2O5 mixture and subsequent sintering at various temperatures T S were performed. The room temperature Mössbauer spectra consist of two doublets (D1 and D2) for the samples with T S < 800 °C and one doublet (D1) for the samples with T S > 800 °C. The parameters of the doublet D1 correspond to Fe3+ in the octahedron environment. Doublet D2 has a lower isomer shift corresponding to Fe3+ with the coordination number 5 that indicates the presence of oxygen vacancies. Dependence of the temperature T N of magnetic phase transition on T S has a maximum at T S ≈ 700 °C. The effect of Fe3+/Nb5+ ordering degree and oxygen deficiency on T N is discussed.
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Acknowledgements
This work was partially supported by Ministry of Education and Science of the Russian Federation (Research project No. 3.5346.2017/BP), Russian Foundation for Basic Research (project 17–03–01293_a) and Research Committee of the University of Macau under Research & Development Grant for Chair Professor No RDG007/FST-CHD/2012.
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Kubrin, S.P. et al. (2017). Mössbauer Study of the Effect of Mechanical Activation on the Magnetic Properties of PbFe0.5Nb0.5O3 . In: Parinov, I., Chang, SH., Jani, M. (eds) Advanced Materials. Springer Proceedings in Physics, vol 193. Springer, Cham. https://doi.org/10.1007/978-3-319-56062-5_14
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