Crystal Structure, Phase and Elemental Composition and Chemical Bonding in Bi1−X A X FeO3±Y Systems (A = Sr, Ca; 0 ≤X ≤ 1) from X-ray Diffraction, Mössbauer, and X-ray Photoelectron Spectra

Kozakov, A. T.; Kochur, A. G.; Torgashev, V. I.; Kubrin, S. P.; Trotsenko, V. G.; Bush, A. A.; Nikolskii, A. V.

doi:10.1007/978-3-319-56062-5_13

A. T. Kozakov⁴,
A. G. Kochur⁵,
V. I. Torgashev⁶,
S. P. Kubrin⁴,
V. G. Trotsenko^6,7,
A. A. Bush⁸ &
…
A. V. Nikolskii⁴

Part of the book series: Springer Proceedings in Physics ((SPPHY,volume 193))

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Abstract

An integrated study of samples of Bi_1−x A _xFeO_3±y (A = Sr, Ca) systems for 0 ≤ x ≤ 1 (step 0.1) is performed using X-ray diffraction (XRD), Mössbauer spectroscopy (MS), and X-ray photoelectron spectroscopy (XPS). Considerable deviations of actual elemental compositions from nominal ones in the samples of both systems are discovered. Both Fe³⁺ and Fe⁴⁺ ions are found to be present in the samples of the Bi_1−xSr_xFeO_3±y system with x > 0. No Fe⁴⁺ ions are discovered upon substitution of Bi³⁺ by Ca²⁺ in Bi_1−xCa_xFeO_3±y, neither by Mössbauer spectroscopy, nor by XPS. Charge compensation in Bi_1−xCa_xFeO_3±y takes place mostly via creation of oxygen vacancies.

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Acknowledgements

This study was supported by the Ministry of Education and Science of Russian Federation (grants Nos. 3.6105.2017/BCh, 3.5346.2017/BCh, and RFMEFI60714X0110).

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Authors and Affiliations

Scientific Research Institute of Physics, Southern Federal University, 194 Stachki Avenue, Rostov-on-Don, 344090, Russia
A. T. Kozakov, S. P. Kubrin & A. V. Nikolskii
Rostov State Transport University, 2, Narodnogo Opolcheniya Square, Rostov-on-Don, 344038, Russia
A. G. Kochur
Faculty of Physics, Southern Federal University, Rostov-on-Don, 344006, Russia
V. I. Torgashev & V. G. Trotsenko
Laboratory of Condensed Matter Physics, University of Picardy, Amiens, 80039, France
V. G. Trotsenko
Moscow State Technical University of Radio Engineering, Electronics and Automation, Moscow, 119454, Russia
A. A. Bush

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A. T. Kozakov
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A. G. Kochur
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V. I. Torgashev
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S. P. Kubrin
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V. G. Trotsenko
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A. A. Bush
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A. V. Nikolskii
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Correspondence to S. P. Kubrin .

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Mathematics, Mechanics and Computer Sciences Institute, Southern Federal University Math., Mech. and CS Inst., Rostov-on-Don, Russia
Ivan A. Parinov
Department of Microelectronics Engineering, National Kaohsiung Marine University Dept. of Microelectronics Eng., Kaohsiung, Taiwan
Shun-Hsyung Chang
Fakultas Teknik, University of 17 Agustus 1945 Surabaya , Surabaya, Indonesia
Muaffaq A. Jani

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Kozakov, A.T. et al. (2017). Crystal Structure, Phase and Elemental Composition and Chemical Bonding in Bi_1−X A _XFeO_3±Y Systems (A = Sr, Ca; 0 ≤X ≤ 1) from X-ray Diffraction, Mössbauer, and X-ray Photoelectron Spectra. In: Parinov, I., Chang, SH., Jani, M. (eds) Advanced Materials. Springer Proceedings in Physics, vol 193. Springer, Cham. https://doi.org/10.1007/978-3-319-56062-5_13

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DOI: https://doi.org/10.1007/978-3-319-56062-5_13
Published: 05 August 2017
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-56061-8
Online ISBN: 978-3-319-56062-5
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