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Polymer Complexes Based on Metal Chelate Monomers

  • Gulzhian I. Dzhardimalieva
  • Igor E. Uflyand
Chapter
Part of the Springer Series in Materials Science book series (SSMATERIALS, volume 257)

Abstract

The principal advances and problems of the preparation of polymeric metal complexes based on metal chelate monomers are analyzed. These monomers contain metal chelate cycle and multiple bonds for (co)polymerization or functionality, which can be involved in polycondensation. Use of metal chelate monomers allows to produce polymeric metal chelates in a single step, at that each chelating fragment contains a metal ion, and in most cases is characterized by a particular spatial configuration of the metal chelate cycle. The data are systematized according to methods for preparing polymeric metal chelates: homopolymerization, copolymerization, living and controlled polymerization, grafting polymerization, electropolymerization, polycondensation, as well as synthesis of dendrimers and hyperbranched polymers based on metal chelate monomers. Special attention is paid to the effect of a metal on reactivity of a multiple bond and functionalities containing in metal chelate monomers as well as the effect of double bond and functionalities on stereochemistry of a chelate node and electronic properties of a metal. The structural features of polymeric metal complexes based on metal chelate monomers are considered.

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Copyright information

© Springer International Publishing AG 2018

Authors and Affiliations

  1. 1.Institute of Problems of Chemical PhysicsRussian Academy of SciencesChernogolovka, Moscow regionRussia
  2. 2.Department of ChemistrySouthern Federal UniversityRostov-on-DonRussia

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